Research progress of SO42-/MxOy solid superacid catalysts

doi:10.16085/j.issn.1000-6613.2017-1325

Abstract

Abstract: SO₄^2-/M_xO_y solid superacid catalysts have many advantages such as high activities,less pollution,no corrosion to reactor and easy recycle,so they are a type of typical eco-friendly catalysts. The effects of four preparation methods of impregnation,sol-gel,low-temperature aging and ultrasonic coprecipitation on the catalytic performance of the catalysts were discussed. The research progress in the modification of support and active component of SO₄^2-/M_xO_y solid superacid catalysts was reviewed. According to the structural model of solid superacid catalysts,the mechanism of acid formation of SO₄^2-/M_xO_y solid superacid was analyzed. The deactivation mechanism,characterization methods and some application examples of the catalysts were introduced. Finally,the structure theory and preparation technology of SO₄^2-/M_xO_y solid superacid catalysts were prospected.

Key words: solid superacid, catalyst, catalyst support, preparation, modification, application

摘要： SO₄^2-/M_xO_y型固体超强酸催化剂具有活性高、无污染、不腐蚀设备和可重复使用等优点，是一种典型的环境友好型催化剂。本文讨论了浸渍沉淀法、溶胶-凝胶法、低温陈化法和超声波共沉淀法4种制备方法对催化剂催化性能的影响。重点综述了SO₄^2-/M_xO_y型固体超强酸催化剂在载体和活性组分改性方面的研究进展。根据固体超强酸催化剂的结构模型，分析了SO₄^2-/M_xO_y型固体超强酸的成酸机理，介绍了催化剂的失活机理、表征手段以及在各个领域的应用实例，最后对SO₄^2-/M_xO_y型固体超强酸催化剂的结构理论和制备技术进行了展望。

关键词: 固体超强酸, 催化剂, 催化剂载体, 制备, 改性, 应用

CLC Number:

CHEN Huanzhang, ZHANG Yue, FENG Xue, SUN Zhaoli. Research progress of SO₄^2-/M_xO_y solid superacid catalysts[J]. Chemical Industry and Engineering Progress, 2018, 37(05): 1795-1803.

陈焕章, 张悦, 冯雪, 孙朝利. SO₄^2-/M_xO_y型固体超强酸催化剂的研究进展[J]. 化工进展, 2018, 37(05): 1795-1803.

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Research progress of SO₄^2-/M_xO_y solid superacid catalysts

SO₄^2-/M_xO_y型固体超强酸催化剂的研究进展

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[3]	XIE Luyao, CHEN Songzhe, WANG Laijun, ZHANG Ping. Platinum-based catalysts for SO₂ depolarized electrolysis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 299-309.
[4]	YANG Xiazhen, PENG Yifan, LIU Huazhang, HUO Chao. Regulation of active phase of fused iron catalyst and its catalytic performance of Fischer-Tropsch synthesis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 310-318.
[5]	WANG Jiaqing, SONG Guangwei, LI Qiang, GUO Shuaicheng, DAI Qingli. Rubber-concrete interface modification method and performance enhancement path [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 328-343.
[6]	CHEN Chongming, CHEN Qiu, GONG Yunqian, CHE Kai, YU Jinxing, SUN Nannan. Research progresses on zeolite-based CO₂ adsorbents [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 411-419.
[7]	WANG Lele, YANG Wanrong, YAO Yan, LIU Tao, HE Chuan, LIU Xiao, SU Sheng, KONG Fanhai, ZHU Canghai, XIANG Jun. Influence of spent SCR catalyst blending on the characteristics and deNO _x performance for new SCR catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 489-497.
[8]	DENG Liping, SHI Haoyu, LIU Xiaolong, CHEN Yaoji, YAN Jingying. Non-noble metal modified vanadium titanium-based catalyst for NH₃-SCR denitrification simultaneous control VOCs [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 542-548.
[9]	CHENG Tao, CUI Ruili, SONG Junnan, ZHANG Tianqi, ZHANG Yunhe, LIANG Shijie, PU Shi. Analysis of impurity deposition and pressure drop increase mechanisms in residue hydrotreating unit [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4616-4627.
[10]	ZHU Jie, JIN Jing, DING Zhenghao, YANG Huipan, HOU Fengxiao. Modification of CaSO₄ oxygen carrier by Zhundong coal ash in chemical looping gasification and its mechanism [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4628-4635.
[11]	WANG Jingang, ZHANG Jianbo, TANG Xuejiao, LIU Jinpeng, JU Meiting. Research progress on modification of Cu-SSZ-13 catalyst for denitration of automobile exhaust gas [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4636-4648.
[12]	WANG Peng, SHI Huibing, ZHAO Deming, FENG Baolin, CHEN Qian, YANG Da. Recent advances on transition metal catalyzed carbonylation of chlorinated compounds [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4649-4666.
[13]	GAO Yanjing. Analysis of international research trend of single-atom catalysis technology [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4667-4676.
[14]	ZHANG Qi, ZHAO Hong, RONG Junfeng. Research progress of anti-toxicity electrocatalysts for oxygen reduction reaction in PEMFC [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4677-4691.
[15]	GE Quanqian, XU Mai, LIANG Xian, WANG Fengwu. Research progress on the application of MOFs in photoelectrocatalysis [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4692-4705.