Research progress on formation kinetics of gas hydrate in porous media below freezing point

doi:10.16085/j.issn.1000-6613.2021-0689

Chemical Industry and Engineering Progress ›› 2021, Vol. 40 ›› Issue (S2): 101-108.DOI: 10.16085/j.issn.1000-6613.2021-0689

• Energy processes and technology • Previous Articles Next Articles

Research progress on formation kinetics of gas hydrate in porous media below freezing point

ZHANG Xuemin¹^,²^,³(), ZHANG Mengjun¹^,²^,³, YANG Huijie¹^,²^,³, LI Yinhui¹^,²^,³, LI Jinping¹^,²^,³, WANG Yingmei¹^,²^,⁴

^1.School of Energy and Power Engineering, Lanzhou University of Technology, Lanzhou 730050, Gansu, China
^2.Key Lab of Complementary Energy System of Biomass and Solar Energy Gansu Province, Lanzhou 730050, Gansu, China
^3.Western China Energy & Environment Research Center, Lanzhou University of Technology, Lanzhou 730050, Gansu, China
^4.Northwest Institute of Eco-Environment and Resources, Chinese Academy of Sciences, Lanzhou 730050, Gansu, China

Received:2021-04-05 Revised:2021-05-19 Online:2021-11-12 Published:2021-11-12
Contact: ZHANG Xuemin

冰点以下多孔介质中气体水合物的生成动力学研究进展

张学民¹^,²^,³(), 张梦军¹^,²^,³, 杨惠结¹^,²^,³, 李银辉¹^,²^,³, 李金平¹^,²^,³, 王英梅¹^,²^,⁴

^1.兰州理工大学能源与动力工程学院，甘肃兰州 730050
^2.甘肃省生物质能与太阳能互补供能系统重点实验室，甘肃兰州 730050
^3.兰州理工大学西部能源与环境研究中心，甘肃兰州 730050
^4.中国科学院西北生态环境资源研究院冻土工程国家重点实验室，甘肃兰州 730050

通讯作者: 张学民
作者简介:张学民（1987—），男，博士，副教授，硕士生导师，主要从事气体水合物生成与分解动力学方面的研究。E-mail: zxm2010lut@163.com。
基金资助:
国家自然科学基金(51906093);甘肃省高等学校创新能力提升项目(2019A-019);中科院天然气水合物重点实验室开放基金(Y907ke1001);兰州理工大学“红柳优秀青年人才支持计划”（2018）

Abstract

Abstract:

There are a lot of natural gas hydrate resources in the permafrost area of Qinghai-Tibet Plateau. The safe exploitation of natural gas hydrate and the formation storage of greenhouse gas CO₂can be realized by the CO₂ replacement mining of natural gas hydrate in permafrost area. The formation kinetics of gas hydrate in porous media below the freezing point is a difficult and hot issue in the research field of gas hydrate replacement and exploitation in frozen soil regions. In this paper, the research progress on the formation kinetics of gas hydrate in porous media below freezing point is comprehensively reviewed, and the formation mechanism and characteristics of gas hydrate in porous media below freezing point in different systems are discussed. In addition, the mechanism of ice hydrate formation and the formation characteristics of gas hydrate in the ice powder/porous media system are described in detail, and analyzed the area that need to be perfected and improved in the research on the kinetics of gas hydrate formation in porous media below freezing point. Finally, it is pointed out that the formation process of hydrate in porous media below freezing point is controlled by various factors such as heat transfer and mass transfer, and revealing the dominant factors and influence laws of different processes is the focus of future research. At present, the understanding of the formation characteristics and mechanism of hydrates in porous media below the freezing point is not yet mature, and in-depth research is still needed.

Key words: porous media, gas hydrate, formation kinetics, formation mechanism, formation promotion

摘要：

青藏高原冻土区储存着大量的天然气水合物资源，CO₂置换开采冻土区的天然气水合物可实现天然气水合物的安全开采和温室气体CO₂的地层封存。冰点以下多孔介质中气体水合物的生成动力学，是冻土区天然气水合物置换开采研究领域的难点和热点问题。本文全面综述了冰点以下多孔介质中气体水合物的生成动力学研究进展，讨论了不同体系冰点以下多孔介质中气体水合物的形成机理及其生成特性；详述了冰生成水合物机理及其冰粉/多孔介质体系中气体水合物的生成特性，分析了冰点以下多孔介质中气体水合物生成动力学研究尚待完善和改进的地方。最后本文指出冰点以下多孔介质中水合物的生成过程是由传热、传质等多种因素所控制，揭示不同过程的主导因素及其影响规律是今后研究的重点方向。目前对冰点以下多孔介质中水合物的生成特性及机理的认识尚未成熟，仍需深入研究。

关键词: 多孔介质, 气体水合物, 生成动力学, 形成机理, 生成促进

CLC Number:

O643.1

ZHANG Xuemin, ZHANG Mengjun, YANG Huijie, LI Yinhui, LI Jinping, WANG Yingmei. Research progress on formation kinetics of gas hydrate in porous media below freezing point[J]. Chemical Industry and Engineering Progress, 2021, 40(S2): 101-108.

张学民, 张梦军, 杨惠结, 李银辉, 李金平, 王英梅. 冰点以下多孔介质中气体水合物的生成动力学研究进展[J]. 化工进展, 2021, 40(S2): 101-108.

Figures/Tables 2

References 57

1	SLOAN E D. Fundamental principles and applications of natural gas hydrates[J]. Nature, 2003, 426(6964): 353-359.
2	孙萍. 天然气水合物——二十一世纪的新能源[J]. 海洋地质动态, 1998(12):3-6.
	SUN P. Natural gas hydrate—new energy in the 21st century[J]. Frontiers of Marine Geology, 1998(12): 3-6.
3	BENSON S M, COLE D R. CO₂ sequestration in deep sedimentary formations[J]. Elements, 2008, 4(5): 325-331.
4	ZHANG X M, WANG Y M, LI J P, et al. Recovering CH₄ from natural gas hydrate with CO₂ in porous media below the freezing point[J]. Petroleum Science and Technology, 2019, 37(7): 770-779.
5	XIE Y, ZHU Y J, ZHENG T, et al. Replacement in CH₄-CO₂ hydrate below freezing point based on abnormal self-preservation differences of CH₄ hydrate[J]. Chemical Engineering Journal, 2021, 403(3):1-11.
6	REHDER G, ECKL R, ELFGEN M, et al. Methane hydrate pellet transport using the self-preservation effect: a techno-economic analysis[J]. Energies, 2012, 5(7): 2499-2523.
7	MIMACHI H, TAKEYA S, YONEYAMA A, et al. Natural gas storage and transportation within gas hydrate of smaller particle: size dependence of self-preservation phenomenon of natural gas hydrate[J]. Chemical Engineering Science, 2014, 118(3): 208-213.
8	MUROMACHI S, OHMURA R, TAKEYA S, et al. Clathrate hydrates for ozone preservation[J]. The Journal of Physical Chemistry B, 2010, 114(35): 11430-11435.
9	NAKAJIMA T, AKATSU S, OHMURA R, et al. Molecular storage of ozone in a clathrate hydrate formed from an O₃+ O₂+ CO₂ gas mixture[J]. Angewandte Chemie, 2011, 123(44): 10524-10527.
10	PETERS T B, SMITH J L, BRISSON J G. Production of CO₂ clathrate hydrate frozen desserts by flash freezing[J]. Journal of food engineering, 2010, 100(4): 669-677.
11	SATO T, TAKEYA S, NAGASHIMA H D, et al. Preservation of carbon dioxide clathrate hydrate coexisting with sucrose under domestic freezer conditions[J]. Journal of Food Engineering, 2014, 120(1):69-74.
12	NAGASHIMA H D, ALAVI S, OHMURA R. Preservation of carbon dioxide clathrate hydrate in the presence of fructose or glucose and absence of sugars under freezer conditions[J]. Journal of Industrial and Engineering Chemistry, 2017, 54(7): 332-340.
13	HATAKEYAMA T, AIDA E, YOKOMORI T, et al. Fire extinction using carbon dioxide hydrate[J]. Industrial & Engineering Chemistry Research, 2009, 48(8): 4083-4087.
14	ZHANG X M, LI J P, WU Q B, et al. Experimental study on the characteristics of CO₂ hydrate formation in porous media below freezing point[J]. China Petroleum Processing & Petrochemical Technology, 2015, 17(3): 32-38.
15	CHONG Z R, YANG S H B, BABU P, et al. Review of natural gas hydrates as an energy resource: prospects and challenges[J]. Applied Energy, 2016, 162(7): 1633-1652.
16	孙长宇, 陈光进, 郭天民. 水合物成核动力学研究现状[J]. 石油学报, 2001, 22(4): 82-86.
	SUN C Y, CHEN G J, GUO T M. Research status of hydrate nucleation kinetics[J]. Acta Petrolei Sinica, 2001, 22(4): 82-86.
17	SLOAN E D, FLEYFEL F. A molecular mechanism for gas hydrate nucleation from ice[J]. AIChE Journal, 1991, 37(9): 1281-1292.
18	JANDER W. Reaktionen im festen zustande bei höheren temperaturen. reaktionsgeschwindigkeiten endotherm verlaufender umsetzungen[J]. Zeitschrift für Anorganische und Allgemeine Chemie, 1927, 163(1): 1-30.
19	FUJII K, KONDO W. Kinetics of the hydration of tricalcium silicate[J]. Journal of the American Ceramic Society, 1974, 57(11): 492-497.
20	HENNING R W, SCHULTI A J, THIEU V, et al. Neutron diffraction studies of CO₂clathrate hydrate: formation from deuterated ice[J]. The Journal of Physical Chemistry A, 2000, 104(21): 5066-5071.
21	KUHS W F, STAYKOVA D K, SALAMATIN A N. Formation of methane hydrate from polydisperse ice powders[J]. The Journal of Physical Chemistry B, 2006, 110(26): 13283-13295.
22	KAWAMURA T, KOMIA T, YAMAMOTO Y, et al. Growth kinetics of CO₂ hydrate just below melting point of ice[J]. Journal of Crystal Growth, 2002, 234(1): 220-226.
23	WANG X, SCHULTZ A J, HALPERN Y. Kinetics of methane hydrate formation from polycrystalline deuterated ice[J]. The Journal of Physical Chemistry A, 2002, 106(32): 7304-7309.
24	FALENTY A, GENVO G, HANSEN T C, et al. Kinetics of CO₂ hydrate formation from water frost at low temperatures: experimental results and theoretical model[J]. The Journal of Physical Chemistry C, 2011, 115(10): 4022-4032.
25	VLASOV V A. Phenomenological diffusion theory of formation of gas hydrate from ice powder[J]. Theoretical Foundations of Chemical Engineering, 2012, 46(6): 576-582.
26	VLASOV V A. Diffusion model of gas hydrate formation from ice[J]. Heat and Mass Transfer, 2016, 52(3): 531-537.
27	VLASOV V A. Simplified diffusion model of gas hydrate formation from ice[J]. International Journal of Heat and Mass Transfer, 2021, 165(7): 1-7.
28	BARRER R M, EDGE A V J. Gas hydrates containing argon, krypton and xenon: kinetics and energetics of formation and equilibria[J]. Proceedings of the Royal Society of London, 1967, 300(1460):1-24.
29	HWANG M J, WRUGHT D A, KAPUR A, et al. An experimental study of crystallization and crystal growth of methane hydrates from melting ice[J]. Journal of Inclusion Phenomena & Molecular Recognition in Chemistry, 1990, 8(1):103-116.
30	RIVREA J J, JANDA K C. Ice particle size and temperature dependence of the kinetics of propane clathrate hydrate formation[J]. The Journal of Physical Chemistry C, 2012, 116(36): 19062-19072.
31	NGUYEN M T, AMTAWONG J, SMOLL K, et al. Gas flow rate and temperature dependence of the kinetics of difluoromethane clathrate hydrate formation from CF₂H₂ gas and ice particles[J]. The Journal of Physical Chemistry C, 2016, 120(16): 8482-8489.
32	PIRZADEH P, KUSALIK P G. Molecular insights into clathrate hydrate nucleation at an ice-solution interface[J]. Journal of the American Chemical Society, 2013, 135(19): 7278-7287.
33	MOUR M, HAARDA M, HASEGAWA T, et al. Formation and growth of tetrahydrofuran hydrate at the ice/hexane interface[J]. The Journal of Physical Chemistry C, 2012, 116(24): 13296-13301.
34	LIU W G, WANG L J, YANG M J, et al. Experimental study on the methane hydrate formation from ice powders[J]. Energy Procedia, 2014, 61(1): 619-623.
35	展静, 吴青柏, 王英梅. 冰点以下不同粒径冰颗粒形成CH₄水合物的实验[J]. 天然气工业, 2009, 29(6): 126-129.
	ZHAN J, WU Q B, WANG Y M. Experiments on the formation of methane hydrate from ice particles with different sizes below freezing point[J]. Natural Gas Industry, 2009, 29(6): 126-129.
36	LIU W G, LI Q Q, SONG Y C, et al. Diffusion theory of formation of gas hydrate from ice powder without melting[J]. Energy Procedia, 2014, 61(1): 513-522.
37	VLASOV V A. Formation and dissociation of gas hydrate in terms of chemical kinetics[J]. Reaction Kinetics, Mechanisms and Catalysis, 2013, 110(1): 5-13.
38	CHIGLINTSEVA A S, RUSINOV A A. Formation of a hydrate layer at a gas-water (ice) interface[J]. Journal of Engineering Physics and Thermophysics, 2019, 92(6): 1396-1405.
39	NAGASHIMA H D, OSHIMA M, JIN Y. Film-growth rates of methane hydrate on ice surfaces[J]. Journal of Crystal Growth, 2020, 537(3): 1-6.
40	ZHAO J F, LIANG H Y, YANG L, et al. Growth kinetics and gas diffusion in formation of gas hydrates from ice[J]. The Journal of Physical Chemistry C, 2020, 124(24): 12999-13007.
41	WANG Z, LU W G, LI Y H, et al. Influence of porous media on methane hydrate formation from ice powders[J]. Energy Procedia, 2017, 105(6): 224-229.
42	ZHANG X M, LI J P, WU Q B, et al. Effect of initial pressure on the formation of carbon dioxide hydrate in frozen quartz sand[J]. Energy & Fuels, 2019, 33(11): 11346-11352.
43	CHUVILIN E M, DAVLETSHINA D A, LUPACHIK M V. Hydrate formation in frozen and thawing methane-saturated sediments[J]. Earth’s Cryosphere, 2019, 23(2): 42-52.
44	李金平, 姚泽, 李洋, 等. 冰点以下石英砂中二氧化碳水合物的生成特性[J]. 应用基础与工程科学学报, 2020, 28(4): 843-851.
	LI J P, YAO Z, LI Y, et al. Formation characteristics of carbon dioxide hydrate in quartz sand below freezing point[J]. Journal of Applied Basic Science and Engineering, 2020, 28(4): 843-851.
45	LIU J, DING J X, LIANG D Q. Experimental study on hydrate-based gas separation of mixed CH₄/CO₂ using unstable ice in a silica gel bed[J]. Energy, 2018, 157(2): 54-64.
46	LIU J, LIANG D Q. Investigation on methane hydrate formation in silica gel particles below the freezing point[J]. RSC Advances, 2019, 9(26): 15022-15032.
47	KHASANOV M K, MUSAKAEV N G. Gas hydrate formation in porous ice rich methane reservoirs upon injection of carbon dioxide: forward modeling[J]. Earth’s Cryosphere, 2016, 20(3): 59-65.
48	PIRZADEH P, KUSALIK P G. Molecular insights into clathrate hydrate nucleation at an ice-solution interface[J]. Journal of the American Chemical Society, 2013, 135(19): 7278-7287.
49	LIU W G, LI Y H, XU X H. Influence factors of methane hydrate formation from ice: temperature, pressure and SDS surfactant[J]. Chinese Journal of Chemical Engineering, 2019, 27(2): 405-410.
50	SA J H, SUM A K. Promoting gas hydrate formation with ice-nucleating additives for hydrate-based applications[J]. Applied Energy, 2019, 251(2): 1-10.
51	AMTAWONG J, GUO J, HALE J S, et al. Propane clathrate hydrate formation accelerated by methanol[J]. The Journal of Physical Chemistry Letters, 2016, 7(13): 2346-2349.
52	MCLAURIN G, SHINK K, ALAVI S, et al. Antifreezes act as catalysts for methane hydrate formation from ice[J]. Angewandte Chemie, 2014, 126(39): 10597-10601.
53	BOBEV S, TAIT K T. Methanol-inhibitor or promoter of the formation of gas hydrates from deuterated ice?[J]. American Mineralogist, 2004, 89(8-9): 1208-1214.
54	CHEN Y A, CHU L K, CHU C K, et al. Synthesis of methane hydrate from ice powder accelerated by doping ethanol into methane gas[J]. Scientific Reports, 2019, 9(1): 1-11.
55	MOUDRAKOVSKI I L, RATCLIFFE C I, MCLAURIN G E, et al. Hydrate layers on ice particles and superheated ice: a¹ HNMR microimaging study[J]. The Journal of Physical Chemistry A, 1999, 103(26): 4969-4972.
56	PRADO M R, CAZARES Y, JANDA K C. Toward the efficient production of methane/propane double hydrate[J]. Industrial & Engineering Chemistry Research, 2009, 48(11): 5160-5164.
57	ABBONDONDOLA J A, FLEISCHER E B, JANDA K C. Propane clathrate hydrate formation accelerated by xenon[J]. The Journal of Physical Chemistry C, 2009, 113(11): 4717-4720.

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Research progress on formation kinetics of gas hydrate in porous media below freezing point

冰点以下多孔介质中气体水合物的生成动力学研究进展

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