Chemical Industry and Engineering Progress ›› 2021, Vol. 40 ›› Issue (8): 4573-4586.DOI: 10.16085/j.issn.1000-6613.2020-2031

• Resources and environmental engineering • Previous Articles     Next Articles

Progress in preparation and application of lignin porous carbon

ZENG Maozhu1(), SHE Yuqi1(), HU Yubin1, WU Linjun1, YUAN Manjing1, QI Yi1, WANG Huan2, LIN Xuliang1, QIN Yanlin1()   

  1. 1.School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, Guangdong, China
    2.School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, Guangdong, China
  • Received:2020-10-09 Online:2021-08-12 Published:2021-08-05
  • Contact: QIN Yanlin

木质素多孔炭的制备及应用研究进展

曾茂株1(), 佘煜琪1(), 胡玉彬1, 吴林军1, 袁慢景1, 漆毅1, 王欢2, 林绪亮1, 秦延林1()   

  1. 1.广东工业大学轻工化工学院,广东 广州 510006
    2.华南理工大学化学与化工学院,广东 广州 510641
  • 通讯作者: 秦延林
  • 作者简介:曾茂株(1997—),男,硕士研究生,研究方向为木质素高值化利用。E-mail:a635784589@163.com|佘煜琪(1998—),女,硕士研究生,研究方向为木质素高值化利用。E-mail:syq31717@163.com
  • 基金资助:
    广东省自然科学基金(2019B151502038);国家自然科学基金(22078069)

Abstract:

Lignin is a kind of natural polymer with three-dimensional network structure, large amount of aromatic groups and high carbon content. It has great potential in the field of preparation of porous carbon materials. Porous carbon materials have a great application prospect in the field of catalyst and the energy storage. Industrial lignin, as a byproduct from the pulp and paper and biological refining industry, is used to prepare porous carbon and used in energy storage, adsorption, catalyst carrier and other field, which can realize the high-valued recycling utilization of industrial lignin. This paper summarized the current lignin commonly used preparation methods of porous carbon materials and micro channel structure adjustment methods, and summarized the main characteristics of the various preparation methods, as well as the key factors affecting on the structure and performance of lignin-derived porous carbon materials. It focused on the research on pore control of lignin-derived porous carbon materials in recent years and summarized the pore regulation methods. Taking supercapacitors, adsorbents and catalyst carriers as representatives, the application status of lignin porous carbon materials in the field of catalysis and energy storage materials was reviewed, and the microstructure characteristics of lignin-derived porous carbon materials were discussed. The opportunities and challenges of lignin in the preparation and application of porous carbon were summarized and prospected.

Key words: lignin, porous carbon, channel regulation, energy storage material, adsorbent, catalyst support

摘要:

木质素是一种具有三维网状分子结构、含有大量芳香基团和高含碳量等特点的天然高分子,其在制备多孔炭领域具有巨大潜力。多孔炭在催化剂和能源储存领域具有极大的应用前景。以来源于制浆造纸和生物炼制行业的副产物工业木质素作为原料制备多孔炭应用于能源储存、吸附、催化剂载体等领域,可实现工业木质素在碳基功能材料领域的高附加值循环再利用。本文详细综述了目前木质素多孔炭的常用制备方法和微结构特性的调控方法,总结归纳了各制备方法的主要特点以及影响木质素多孔炭微结构与性能的关键因素;重点综述了近些年对木质素多孔炭孔道结构调控方面的研究,归纳了孔调控的方法;此外,总结了木质素多孔炭在超级电容器、锂离子电池、吸附剂和催化剂载体领域中的应用研究现状,讨论了催化和储能材料对木质素多孔炭的微结构特性要求。总结并展望了木质素多孔炭在制备与应用中面临的机遇和挑战。

关键词: 木质素, 多孔炭, 孔道调控, 储能材料, 吸附剂, 催化剂载体

CLC Number: 

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