Chemical Industry and Engineering Progress ›› 2017, Vol. 36 ›› Issue (12): 4519-4523.DOI: 10.16085/j.issn.1000-6613.2017-0457

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Preparation of MoS2/graphene and its performance for anode materials of Li-ion battery

TAN Fengzhi1, ZHAO Yanru1,2, CAO Yafeng1, WANG Yuanhao1, SUN Yanfeng3   

  1. 1 School of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034, Liaoning, China;
    2 School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China:
    3 Zhejiang Jihua Group Limited, Hangzhou 311234, Zhejiang, China
  • Received:2017-03-20 Revised:2017-08-06 Online:2017-12-05 Published:2017-12-05

MoS2/石墨烯锂离子电池负极材料的制备及其性能

谭凤芝1, 赵艳茹1,2, 曹亚峰1, 汪源浩1, 孙岩峰3   

  1. 1 大连工业大学轻工与化学工程学院, 辽宁 大连 116034;
    2 上海交通大学化学化工学院, 上海 200240;
    3 浙江吉华股份有限公司, 浙江 杭州 311234
  • 通讯作者: 谭凤芝(1975-),女,硕士,副教授,研究方向为碳基材料的制备与应用。
  • 作者简介:谭凤芝(1975-),女,硕士,副教授,研究方向为碳基材料的制备与应用。E-mail:tanfz@dlpu.edu.cn。

Abstract: A facile solvothermal approach has been developed to fabricate graphene-based MoS2 composite,which used PVP decorated graphene as the carrier and sodium molybdate and thiourea as the starting materials. The structure and morphology of the composite were characterized by field-emission scanning electron microscope(FESEM),transmission electron microscope(TEM),X-ray diffractometer(XRD)and X-ray photoelectron spectrum(XPS)respectively. Electrochemical performances of the material were also evaluated. The result demonstrated that the usage of graphene as substrate can prevent the aggregation of MoS2 sheets and thus lead to adequate contact between the active material and the electrolyte. MoS2/graphene composite manifests superior reversible specific capacity(about 800mA·h/g,50 cycles)and excellent rate capability as anode materials in lithium-ion batteries.

Key words: molybdenum sulfide, graphene, composites, synthesis, electrochemistry

摘要: 以聚乙烯吡咯烷酮(PVP)修饰的氧化石墨烯(GO)为载体,钼酸钠(Na2MoO4)、硫脲[CS(NH22]作为前体,采用溶剂热合成方法制得石墨烯基硫化钼(MoS2)复合材料,通过场发射扫描电子显微镜(FESEM)、透射电子显微镜(TEM)、X射线衍射仪(XRD)、X射线光电子能谱(XPS)等对材料的结构和形貌进行表征,并对材料作电化学性能测试。结果表明:石墨烯作为载体可以阻止MoS2片层的团聚,使电解液与活性物质充分接触,进而提高活性物质的利用率。MoS2/石墨烯作为锂离子电池负极材料表现出良好的可逆比容量(约800mA·h/g,循环50次)和优异的倍率性能。

关键词: 硫化钼, 石墨烯, 复合材料, 合成, 电化学

CLC Number: 

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