Chemical Industry and Engineering Progress ›› 2019, Vol. 38 ›› Issue (07): 3088-3096.DOI: 10.16085/j.issn.1000-6613.2018-1983
• Energy processes and technology • Previous Articles Next Articles
Haiying WANG1,2(),Hongjing HAN1,2,Hua SONG1,2,Enhao SUN3,Yanan ZHANG1,2,Yanguang CHEN1,2(),Hongzhi ZHAO1,2,Jinxin LI1,2,Yue KANG1,2
Received:
2018-10-08
Online:
2019-07-05
Published:
2019-07-05
Contact:
Yanguang CHEN
王海英1,2(),韩洪晶1,2,宋华1,2,孙恩浩3,张亚男1,2,陈彦广1,2(),赵宏志1,2,李金鑫1,2,康越1,2
通讯作者:
陈彦广
作者简介:
王海英(1990—),女,博士研究生,研究方向为催化材料合成及生物质资源化利用。E-mail:<email>wanghaiying1990@126.com</email>。
基金资助:
CLC Number:
Haiying WANG, Hongjing HAN, Hua SONG, Enhao SUN, Yanan ZHANG, Yanguang CHEN, Hongzhi ZHAO, Jinxin LI, Yue KANG. Progress in pyrolysis of lignin and its model compounds[J]. Chemical Industry and Engineering Progress, 2019, 38(07): 3088-3096.
王海英, 韩洪晶, 宋华, 孙恩浩, 张亚男, 陈彦广, 赵宏志, 李金鑫, 康越. 木质素及其模型化合物热解研究进展[J]. 化工进展, 2019, 38(07): 3088-3096.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2018-1983
模型化合物 | 化学键 变化 | ΔE /kJ·mol-1 | 主要产物 | 参考文献 |
---|---|---|---|---|
| Cβ―O 均裂 | 221.4 | , | [ |
Cα―Cβ 均裂 | 259.3 | ,,含羰基类物质 | ||
Cβ―O 协同反应 | 264.4 | ,,小分子产物 | ||
| Cβ―O 均裂 | 245.3 | ,,,, | [ |
Cα―Cβ 均裂 | 259.2 | ,,,,, | ||
协同反应 | >300 | ,,,CH2O,CH4 | ||
| Cβ―O 裂解 | 228.0 | ,,,CH3CH2OH | [ |
Cα―Cβ 裂解 | 241.1 | ,,CH3CH2OH | ||
| Cβ―O 均裂 | 230.6 | ,,,,,C2H2 | [ |
Cα―Cβ 均裂 | 292.5 | — | ||
协同反应 1 | 247.6 | ,, | ||
协同反应 2 | 274.8 | ,,,,H2C=CHOH |
模型化合物 | 化学键 变化 | ΔE /kJ·mol-1 | 主要产物 | 参考文献 |
---|---|---|---|---|
| Cβ―O 均裂 | 221.4 | , | [ |
Cα―Cβ 均裂 | 259.3 | ,,含羰基类物质 | ||
Cβ―O 协同反应 | 264.4 | ,,小分子产物 | ||
| Cβ―O 均裂 | 245.3 | ,,,, | [ |
Cα―Cβ 均裂 | 259.2 | ,,,,, | ||
协同反应 | >300 | ,,,CH2O,CH4 | ||
| Cβ―O 裂解 | 228.0 | ,,,CH3CH2OH | [ |
Cα―Cβ 裂解 | 241.1 | ,,CH3CH2OH | ||
| Cβ―O 均裂 | 230.6 | ,,,,,C2H2 | [ |
Cα―Cβ 均裂 | 292.5 | — | ||
协同反应 1 | 247.6 | ,, | ||
协同反应 2 | 274.8 | ,,,,H2C=CHOH |
相同点 | 不同点 |
---|---|
①在初次裂解时,侧链的烷基醚键最先断裂,然后是Cα―Cβ键的断裂,而其他链接键的断裂则相对较难 ②可能的最终产物都是苯酚及其取代物,且都伴随有小分子生成 | ①生成的小分子物质的种类往往有很大差别 ②β-O-4型模型化合物的热解产物中可出现对位取代基中含有不饱和羰基的物质,在α-O-4型模型化合物的热解产物中很少出现 |
相同点 | 不同点 |
---|---|
①在初次裂解时,侧链的烷基醚键最先断裂,然后是Cα―Cβ键的断裂,而其他链接键的断裂则相对较难 ②可能的最终产物都是苯酚及其取代物,且都伴随有小分子生成 | ①生成的小分子物质的种类往往有很大差别 ②β-O-4型模型化合物的热解产物中可出现对位取代基中含有不饱和羰基的物质,在α-O-4型模型化合物的热解产物中很少出现 |
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