Chemical Industry and Engineering Progress ›› 2020, Vol. 39 ›› Issue (S1): 153-162.DOI: 10.16085/j.issn.1000-6613.2020-0260

• Industrial catalysis • Previous Articles     Next Articles

Research progress on reaction mechanism and catalysts for catalytic hydrodeoxygenation(HDO) of biomass oil

Caixia LIAN1,2(), Ning LI1(), Wu JIANG1, Hao MA1, Han PENG1,2   

  1. 1.College of Chemical Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, Guangdong, China
    2.College of Chemical Engineering, Xiangtan University, Xiangtan 410001, Hunan, China
  • Received:2020-02-24 Online:2020-06-29 Published:2020-05-20
  • Contact: Ning LI

生物质油催化加氢脱氧(HDO)反应机理及催化剂研究进展

练彩霞1,2(), 李凝1(), 蒋武1, 马浩1, 彭瀚1,2   

  1. 1.广东石油化工学院化学工程学院,广东 茂名 525000
    2.湘潭大学化学工程学院,湖南 湘潭 410001
  • 通讯作者: 李凝
  • 作者简介:练彩霞(1995—),女,硕士研究生,研究方向为催化材料与多相催化技术。E-mail:854519415@qq.com
  • 基金资助:
    广东省重大基础研究项目(2017KZDXM057)

Abstract:

In this paper, the research progress on the preparation, catalytic performance and reaction mechanism of biomass oil catalytic hydrodeoxygenation catalysts in recent years are summarized. The preparation methods, catalytic performance and mechanism of noble metal catalysts, transition metal catalysts and sulfides, carbides, nitrides, phosphide catalysts were mainly discussed. The reasons for the deactivation of the hydrodeoxygenation catalyst were analyzed, and the future development of the biomass oil hydrodeoxygenation catalysts was also proposed: the application of three-dimensional ordered mesoporous (3DOM) perovskite oxide may play a role in improving the catalytic performance of the catalyst.

Key words: biomass oil, hydrodeoxygenation, catalyst, reaction mechanism, deactivation, perovskite oxide

摘要:

对近年来生物质油催化加氢脱氧催化剂的制备、催化性能和反应机理的研究进展进行了整理总结。重点对贵金属催化剂、过渡金属催化剂和硫、氮、碳、磷等金属化合物催化剂的制备方法、催化性能和作用机理进行了概述,并分析了加氢脱氧催化剂的失活原因,同时提出生物质油加氢脱氧反应催化剂的未来发展方向:三维有序大孔(3DOM)钙钛矿氧化物的应用可能在提高催化剂的催化性能有作用。

关键词: 生物质油, 加氢脱氧, 催化剂, 反应机理, 失活, 钙钛矿氧化物

CLC Number: 

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