Research progress of wave-transmitting materials for microwave heating

doi:10.16085/j.issn.1000-6613.2021-0142

Abstract

Abstract:

Microwave heating technology has been widely used in many fields, such as chemical strengthening, metal smelting, ceramic sintering, food processing and so on, because of its advantages of green environmental protection, volume heating and selective heating. However, there are many problems in microwave reactor, such as poor transmission effect and low utilization rate of microwave. With the continuous development of microwave heating technology, more and more attention has been paid to the selection of wave-transmitting materials in microwave heating equipment. This research mainly reviewes the application status of wave-transmitting materials in the field of microwave heating. The types of wave-transmitting materials are briefly introduced, and the microwave heating containers and thermal insulation materials are discussed. The research progress of high-temperature wave-transmitting materials such as oxides, nitrides, silicates and phosphates, and medium and low-temperature wave-transmitting materials such as polytetrafluoroethylene, glass fiber reinforced resin base and epoxy resin are introduced in detail. It also specifically discusses the dielectric properties and wave-transmitting properties of various ceramic fiber products such as fiber cotton, fiber blankets and fiberboards commonly used in microwave heating. Finally, this article points out the current common problems of wave-transmitting materials for microwave heating, and prospected the application and development of wave-transmitting materials.

Key words: microwave heating, ware-transmitting material, container, insulation refractory

摘要：

微波加热技术因其绿色环保、体积加热、选择性加热等优势，已被广泛应用于化工强化、金属冶炼、陶瓷烧结、食品加工等众多领域，但微波在反应器内普遍存在透波效果差、微波利用率低等问题。随着微波加热技术的不断发展，微波加热设备中透波材料的选用越来越受到大家的关注。本文主要针对透波材料在微波加热领域中的应用现状进行综述，对透波材料的种类进行简要介绍，分别从微波加热用容器和保温材料两方面进行论述。详细介绍了氧化物、氮化物、硅酸盐、磷酸盐等高温透波材料及聚四氟乙烯、玻纤增强树脂基、环氧树脂等中、低温透波材料的研究进展，并具体论述了目前微波加热常用纤维棉、纤维毯和纤维板等各种陶瓷纤维制品的介电特性和透波性能，最后指出了目前微波加热用透波材料普遍存在的问题，并对透波材料的应用和发展作出了展望。

关键词: 微波加热, 透波材料, 容器, 隔热耐火材料

CLC Number:

TB35

BAI Yongzhen, SHANG Xiaobiao, LIU Meihong, WEI Cong, ZHANG Fucheng, XIAO Liping, LI Guangchao, CHEN Junruo. Research progress of wave-transmitting materials for microwave heating[J]. Chemical Industry and Engineering Progress, 2022, 41(1): 253-263.

白永珍, 尚小标, 刘美红, 魏聪, 张富程, 肖利平, 李广超, 陈君若. 微波加热用透波材料的研究进展[J]. 化工进展, 2022, 41(1): 253-263.

Figures/Tables 8

材料	频率	温度	介电参数	数值
氧化铝	2450MHz	22℃≤T≤1379℃	$ε r'$	8.9~11.77
氧化铝	2450MHz	22℃≤T≤1379℃	$ε r ″$	0.004~0.0476
莫来石	915MHz	400℃≤T≤1300℃	$ε r'$	3×10^-9T³-4×10^-6T²+0.0032T+4.4869
	915MHz	400℃≤T≤1300℃	$ε r ″$	9×10^-7T²-0.0002T-0.0268
	2450MHz	27℃≤T≤1027℃	$ε r'$	2.119×10^-6T²-0.00037T+6.1438
	2450MHz	27℃≤T≤1027℃	$ε r ″$	1.7052×10^-9T³-1.4616×10^-6T²+0.000559T+0.02279
熔融石英	915MHz	25℃≤T≤1400℃	$ε r'$	3.816~3.988
	915MHz	25℃≤T≤1400℃	tanδ	4.98×10^-6~8.39×10^-6
	2360MHz	25℃≤T≤800℃	$ε r'$	3.820~3.892
	2360MHz	25℃≤T≤800℃	tanδ	4.97×10^-6~5.85×10^-6
硅酸铝纤维板^［13］	2422MHz	20℃≤T≤1300℃	$ε r'$	2×10^-10T³-6×10^-8T²-0.0003T+1.2671
硅酸铝纤维板^［13］	2422MHz	20℃≤T≤1300℃	$ε r ″$	2×10^-11T³-8×10^-9T²-9×10^-6T+0.0027
氧化锆纤维板^［13］	2422MHz	20℃≤T≤1400℃	$ε r'$	6×10^-10T³-9×10^-7T²-0.0003T+2.5433
氧化锆纤维板^［13］	2422MHz	20℃≤T≤1400℃	$ε r ″$	3×10^-9T³-5×10^-7T²-0.0003T+0.0438

材料	频率	温度	介电参数	数值
氧化铝	2450MHz	22℃≤T≤1379℃	$ε r'$	8.9~11.77
氧化铝	2450MHz	22℃≤T≤1379℃	$ε r ″$	0.004~0.0476
莫来石	915MHz	400℃≤T≤1300℃	$ε r'$	3×10^-9T³-4×10^-6T²+0.0032T+4.4869
	915MHz	400℃≤T≤1300℃	$ε r ″$	9×10^-7T²-0.0002T-0.0268
	2450MHz	27℃≤T≤1027℃	$ε r'$	2.119×10^-6T²-0.00037T+6.1438
	2450MHz	27℃≤T≤1027℃	$ε r ″$	1.7052×10^-9T³-1.4616×10^-6T²+0.000559T+0.02279
熔融石英	915MHz	25℃≤T≤1400℃	$ε r'$	3.816~3.988
	915MHz	25℃≤T≤1400℃	tanδ	4.98×10^-6~8.39×10^-6
	2360MHz	25℃≤T≤800℃	$ε r'$	3.820~3.892
	2360MHz	25℃≤T≤800℃	tanδ	4.97×10^-6~5.85×10^-6
硅酸铝纤维板^［13］	2422MHz	20℃≤T≤1300℃	$ε r'$	2×10^-10T³-6×10^-8T²-0.0003T+1.2671
硅酸铝纤维板^［13］	2422MHz	20℃≤T≤1300℃	$ε r ″$	2×10^-11T³-8×10^-9T²-9×10^-6T+0.0027
氧化锆纤维板^［13］	2422MHz	20℃≤T≤1400℃	$ε r'$	6×10^-10T³-9×10^-7T²-0.0003T+2.5433
氧化锆纤维板^［13］	2422MHz	20℃≤T≤1400℃	$ε r ″$	3×10^-9T³-5×10^-7T²-0.0003T+0.0438

References 70

1	周德良, 刘洁. 微波加热及其量子特性[J]. 黑龙江八一农垦大学学报, 2019, 31(1): 74-77, 108.
	ZHOU Deliang, LIU Jie. Microwave heating and quantum property[J]. Journal of Heilongjiang Bayi Agricultural University, 2019, 31(1): 74-77, 108.
2	牟群英, 李贤军. 微波加热技术的应用与研究进展[J]. 物理, 2004, 33(6): 438-442.
	MOU Qunying, LI Xianjun. Applications of microwave heating technology[J]. Physics, 2004, 33(6): 438-442.
3	彭金辉, 梅毅, 巨少华, 等. 微波化工技术[M]. 北京: 化学工业出版社, 2020.
	PENG Jinhui, MEI Yi, JU Shaohua, et al. Microwave chemical technology[M]. Beijing: Chemical Industry Press, 2020.
4	LI Bo, ZHENG Jingguo, LI Wei. Influence of cobalt ions non-stoichiometry on the microstructure and microwave properties of Ca₅Co₄(VO₄)₆ceramics[J]. Ceramics International, 2017, 43(16): 13956-13962.
5	HORIKOSHI S, SCHIFFMANN R F, FUKUSHIMA J, et al. Microwave-assisted chemistry[M]//Microwave Chemical and Materials Processing, 2018: 243-319.
6	CAMPAONE A, BAVA J, MASCHERONI R. Modeling and process simulation of controlled microwave heating of foods by using of the resonance phenomenon[J]. Applied Thermal Engineering, 2014, 73(1): 914-923.
7	BEHREND R, DORN C, UHLIG V, et al. Investigations on container materials in high temperature microwave applications[J]. Energy Procedia, 2017, 120: 417-423.
8	蔡德龙, 陈斐, 何凤梅, 等. 高温透波陶瓷材料研究进展[J]. 现代技术陶瓷, 2019, 40(S1): 4-120.
	CAI Delong, CHEN Fei, HE Fengmei, et al. Recent progress and prospestion on high-temperature wave-transparent ceramic materials[J]. Advanced Ceramics, 2019, 40(Si): 4-120.
9	黄新松, 李文钦, 简科. 耐高温陶瓷透波纤维研究进展[J]. 安全与电磁兼容, 2010(2): 53-56.
	HUANG Xinsong, LI Wenqin, JIAN Ke. Progress in the research of high-temperature ceramic wave-transparent fibers[J]. Safety and EMC, 2010(2): 53-56.
10	张子龙. 超常材料对常规微波材料吸收性能的调控研究[D]. 长沙: 湖南大学, 2016.
	ZHANG Zilong. Absorbing properties of conventional microwave absorbing material optimized by metamaterials[D]. Changsha: Hunan University, 2016.
11	AAKRITI R, ABHISHEKKUMAR J, MARIFHUSSAIN A, et al. Metamaterial-inspired microwave sensor for measurement of complex permittivity of materials[J]. Microwave and Optical Technology Letters,2016, 58(11): 2577-2581.
12	谢绵钰. 几种功能材料的高效能制备与性能表征[D]. 广州: 暨南大学, 2016.
	XIE Mianyu. Efficient preparation and characterization of several kinds of functional materials[D]. Guangzhou: Jinan University, 2016.
13	尚小标, 陈君若, 张伟峰, 等. 硅酸铝/氧化锆纤维板在微波加热中透波性研究[J]. 化学工程, 2014, 42(5): 35-38.
	SHANG Xiaobiao, CHEN Junruo, ZHANG Weifeng, et al. Wave-transparent property of alumino silicate/zirconia fiberboard in microwave heating[J]. Chemical Engineering, 2014, 42(5): 35-38.
14	BHATTACHARYA M, BASAK T. A review on the susceptor assisted microwave processing of materials[J]. Energy, 2016, 97: 306-338.
15	ZHOU B, ZHOU J, ZHANG Z, et al. Dielectric characterizations and heating behavior of siderite in microwave field[J]. Materials Research Express, 2018, 5(10): 105502.
16	SHANG X B, ZHAI D, ZHANG F, et al. Electromagnetic waves transmission performance of alumina refractory ceramics in 2.45GHz microwave heating[J]. Ceramics International, 2019, 45(17): 23493-23500.
17	AFSAR M N, BIRCH J R, CLARKE R N, et al. The measurement of the properties of materials[J]. Proceedings of the IEEE, 1986, 74(1): 183-199.
18	赵艳丽. 典型地物微波介电特性及其室内测量方法研究[D]. 成都: 电子科技大学, 2009.
	ZHAO Yanli. Microwave dielectric properties of typical ground objects and its indoor measurement method[D]. Chengdu: University of Electronic Science and Technology, 2009.
19	王秀丽. 典型地物介电常数测量方法研究[D]. 成都: 电子科技大学, 2011.
	WANG Xiuli. Research on measurement method of dielectric constant of typical ground objects[D]. Chengdu: University of Electronic Science and Technology, 2011.
20	黎义, 李建保, 何小瓦. 采用谐振腔法研究透波材料的高温介电性能[J]. 红外与毫米波学报, 2004, 23(2): 157-160.
	LI Yi, LI Jianbao, HE Xiaowa. Study on high temperature dielectric properties of magnetic window materials by cavity resonator method[J]. Journal of Infrared and Millimeter Waves, 2004, 23(2): 157-160.
21	王依超, 郭高凤, 王娟, 等. 自由空间法测量电磁材料电磁参数[J]. 宇航材料工艺, 2014, 44(1): 107-111.
	WANG Yichao, GUO Gaofeng, WANG Juan, et al. Measurement of electromagnetic parameters of electromagnetic materials by free-space method[J]. Aerospace Materials & Technology, 2014, 44(1): 107-111.
22	PENG Z W, JIANN T. Microwave dielectric characterization of silicon dioxide[M]. Hoboken: John Wiley & Sons, Inc., 2013.
23	SHANG X B, CHEN J R, PENG J H. Dynamic transmission performances of alumina and mullite refractory ceramics in microwave high-temperature heating[J]. High Temperature Materials and Processes, 2016, 35(1): 113-119.
24	ZHAI D, WEI C, ZHANG F C, et al. Microwave transmission performance of fused silica ceramics in microwave high-temperature heating[J]. Ceramics International, 2019, 45(5): 6157-6162.
25	ZHAI D, ZHANG F C, WEI C, et al. Dielectric properties and electromagnetic wave transmission performance of polycrystalline mullite fiberboard at 2.45GHz[J]. Ceramics International, 2020, 46(6): 7362-7373.
26	LEWIS D, SPANN J R. Assessment of new radome materials as replacements for pyroceram 9606[J]. Scientia Sinica, 1980: 165-169.
27	吴文军, 胡子君, 李俊宁, 等. Al₂O₃掺杂对SiO₂纳米透波/隔热材料性能的影响[J]. 宇航材料工艺, 2014, 44(1): 97-100.
	WU Wenjun, HU Zijun, LI Junning, et al. Effect on the properties of SiO₂ nanoporous transparent-wave/heat-insulation materials doped with Al₂O₃[J]. Aerospace Materials & Technology, 2014, 44(1): 97-100.
28	张雄, 王义, 程海峰. 石英纤维透波复合材料的研究进展[J]. 材料导报, 2012, 26(S1): 96-100.
	ZHANG Xiong, WANG Yi, CHENG Haifeng. Research and development of wave-transparent composites reinforced by silica fibers[J]. Materials Review, 2012, 26(S1): 96-100.
29	万欣欣, 尚小标, 陈君若, 等. 二氧化硅陶瓷在微波场中的透波性能研究[J]. 中国陶瓷, 2015, 51(3): 15-17.
	WAN Xinxin, SHANG Xiaobiao, CHEN Junruo, et al. Study on the wave-transparent property of silicon dioxide under microwave irradiation[J]. China Ceramics, 2015, 51(3): 15-17.
30	HOTTA M, HAYASHI M, NISHIKATA A, et al. Complex permittivity and permeability of SiO₂ and Fe₃O₄ powders in microwave frequency range between 0.2 and 13.5GHz[J]. ISIJ International, 2009, 49(9): 1443-1448.
31	Jane’s Information Group. Jane’s strategic weapon systems [R]. Jane’s Air-Launched Weapons, 2009.
32	张雯, 王红洁, 金志浩. 先驱体热解制备BN复合陶瓷材料研究进展[J]. 兵器材料科学与工程, 2004, 27(5): 58-63.
	ZHANG Wen, WANG Hongjie, JIN Zhihao. Preparation of BN matrix composites, by precursor thermolysis[J]. Ordnance Material Science and Engineering, 2004, 27(5): 58-63.
33	GOLDEN K, HANAWALT B, OSSMANN W. The prediction and measure of dielectric proper-ties and RF transmission through ablating BN antenna windows[C]//16th Thermophysics Conference. California: Palo Alto, 1981: 23-25.
34	HANAWALT A. Plasma arc test technique for evaluating antenna window RF transmission performance[C]//American Institute of Aeronautics and Astronautics and American Society of Mechanical Engineers. Joint Thermophysics, Fluids, Plasma and Heat Transfer Conference, 3rd, St. Louis, MO, 1982: 9.
35	HAN J, SUN Y, ZHANG Y. Dielectric properties in GHz range of porous Si₃N₄-BN-SiO₂ ceramics with considerable flexural strength prepared by low temperature sintering in air[J]. Materials Science and Technology, 2010, 26(8): 996-1000.
36	刘坤, 张长瑞, 曹峰, 等. BNp/BN复合材料的制备及其性能研究[C]//全国高技术陶瓷学术年会摘要集. 南京, 2012.
	LIU Kun, ZHANG Changrui, CAO Feng, et al. Preparation and properties of BNp/BN composites[C]//National High Tech Ceramics Annual Meeting. Nanjing, 2012.
37	邹春荣, 张长瑞, 肖永栋, 等. 高性能透波陶瓷纤维的研究现状和展望[J]. 硅酸盐通报, 2013, 32(2): 274-279.
	ZOU Chunrong, ZHANG Changrui, XIAO Yongdong, et al. Progress and prospect of high performance wave-transparent ceramic fibers[J]. Bulletin of the Chinese Ceramic Society, 2013, 32(2): 274-279.
38	李光亚, 梁艳媛. 纤维增强SiBN陶瓷基复合材料的制备及性能[J]. 宇航材料工艺, 2016, 46(3): 61-64.
	LI Guangya, LIANG Yanyuan. Preparation and performance of fiber reinforced SiBN ceramic matrix composite[J]. Aerospace Materials & Technology, 2016, 46(3): 61-64.
39	范冰冰, 李红霞, 李威, 等. 一种微波窑用SiNO透波-隔热一体化内衬材料及其制备方法: CN201710118361.X[P]. 2017-05-31.
	FAN Bingbing, LI Hongxia, LI Wei, et al. SiNO wave transmission-heat insulation integrated inner lining material for microwave kiln, and preparation method of material: CN 201710118361.X[P]. 2017-05-31.
40	徐恩霞, 王玉霞, 董萌蕾, 等. 一种微波冶金窑车用刚玉-氧氮化硅复合耐火材料: CN 201710736091.9[P]. 2017-12-01.
	XU Enxia, WANG Yuxia, DONG Menglei, et al. Corundum silicon oxynitride composite refractory material for microwave metallurgical kiln car: CN 201710736091.9[P]. 2017-12-01.
41	魏坤, 贺伦燕, 石燕. 莫来石材料的研究现状及其应用[J]. 功能材料, 1993, 24(1): 85-91.
	WEI Kun, HE Lunyan, SHI Yan. Study present situation and application of mullite materials[J]. Journal of Functional Materials, 1993, 24(1): 85-91.
42	张桂敏. 莫来石的低温合成与透波性能研究[D]. 武汉: 武汉理工大学, 2010.
	ZHANG Guimin. Synthesis of mullite at low temperature and research of transparency of mullite ceramic[D]. Wuhan: Wuhan University of Technology, 2010.
43	孟彬, 彭金辉, 刘永鹤, 等. 微波冶金用堇青石莫来石耐火材料制备及性能[J]. 材料科学与工艺, 2011, 19(3): 32-36.
	MENG Bin, PENG Jinhui, LIU Yonghe, et al. Preparation and its properties of cordierite-mullite refractory material used in microwave metallurgy[J]. Materials Science and Technology, 2011, 19(3): 32-36.
44	刘永鹤. 原位合成莫来石晶须韧化微波冶金用刚玉-莫来石耐火材料的研究[D]. 昆明: 昆明理工大学, 2011.
	LIU Yonghe. Study on toughening corundum mullite refractories for microwave metallurgy by in situ synthesized mullite whiskers[D]. Kunming: Kunming University of Technology, 2011.
45	尚小标, 陈君若, 张伟峰, 等. 莫来石耐火材料在微波加热中的透波性能研究[J]. 材料导报, 2014, 28(10): 109-112.
	SHANG Xiaobiao, CHEN Junruo, ZHANG Weifeng, et al. Study on the wave-transparent property of mullite refractory layer in microwave heating[J]. Materials Review, 2014, 28(10): 109-112.
46	李光亚, 梁艳媛, 刘家臣, 等. 刚玉-莫来石多孔透波材料的制备及性能研究[J]. 稀有金属材料与工程, 2015, 44(S1): 43-46.
	LI Guangya, LIANG Yanyuan, LIU Jiachen,et al. Preparation of porous and wave-transmitting alumina-mullite materials and their properties[J]. Rare Metal Materials and Engineering, 2015, 44(S1): 43-46.
47	董萌蕾. 微波冶金用刚玉-氮化硅及莫来石-氮化硅复合材料的研制[D]. 郑州: 郑州大学, 2017.
	DONG Menglei. Research and preparation of corundum-silicon nitride and mullite-silicon nitride composites for microwave metallurgy[D]. Zhengzhou: Zhengzhou University, 2017.
48	胡连成, 黎义, 于翘. 俄罗斯航天透波材料现状考察[J] . 宇航材料工艺, 1994, 24(1): 48-52.
	HU Liancheng, LI Yi, YU Qiao. Investigation on the current situation of wave transmission in Russian space[J]. Aerospace Materials & Technology, 1994, 24(1): 48-52.
49	曹海琳, 张杰, 黄玉东, 等. 磷酸铬铝高温透波材料的制备和性能研究[J]. 宇航材料工艺, 2004, 34(2): 29-32.
	CAO Hailin, ZHANG Jie, HUANG Yudong, et al. Study on synthesis and properties of heat-resistant electrically transparent chrome-alumina phosphate[J]. Aerospace Materials & Technology, 2004, 34(2): 29-32.
50	刘文娟. 晶须增强磷酸铝透波材料的研究[D]. 济南: 济南大学, 2010.
	LIU Wenjuan. Whisher reinforced wave-transparents materials[D]. Jinan: Jinan University, 2010.
51	陈宁. 原位生长莫来石增强磷酸铬铝高温透波材料的研究[D]. 北京: 中国建筑材料科学研究总院, 2014.
	CHEN Ning. Study on in-situ mullite reinforced aluminum-chrome phosphates high temperature wave-transparent composites[D]. Beijing: China General Research Institute of Building Materials, 2014.
52	耿浩然, 刘文娟, 侯宪钦, 等. 硼酸盐系晶须增强的磷酸铝陶瓷透波材料及其制备方法: CN 201010106994.7[P]. 2010-09-01.
	GENG Haoran, LIU Wenjuan, HOU Xianqin, et al. Borate whisker reinforced aluminum phosphate ceramic wave transparent material and its preparation method there of: CN 201010106994.7[P]. 2010-09-01.
53	WANG H, GENG H, LIU C. The influence of SiO₂ on the aluminum borate whisker reinforced aluminum phosphate wave-transparent materials[J]. Procedia Engineering, 2012, 27: 1222-1227.
54	王锋, 王继辉, 肖永栋. 磷酸铝系透波复合材料的力学性能与介电性能研究[J]. 宇航材料工艺, 2006, 36(6): 26-28.
	WANG Feng, WANG Jihui, XIAO Yongdong. The mechanical and dielectrical properties of aluminum phosphate matrix composite[J]. Aerospace Materials & Technology, 2006, 36(6): 26-28.
55	王河. 高性能磷酸铝基透波材料的制备及性能研究[D]. 济南: 济南大学, 2012.
	WANG He. Study and preparation of high performance aluminum phosphates wave-transparent materials[D]. Jinan: Jinan University, 2012.
56	李瑞波. 玻纤布增强聚四氟乙烯透波材料性能研究[D]. 郑州: 郑州大学, 2016.
	LI Ruibo. Research on properties of glass fibe fabric reinforced PTFE composites[D]. Zhengzhou: Zhengzhou University, 2016.
57	宋麦丽, 崔红, 杨星, 等. 高硅氧/有机硅透波材料性能研究[J]. 材料导报, 2009, 23(S1): 384-386.
	SONG Maili, CUI Hong, YANG Xing, et al. Study on properties of silica glass/silicone resin radome materials[J]. Materials Review, 2009, 23(S1): 384-386.
58	陈立瑶. 玻纤增强树脂基透波复合材料的制备及性能研究[D]. 郑州: 中原工学院, 2018.
	CHEN Liyao. Study on fabrication and properties of glass fiber reinforced resin wave-transparent composites[D]. Zhengzhou: Zhongyuan University of Technology, 2018.
59	胡艳志. 环氧树脂基透波复合材料制备与性能研究[D]. 武汉: 武汉理工大学, 2014.
	HU Yanzhi. Study on preparation and properties of epoxy-matrix wave-transparent composite[D]. Wuhan: Wuhan University of Technology, 2014.
60	RAJESH S, NISA V S, MURALI K P, et al. Microwave dielectric properties of PTFE/rutile nanocomposites[J]. Journal of Alloys and Compounds, 2009, 477(1/2): 677-682.
61	ESTEL L, POUX M, BENAMARA N, et al. Continuous flow-microwave reactor: where are we?[J]. Chemical Engineering and Processing, 2017, 113: 56-64.
62	LI Yingguang, CHENG Libing, ZHOU Jing, Curing multidirectional carbon fiber reinforced polymer composites with indirect microwave heating[J]. The International Journal of Advanced Manufacturing Technology, 2018, 97(1/2/3/4): 1137-1147.
63	CASTILLEJO N, MARTÍNEZ-HERNÁNDEZ G B, LOZANO-GUERRERO A J, et al. Microwave heating modelling of a green smoothie: effects on glucoraphanin, sulforaphane and S-methyl cysteine sulfoxide changes during storage[J]. Journal of the Science of Food and Agriculture, 2018, 98(5): 1863-1872.
64	范景莲, 黄伯云, 刘军, 等. 微波烧结原理与研究现状[J]. 粉末冶金工业, 2004, 14(1): 29-33.
	FAN Jinglian, HUANG Baiyun, LIU Jun, et al. Principles and status of microwave sintering[J]. Powder Metallurgy Industry, 2004, 14(1): 29-33.
65	殷增斌, 徐伟伟, 汪家傲, 等. 一种陶瓷材料微波烧结用保温装置: CN 201710263010.8[P]. 2019-10-18.
	YIN Zengbin, XU Weiwei, WANG Jia,ao, et al. Thermal insulation device for microwave sintering of ceramic material: CN 1710263010.8[P]. 2019-10-18.
66	盛新太. 用于高温管线、设备保温的新型绝热节能材料——陶瓷纤维覆铝箔针刺毯[J]. 化工设备与管道, 2007, 44(5): 59-62.
	SHENG Xintai. A new energy-saving insulator material used in high temperature pipeline and vessel—Ceramic fiber blanket with aluminum foil[J]. Process Equipment & Piping, 2007, 44(5): 59-62.
67	李呈顺, 张玉军, 张景德. 溶胶凝胶法制备多晶莫来石纤维[J]. 无机材料学报, 2009, 24(4): 848-852.
	LI Chengshun, ZHANG Yujun, ZHANG Jingde. Polycrystalline mullite fibers prepared by sol-gel method[J]. Journal of Inorganic Materials, 2009, 24(4): 848-852.
68	SHANG X B, ZHAI D, LIU M H, et al. Dielectric properties and electromagnetic wave transmission performance of aluminium silicate fibreboard at 915MHz and 2450MHz[J]. Ceramics International, 2021, 47(6): 7539-7557.
69	WANG S, ZHAO C S, WANG D Q, et al. Preparation of refractory fiber cardboard for building insulation[J]. Applied Mechanics and Materials, 2013, 357/358/359/360: 1295-1299.
70	MECHNICH P, FLUCHT F, SCHMÜCKER M. Manufacturing of porous mullite fiber compacts by uniaxial hot pressing of semicrystalline MAFTEC^® MLS-2 organic bound mats[J]. Journal of Materials Research, 2017, 32(17): 3294-3301.

[1]	WEI Cong, SHANG Xiaobiao, ZHANG Fucheng, LIU Meihong, BAI Yongzhen, LI Guangchao, XIAO Liping, Di ZHAI, CHEN Junruo. Transmission properties of polytetrafluoroethylene container for microwave chemical reaction [J]. Chemical Industry and Engineering Progress, 2021, 40(7): 3862-3869.
[2]	WEN Jiaxin, ZHANG Xin, LIU Yunxia, HE Zhiqiang, QU Qichao. Preparation and performance of smart anti-corrosion coating based on nanocontainers of BTA@MSNs-PAA [J]. Chemical Industry and Engineering Progress, 2021, 40(5): 2685-2694.
[3]	Huanlei ZHANG, Lisheng CHENG, Zhenghe ZHANG, Jing TAN, Weimin YANG, Ying AN. Insights into the distribution regularity of temperature and thermal stress for the co-heating process of carbon fibers via laser and microwave [J]. Chemical Industry and Engineering Progress, 2020, 39(S1): 195-199.
[4]	XING Qingda, ZHOU Liang, LI Huazheng, WANG Jinqu, ZHANG Wenjun. Preparation and desalination performance of high quality NaA zeolite membrane [J]. Chemical Industry and Engineering Progress, 2017, 36(11): 4170-4175.
[5]	MENG Lingjia, JI Zhonghai, CHEN Jin. Advance of the thermal decomposition of industrial by-product gypsum [J]. Chemical Industry and Engineering Progree, 2017, 36(02): 626-633.
[6]	YANG Zhaozhong, ZHU Jingyi, LI Xiaogang, LUO Dan. Progress in researches on microwave heating in unconventional oil resources [J]. Chemical Industry and Engineering Progress, 2016, 35(11): 3478-3483.
[7]	JI Zhonghai, CHEN Jin, GUO Yu, GUO Lina, QIN Li, MENG Lingjia. Decomposition of flue gas desulfurization (FGD) gypsum under microwave heating to produce sinter ore [J]. Chemical Industry and Engineering Progree, 2016, 35(07): 2251-2257.
[8]	LUO Wanjiang, LAN Xinzhe, SONG Yonghui. Release of gaseous products in oil shale pyrolysis by microwave heating [J]. Chemical Industry and Engineering Progree, 2015, 34(3): 689-694.
[9]	SHANG Hui，LU Ranran，CHEN Yu. Microwave-assisted synthesis of naphthalenetetracarboxylic acid and o-phenylenediamine [J]. Chemical Industry and Engineering Progree, 2011, 30(8): 1832-.
[10]	WANG Wanfu1，LI Guo2，YONG Xingyue2，LIU Peng1，ZHANG Xiaofei1，WANG Jidong2. Microwave thermal inversion of oily sludge by programmed temperature increasing [J]. Chemical Industry and Engineering Progree, 2011, 30(10): 2310-.
[11]	ZHAO Xiqiang，SONG Zhanlong，WANG Tao，LI Longzhi，MA Chunyuan. Progress of pyrolysis using microwave heating technique [J]. Chemical Industry and Engineering Progree, 2008, 27(12): 1873-.