Research progress on influencing factors of stable storage of carbon dioxide hydrate

doi:10.16085/j.issn.1000-6613.2021-1275

Chemical Industry and Engineering Progress ›› 2021, Vol. 40 ›› Issue (S2): 364-372.DOI: 10.16085/j.issn.1000-6613.2021-1275

• Resources and environmental engineering • Previous Articles Next Articles

Research progress on influencing factors of stable storage of carbon dioxide hydrate

WANG Yingmei¹^,²^,³^,⁴(), ZHANG Zhaohui¹^,²^,³, NIU Aili¹^,²^,³, LIU Shenghao¹^,²^,³, JIAO Wenze¹^,²^,³, ZHANG Peng⁴

^1.School of Energy and Power Engineering, Lanzhou University of Technology, Lanzhou 730050, Gansu, China
^2.Key Lab of Complementary Energy System of Biomass and Solar Energy Gansu Province, Lanzhou 730050, Gansu, China
^3.Western China Energy & Environment Research Center, Lanzhou University of Technology, Lanzhou 730050, Gansu, China
^4.Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730050, Gansu, China

Received:2021-06-17 Revised:2021-06-28 Online:2021-11-12 Published:2021-11-12
Contact: WANG Yingmei

二氧化碳水合物稳定储存的影响因素研究进展

王英梅¹^,²^,³^,⁴(), 张兆慧¹^,²^,³, 牛爱丽¹^,²^,³, 刘生浩¹^,²^,³, 焦雯泽¹^,²^,³, 张鹏⁴

^1.兰州理工大学能源与动力工程学院，甘肃兰州 730050
^2.甘肃省生物质能与太阳能互补供能系统重点实验室，甘肃兰州 730050
^3.兰州理工大学西部能源与环境研究中心，甘肃兰州 730050
^4.中国科学院西北生态环境资源研究院冻土工程国家重点实验室，甘肃兰州 730050

通讯作者: 王英梅
作者简介:王英梅（1987—），女，博士，副教授，硕士研究生导师，主要从事多年冻土区天然气水合物方面的研究工作。E-mail: wymch@lab.ac。
基金资助:
国家自然科学基金(41661103);中国科学院冻土工程国家重点实验室开放基金(SKLFSE201406);国家重点研发计划(2017YFC0307303)

Abstract

Abstract:

Gas hydrate extraction by CO₂ replacement and gas storage and transportation by gas hydrate method are the focus of research by scientists at present, and the stability of gas hydrate is very important for its long-term storage and long-distance transportation. Therefore, it is necessary to improve the storage capacity of carbon dioxide hydrate and to seek the high efficient and stable storage conditions of hydrate. However, scientists have found that some accelerators can make hydrate stored for a long time under mild conditions. This paper analyzes the influence of the“self-protection”effect on the stability of carbon dioxide hydrate from the three mechanisms, temperature, pressure, particle size, accelerator and hydrate form, and proves that gas hydrate generally has good stability under the conditions of 260~270K and 0.1~0.4MPa. In addition, the same accelerators have different effects on the stability of hydrate above and below freezing point. Finally, the research direction of hydrate stability in the future is pointed out.

Key words: carbon dioxide hydrate, controlled decomposition, stable storage, accelerator

摘要：

CO₂置换开采天然气水合物以及水合物法气体储运技术是当前科学家们研究的热点，而水合物的稳定性对其长时间储存和长距离运输至关重要。因此必须提高二氧化碳水合物储存能力和寻求水合物高效稳定的储存条件，然而科学家们发现一些促进剂可以使水合物在温和的条件下长时间存储。本文从“自保护”效应的3种机制、温度、压力以及粒径、促进剂和水合物形态这些因素分析了其对二氧化碳水合物稳定性的影响，证明气体水合物普遍在260~270K和0.1~0.4MPa的条件下稳定性较好，并且同种促进剂在冰点上下对水合物稳定性的影响不同，最后指出了水合物稳定性方面今后的研究方向。

关键词: 二氧化碳水合物, 可控分解, 稳定储存, 促进剂

CLC Number:

O643.1

WANG Yingmei, ZHANG Zhaohui, NIU Aili, LIU Shenghao, JIAO Wenze, ZHANG Peng. Research progress on influencing factors of stable storage of carbon dioxide hydrate[J]. Chemical Industry and Engineering Progress, 2021, 40(S2): 364-372.

王英梅, 张兆慧, 牛爱丽, 刘生浩, 焦雯泽, 张鹏. 二氧化碳水合物稳定储存的影响因素研究进展[J]. 化工进展, 2021, 40(S2): 364-372.

Figures/Tables 2

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Research progress on influencing factors of stable storage of carbon dioxide hydrate

二氧化碳水合物稳定储存的影响因素研究进展

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