Progress on acrylic pressure sensitive adhesive with high temperature resistance

doi:10.16085/j.issn.1000-6613.2018-1847

Abstract

Abstract:

Acrylic pressure sensitive adhesives (APSA) have many advantages, such as excellent adhesion strength, good aging resistance, well stability, low-cost, and easy preparation. They are used in a broad range of fields, including self-adhesive tape, labels, pharmaceuticals, homecare and auto parts. However, the poor heat resistance of the APSA has always limited their further applications at higher temperatures. Therefore, it is of great significance to research the APSA with high temperature resistance (HTRAPSA). In this work, recent advances in improving both solvent-based and waterborne HTRAPSA were reviewed, and several major modification methods for HTRAPSA including crosslinking, introducing modified monomers and heat-resistant materials, improving feed-type and polymerization process, blending were stated, as well as the shortcomings and the existing problems of those modification methods for HTRAPSA were discussed. Finally, the future development of HTRAPSA was prospected.

Key words: high temperature resistance, pressure sensitive adhesive, acrylate, modification

摘要：

丙烯酸酯类压敏胶（APSA）具有粘接性能优异、耐老化性能好、成本低、性能稳定、合成工艺简单等优点，由于其优异的性能被广泛应用于自黏带、标签、医药、家庭护理、汽车零部件等领域。但目前APSA应用领域仍较窄，大多数产品耐热性较差，不能在高温条件下使用。因此，开发耐高温性能的压敏胶（HTRAPSA）具有重要意义。文章综述了近年来国内外对HTRAPSA的研究进展，重点阐述了提高溶剂型和乳液型APSA耐高温性的相关研究工作。主要改性方法包括引入交联剂改性、引入特殊的改性单体、引入耐高温性物质改性和改进加料方式、聚合工艺、共混改性等方法来提高APSA的耐高温性能。同时，也指出了这些改性方法存在的问题与不足，以及所制备出的HTRAPSA存在的问题，并对今后相关研究的发展进行了展望。

关键词: 耐高温, 压敏胶, 丙烯酸酯, 改性

CLC Number:

TQ436.3

Daohuan LU, Bin WANG, Yuewen HUANG. Progress on acrylic pressure sensitive adhesive with high temperature resistance[J]. Chemical Industry and Engineering Progress, 2019, 38(05): 2269-2275.

鲁道欢, 王斌, 黄月文. 耐高温丙烯酸酯类压敏胶的研究进展[J]. 化工进展, 2019, 38(05): 2269-2275.

Figures/Tables 2

References 50

1	Istvan BENEDEK , FELDSTEIN Mikhail M . Hand book of pressure sensitive adhesives and products[M]. Boca Raton: CRC Press, 2008:1100.
2	FELDSTEIN Mikhail M , DORMIDONTOVA Elena E , KHOKHLOV Alexei R .Pressure sensitive adhesives based on interpolymer complexes[J]. Progress in Polymer Science, 2015,42:79-153.
3	FANG Cheng , LIN Zhongxiang . Effect of propyleneimine external cross-linker on the properties of acrylate latex pressure sensitive adhesives[J]. International Journal of Adhesion and Adhesives, 2015,61:1-7.
4	FANG Cheng , JING Yi , ZONG Yajun , et al . Effect of N,N-dimethylacrylamide (DMA) on the comprehensive properties of acrylic latex pressure sensitive adhesives[J]. International Journal of Adhesion and Adhesives, 2016,71:105-111.
5	Zbigniew CZECH , Marta WOJCIECHOWICZ . The crosslinking reaction of acrylic PSA using chelate metal acetylacetonates[J]. European Polymer Journal, 2006, 42(9):2153-2160.
6	刘文仓, 王磊 . 交联方式对丙烯酸酯压敏胶性能的影响[J]. 化学与黏合, 2016,37(5):339-342.
	LIU Wencang , WANG Lei . The effect of crosslinking methods on the performance of acrylate pressure sensitive adhesive[J]. Chemistry and Adhesion,2015,37(5):339-342.
7	CZECH Z , KABATC J , RAGAŃSKA P , et al . 2-Methylbenzothiazolium derivatives as cationic photoreactive crosslinker for acrylic pressure-sensitive adhesives containing oxirane groups from glycidyl methacrylate[J]. International Journal of Adhesion and Adhesives, 2018,80:39-42.
8	Junghun LEE , Taehyung LEE , SHIM Kyu Sung, et al . Effect of crosslinking density on adhesion performance and flexibility properties of acrylic pressure sensitive adhesives for flexible display applications[J]. International Journal of Adhesion and Adhesives, 2017,74:137-143.
9	Hiroto MURAKAMI , Keisuke FUTASHIMA , Minoru NANCHI , et al . Unique thermal behavior of acrylic PSAs bearing long alkyl side groups and crosslinked by aluminum chelate[J]. European Polymer Journal, 2011,47(3):378-384.
10	ZHANG Xiaowen , DING Yuting , ZHANG Guanli , et al . Preparation and rheological studies on the solvent based acrylic pressure sensitive adhesives with different crosslinking density[J]. International Journal of Adhesion and Adhesives, 2011,31(7):760-766.
11	陈平绪, 叶南飚, 王林, 等 . 耐高温丙烯酸酯乳液压敏胶的固化及性能研究[J]. 化学与黏合, 2015,37(4):264-267.
	CHEN Pingxu , YE Nanbiao , WANG Lin ,et al . Study on the curing and property of acrylate emulsion pressure sensitive adhesive with high temperature resistance[J]. Chemistry and Adhesion,2015,37(4):264-267.
12	尉晓丽, 傅和青, 赖婉婷, 等 . 耐高温丙烯酸酯压敏胶的合成[J]. 高分子材料科学与工程, 2013,29(1):5-9.
	WEI Xiaoli , FU Heqing , LAI Wanting , et al . Synthesis of polyacrytate pressure-sensitive adhesive with high temperature resistance[J]. Polymer Materials Science & Engineering,2013,29(1):5-9.
13	钟宏, 刘卓霖, 邱燕平, 等 . 溶剂型耐高温、耐电解液丙烯酸酯压敏胶粘带的制备[J]. 粘接, 2017(10):55-58.
	ZHONG Hong , LIU Zhuolin , QIU Yanping , et al . Preparation of a solvent based acrylic pressure-sensitive adhesive tape with resistance to high temperature and electrolyte[J]. Adhesion,2017(10):55-58.
14	张蕊, 张云飞, 梁利岩,等 . 外交联型丙烯酸酯乳液压敏胶的制备与性能[J]. 精细化工, 2013,30(7):798-804.
	ZHANG Rui , ZHANG Yunfei , LIANG Liyan , et al . Synthesis and properties of post cross-linked acrylic emulsion pressure sensitive adhesive[J]. Fine Chemicals,2013,30(7):798-804.
15	LU Deping , XIE Jin , SHEN Ling , et al . Role of three different carboxylic monomers in acrylate emulsion copolymerization in the presence of reactive emulsifier[J]. Journal of Applied Polymer Science, 2012,125(4):2807-2813.
16	FANG Cheng , YAN Qiming , LIU Zhuangzhuang , et al . The influence of monobutyl itaconate and β-carboxyethyl acrylate on acrylic latex pressure sensitive adhesives[J]. International Journal of Adhesion and Adhesives, 2018,84:387-393.
17	LU Xingchen , CAO Gang , NIU Zhengfa , et al . Viscoelastic and adhesive properties of single-component thermo-resistant acrylic pressure sensitive adhesives[J]. Journal of Applied Polymer Science, 2014,131(7): 1-10.
18	Kyungyul BAE , Donghyuk LIM , Jiwon PARK , et al . Adhesion performance and thermal stability of fluorinated PSAs as a crosslinking system[J]. Journal of Adhesion Science and Technology, 2012,26(1/2/3):361-379.
19	WANG Yu , LONG Jun , BAI Yongping , et al . Thermal stability and surface properties of acrylic PSAs modified by hexafluorobutyl acrylate[J]. Journal of Adhesion Science and Technology, 2015, 30(3):300-312.
20	张晓勇 . 耐高温溶剂型丙烯酸酯压敏胶的研究[D]. 哈尔滨: 哈尔滨工业大学, 2017.
	ZHANG Xiaoyong . Study on high temperature resistance solvent acrylate pressure sensitive adhesive[D]. Harbin: Harbin Institute of Technology,2017.
21	张绪刚, 李坚辉, 张斌, 等 . 高强度耐热丙烯酸酯压敏胶研究Ⅱ——结构与性能研究[J]. 化学与黏合, 2012,34(6):19-21.
22	ZHANG Xugang ， LI Jianhui ， ZHANG Bin ,et al . Study on polyacrylate pressure sensitive adhesive with high strength and heat resistant properties Ⅱ—— study on structure and properties [J]. Chemistry and Adhesion, 2012,34(6):19-21.
23	GUO Longhai , JIANG Sijiu , QIU Teng , et al . Miniemulsion polymerization of fluorinated siloxane-acrylate latex and the application as waterborne textile finishing agent[J]. Journal of Applied Polymer Science, 2014,131(8):24-27.
24	YU Yitao , WANG Jing . Synthesis and properties of block and graft waterborne polyurethane modified with α,ω-bis［3-(1-methoxy-2-hydroxypropoxy) propyl］ polydimethylsiloxane and α-N,N-dihydroxyethylaminopropyl-ω-butylpolydimethylsiloxane[J]. Polymer Engineering & Science,2014,54(4):805-811.
25	顾静 . 耐高温丙烯酸酯压敏胶的研究[D]. 哈尔滨: 哈尔滨工业大学, 2011.
	GU Jing . Study on high temperature resistant acrylate pressure sensitive adhesive[D]. Harbin: Harbin Institute of Technology,2011.
26	郑艳菊, 王素娟, 王继英, 等 . 丙烯酸酯/SBS共聚物的合成及性能研究[J]. 化学与黏合, 2007,29(2):105-107.
	ZHENG Yanju , WANG Sujuan , WANG Jiying ,et al . Study on the synthesis and properties of acrylate/SBS copolymers[J].Chemistry and Adhesion,2007,29(2):105-107.
27	梁建锋, 杨青芳, 张爱军, 等 . 有机硅改性丙烯酸酯乳液压敏胶的研究进展[J]. 中国胶黏剂, 2007,16(11):39-44.
	LIANG Jianfeng , YANG Qingfang , ZHANG Aijun ，et al . The progress on organic silicone modified acrylate polymer emulsion used to pressure-sensitive adhesive[J]. China Adhesives, 2007,16(11):39-44.
28	CHEN Junhua , ZHAO Qiang , WANG Ying , et al . Improvement in mechanical properties and thermal stability of solvent-based pressure-sensitive adhesives based on triazine heterocyclic monomer[J]. Journal of Applied Polymer Science, 2016,133(15):1-8.
29	LI Pengjuan , Fuwei NIAN , ZHANG Min , et al . Siloxane-modified polyacrylate low-residual pressure-sensitive adhesive with high peeling strength [J]. Journal of Applied Polymer Science, 2016,133(8):1-9.
30	赵明, 张绪刚, 张雪, 等 . 硅树脂改性丙烯酸酯压敏胶的耐老化性能及耐温性能研究[J]. 化学与黏合, 2015,37(2):103-106.
	ZHAO Ming , ZHANG Xugang , ZHANG Xue , et al . Study on the aging resistance and temperature tolerance of acrylate pressure-sensitive adhesive modified by silicone resin[J].Chemistry and Adhesion,2015,37(2):103-106.
31	尹朝辉, 潘慧铭, 吴伟卿, 等 . 新型硅改性丙烯酸酯压敏胶的研究[J]. 中国胶黏剂, 2002,12(6):16-19.
	YIN Zhaohui , PAN Huiming , WU Weiqing ,et al . Studies on MQ resins-modified polyacrylatepressure sensitive adhesives[J]. China Adhesives,2002,12(6):16-19.
32	张心亚, 涂伟萍, 陈焕钦 . 有机硅改性丙烯酸酯核-壳结构压敏胶聚合物乳液的研制[J]. 中国胶黏剂, 2003,12(2):1-4.
	ZHANG Xinya , TU Weiping , CHEN Huanqin . Preparation of core-shell organic siloxane modified acrylic emulsion for pressure-sensitive adhesive[J].China Adhesives, 2003,12(2):1-4.
33	郭亚昆, 王永明, 高之香,等 . 硅溶胶/聚丙烯酸酯乳液型压敏胶的制备与性能[J]. 粘接, 2009,30(8):46-49.
	GUO Yakun , WANG Yongming , GAO Zhixiang , et al . Preparation and characterization of core-shell polyacrylate/silica sol composite latexes and their pressure-sensitive adhesive properties[J]. Adhesion, 2009,30(8):46-49.
34	张涛辉, 伍平 . 一种丙烯酸酯压敏胶、压敏胶带及丙烯酸酯压敏胶的制备方法: CN107868639A[P].2017-12-06.
	ZHANG Huitao , WU Ping .A preparation method of acrylate pressure-sensitive adhesive,pressure-sensitive tape and acrylate pressure-sensitive adhesive:CN107868639A[P].2017-12-06.
35	赖婉婷 . 耐高温水性丙烯酸酯压敏胶的制备[D]. 广州: 华南理工大学, 2011.
	LAI Wanting . Preparation of heat-resistant aqueous acrylate pressure-sensitive adhesive[D]. Guangzhou: South China University of Technology,2011.
36	Aamer SAEED , Ghulam SHABIR , 王晓芳 . 耐热高光泽水性聚氨酯-聚丙烯酸酯共聚树脂的合成研究[J]. 中国印刷与包装研究,2014,6(2):66-71.
	Aamer SAEED , Ghulam SHABIR , WANG Xiaofang . Synthesis of thermally stable high gloss water dispersible polyureane/polyacrylate resins[J].China Printing and Packaging Study, 2014,6(2):66-71.
37	尉晓丽, 傅和青 . 改性水性丙烯酸酯压敏胶研究进展[J]. 化工进展, 2011,31(1):176-184.
	WEI Xiaoli ， FU Heqing . Progress in modification of waterborne acrylate pressure-sensitive adhesive[J]. Chemical Industry and Engineering Progress,2011,31(1):176-184.
38	FONSECA Gabriela E , MCKENNA Timothy F , DUBE´MARC A . Miniemulsion vs. conventional emulsion polymerization for pressure-sensitive adhesives production[J]. Chemical Engineering Science, 2010,65(9):2797-2810.
39	Aitziber LOPEZ , Elise DEGRANDI , Elisabetta CANETTA , et al . Simultaneous free radical and addition miniemulsion polymerization: effect of the diol on the microstructure of polyurethane-acrylic pressure-sensitive adhesives[J]. Polymer, 2011,52(14):3021-3030.
40	Ravindra UDAGAMA , Elise DEGRANDI-CONTRAIRES , Costantino CRETON , et al . Synthesis of acrylic-polyurethane hybrid latexes by miniemulsion polymerization and their pressure-sensitive adhesive applications[J]. Macromolecules, 2011,44(8):2632-2642.
41	张绪刚, 王磊, 张斌, 等 . 高强度耐热丙烯酸酯压敏胶研究Ⅰ——合成工艺研究[J]. 化学与黏合, 2012,34(5):30-32.
42	ZHANG Xugang , WANG Lei , ZHANG Bin , et al . Study on polyacrylate pressure sensitive adhesive with high strength and heat resistant properties Ⅰ-study on synthesis technology[J]. Chemistry and Adhesion, 2012,34(5):30-32.
43	何敏, 张秋禹, 程金奎, 等 . 保护膜用耐高温溶剂型丙烯酸酯压敏胶的研究[J]. 中国胶黏剂, 2006,15(12):35-38.
	HE Min , ZHANG Qiuyu , CHENG Jinkui , et al . Study on the heat resistance solvent based acrylic pressure-sensitive adhesive for protective film[J].China Adhesives,2006,15(12):35-38.
44	周明, 王迺昌 . 自交联型丙烯酸酯压敏胶的耐热性研究[J]. 中国胶黏剂, 1991(3):30-32.
	ZHOU Ming ， WANG Naichang . Study on the heat resistance of self-crosslinking acrylic pressure sensitive adhesive[J]. China Adhesives, 1991(3):30-32.
45	吴召洪, 陈建, 朱林英, 等 . 耐热溶剂型丙烯酸酯压敏胶的制备与性能[J]. 塑料, 2015,44(2):92-95.
	WU Zhaohong , CHEN Jian , ZHU Linying , et al . Preparation and performance of solvent acrylic pressure sensitive adhesive [J]. Plastics,2015,44(2):92-95.
46	陈未凤 . 纳米复合材料改性水性丙烯酸酯功能性压敏胶的研究[D]. 广州: 华南理工大学, 2016.
	CHEN Weifeng . Study on waterborne acrylic functional pressure sensitive adhesive modified by nanocomposite[D]. Guangzhou:South China University of Technology,2016.
47	ZHANG Yi , QI Shuhua , ZHANG Fan , et al . Preparation and magnetic properties of polymer magnetic composites based on acrylate resin filled with nickel plating graphite nanosheets[J].Applied Surface Science,2011,258(2):732-737.
48	ZHANG Fan , CHENG Bo , ZHU Wenfeng , et al . Preparation of Ag coating reduced graphene oxide and its application as a conductive filler to polyacrylate[J]. Journal of Materials Science: Materials in Electronics, 2017,28(19):14809-14817.
49	Jarmo KEMPPAINEN , Toni MATTILA , Mervi PAULASTO-KRÖCKEL . Adhesion evaluation of the heat resistant pressure sensitive adhesives at elevated temperatures for MEMS gyroscope testing[J].International Symposium on Advanced Packaging Materials,2011,27(3):363-372.
50	Seoho LEE , YOU Ryong , YOON Young Il, et al . Preparation and characterization of acrylic pressure-sensitive adhesives based on UV and heat curing systems[J]. International Journal of Adhesion and Adhesives, 2017,75:190-195.

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