Application of electrospinning and electrospray technology in battery/cell field

doi:10.16085/j.issn.1000-6613.2020-2080

Abstract

Abstract:

Among various methods for preparing nanomaterials, electrostatic spinning (electrospinning) and electrostatic spraying (electrospray) technologies have opened up low-cost, simple, and efficient routes for continuous nanofiber manufacturing in the past decades, which have attracted widespread attentions from numerous researchers. Therefore, this paper introduced the basic theory, the affecting parameters and the categories and characteristics of various electrospinning and electrospray technologies, including solution electrospinning, melt electrospinning, gas-assisted electrospinning, emulsion electrospinning, coaxial electrospinning, multi-jet electrospinning and needleless electrospinning. Furthermore, this work introduced the technical advantages of electrospinning and electrospray strategies, as well as their frontier applications in energy storage field, especially in lithium ion batteries, fuel cells, solar cells and supercapacitors. Finally, the challenges and development prospects of the electrospinning and electrospray technologies were forecasted.

Key words: electrospinning, nanomaterial, nanotechnology, nanostructure, application

摘要：

在制备纳米材料的各种方法中，静电纺丝和静电喷雾技术在过去数十年中开辟了低成本、简便、高效和可连续的纳米纤维制造技术路线，引起了科研工作者的广泛关注。本文介绍了静电纺丝和静电喷雾技术的基本原理、影响参数及种类（溶液静电纺丝、熔融静电纺丝、气流静电纺丝、乳液静电纺丝、同轴静电纺丝、多喷嘴静电纺丝和无针静电纺丝），并阐明了不同静电纺丝技术种类的原理及特点。文章进一步着重介绍了静电纺丝和静电喷雾技术的优势及其在电池领域的前沿应用，特别是在锂离子电池、燃料电池、太阳能电池及超级电容器的应用，最后展望了静电纺丝和静电喷雾先进制造技术面临的挑战和发展前景。

关键词: 静电纺丝, 纳米材料, 纳米技术, 纳米结构, 应用

CLC Number:

TQ340.64

DENG Jianhui, YANG Xiaoqing, FANG Chenghui, CAO Dongqing, LI Liangjun, ZHANG Guoqing, GUO Jianwei. Application of electrospinning and electrospray technology in battery/cell field[J]. Chemical Industry and Engineering Progress, 2021, 40(10): 5600-5614.

邓建辉, 杨晓青, 方称辉, 曹栋清, 李梁君, 张国庆, 郭建维. 静电纺丝/静电喷雾技术在电池领域的应用进展[J]. 化工进展, 2021, 40(10): 5600-5614.

Figures/Tables 11

References 110

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溶液参数	工艺参数	环境参数
聚合物溶液浓度	外加电压	温度
聚合物分子量	纺丝距离	湿度
溶液黏度	纺丝速率	压强
电导率	针管内径
表面张力	收集器类型

溶液参数	工艺参数	环境参数
聚合物溶液浓度	外加电压	温度
聚合物分子量	纺丝距离	湿度
溶液黏度	纺丝速率	压强
电导率	针管内径
表面张力	收集器类型

[1]	HU Xi, WANG Mingshan, LI Enzhi, HUANG Siming, CHEN Junchen, GUO Bingshu, YU Bo, MA Zhiyuan, LI Xing. Research progress on preparation and sodium storage properties of tungsten disulfide composites [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 344-355.
[2]	XU Chunshu, YAO Qingda, LIANG Yongxian, ZHOU Hualong. Research progress on functionalization strategies of covalent organic frame materials and its adsorption properties for Hg(Ⅱ) and Cr(Ⅵ) [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 461-478.
[3]	YANG Ying, HOU Haojie, HUANG Rui, CUI Yu, WANG Bing, LIU Jian, BAO Weiren, CHANG Liping, WANG Jiancheng, HAN Lina. Coal tar phenol-based carbon nanosphere prepared by Stöber method for adsorption of CO₂ [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 5011-5018.
[4]	MAO Shanjun, WANG Zhe, WANG Yong. Group recognition hydrogenation: From concept to application [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 3917-3922.
[5]	YIN Xinyu, PI Pihui, WEN Xiufang, QIAN Yu. Application of special wettability materials for anti-hydrate-nucleation and anti-hydrate-adhesion in oil and gas pipelines [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4076-4092.
[6]	SUN Xudong, ZHAO Yuying, LI Shirui, WANG Qi, LI Xiaojian, ZHANG Bo. Textual quantitative analysis on China’s local hydrogen energy development policies [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3478-3488.
[7]	XU Peiyao, CHEN Biaoqi, KANKALA Ranjith Kumar, WANG Shibin, CHEN Aizheng. Research progress of nanomaterials for synergistic ferroptosis anticancer therapy [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3684-3694.
[8]	JIN Yong, CHENG Yi, BAI Dingrong, ZHANG Chenxi, WEI Fei. Fluidization research and development in China [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 2761-2780.
[9]	XU Chunshu, YAO Qingda, LIANG Yongxian, ZHOU Hualong. Effects of graphene oxide/carbon nanotubes on the properties of several typical polymer materials [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 3012-3028.
[10]	XU Guobin, LIU Honghao, LI Jie, GUO Jiaqi, WANG Qi. Preparation and properties of ZnO QDs water-based inkjet fluorescent ink [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 3114-3122.
[11]	ZHANG Chenyu, WANG Ning, XU Hongtao, LUO Zhuqing. Performance evaluation of the multiple layer latent heat thermal energy storage unit combined with nanoparticle for heat transfer enhancement [J]. Chemical Industry and Engineering Progress, 2023, 42(5): 2332-2342.
[12]	FU Shurong, WANG Lina, WANG Dongwei, LIU Rui, ZHANG Xiaohui, MA Zhanwei. Oxygen evolution cocatalyst enhancing the photoanode performances for photoelectrochemical water splitting [J]. Chemical Industry and Engineering Progress, 2023, 42(5): 2353-2370.
[13]	CHEN Shaohua, WANG Yihua, HU Qiangfei, HU Kun, CHEN Li’ai, LI Jie. Research progress on detection of Cr(Ⅵ) by electrochemically modified electrode [J]. Chemical Industry and Engineering Progress, 2023, 42(5): 2429-2438.
[14]	YIN Ming, GUO Jin, PANG Jifeng, WU Pengfei, ZHENG Mingyuan. Deactivation mechanisms and stabilizing strategies for Cu based catalysts in reactions with hydrogen [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1860-1868.
[15]	GE Weitong, LIAO Yalong, LI Mingyuan, JI Guangxiong, XI Jiajun. Preparation and dechlorination kinetics of Pd-Fe/MWCNTs bimetallic catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(4): 1885-1894.