Synthesis of Ni/Al2O3 catalysts by azeotropic distillation for hydrogenation of cinnamaldehyde

doi:10.16085/j.issn.1000-6613.2017-0220

Chemical Industry and Engineering Progress ›› 2017, Vol. 36 ›› Issue (12): 4468-4474.DOI: 10.16085/j.issn.1000-6613.2017-0220

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Synthesis of Ni/Al₂O₃ catalysts by azeotropic distillation for hydrogenation of cinnamaldehyde

QIN Jilong¹, WANG Fei¹, CAI Jinpeng¹, HU Jianheng¹, LIU Wenwen¹, JIANG Xingmao^1,2

School of Petrochemical and Engineering, Changzhou University, Changzhou 213164, Jiangsu, China;
2 School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430073, Hubei, China

Received:2017-02-14 Revised:2017-03-08 Online:2017-12-05 Published:2017-12-05

共沸蒸馏法制备Ni/Al₂O₃催化剂及其肉桂醛加氢反应性能

秦跻龙¹, 王非¹, 蔡金鹏¹, 胡建恒¹, 刘雯雯¹, 姜兴茂^1,2

1 常州大学石油化工学院, 江苏常州 213164;
2 武汉工程大学化工与制药学院, 湖北武汉 430073

通讯作者: 非,博士,讲师,研究方向为纳米催化剂的开发及应用研究;姜兴茂,博士,教授,研究方向为能源纳米材料。
作者简介:秦跻龙(1990-),男,硕士研究生,研究方向为纳米材料的制备及应用研究。E-mail:13775610275@163.com。
基金资助:
国家自然科学基金项目（21503023，21373034，U1463210）。

Abstract

Abstract: Highly dispersed nickel nanoparticles supported on Al₂O₃ catalysts were successfully prepared by azeotropic distillation assisted fabrication. The physical and chemical properties of the catalysts were characterized by XRD,TEM,N₂ sorption and BJH pore size analyses. Liquid phase selective hydrogenation of cinnamaldehyde was selected as model reactions to study the catalytic behavior of Ni/Al₂O₃ catalysts. In comparison with the catalysts prepared by impregnation,the catalysts prepared by azeotropic distillation assisted fabrication exhibited high activity in the hydrogenation reaction of cinnamaldehyde because of its smaller particle size and high dispersion. Yield of hydrocinnamic aldehyde was up to 77.24% at 150℃ under 2 MPa(loading of nickel was 15%). In addition,Ni/Al₂O₃ catalysts maintained high activity for hydrogenation of cinnamaldehyde to hydrocinnamic aldehyde after five consecutive runs and its XRD and TEM were the same as before,which revealed that as-prepared Ni/Al₂O₃ catalysts had a remarkable recycling stability.

Key words: nickel, aluminium oxide, azeotropic distillation, cinnamaldehyde, hydrogenation

摘要： 利用共沸蒸馏法制备了金属Ni高度分散的Ni/Al₂O₃催化剂，并利用X射线粉末衍射仪（XRD）、透射电子显微镜（TEM）和全自动比表面积和孔径分析仪（BET）对其进行了一系列表征。实验过程中，选用肉桂醛（CAL）加氢反应来考察该催化剂的催化性能。结果表明，共沸蒸馏法制备出的Ni/Al₂O₃催化剂较浸渍法而言，其金属Ni的粒径较小且高度分散，同时催化剂对肉桂醛加氢生成3-苯丙醛（HCAL）具有良好的催化效果。在反应温度为150℃、反应压力为2MPa、负载量为15%时，3-苯丙醛的产率高达77.24%。此外，该催化剂在循环使用了5次后3-苯丙醛的产率并未出现明显下降的趋势，通过循环过后的XRD和TEM表征显示其前后的数据并没有发生改变，这说明该催化剂具有良好的循环稳定性。

关键词: 镍, 三氧化二铝, 共沸蒸馏法, 肉桂醛, 加氢

CLC Number:

O643.3

QIN Jilong, WANG Fei, CAI Jinpeng, HU Jianheng, LIU Wenwen, JIANG Xingmao. Synthesis of Ni/Al₂O₃ catalysts by azeotropic distillation for hydrogenation of cinnamaldehyde[J]. Chemical Industry and Engineering Progress, 2017, 36(12): 4468-4474.

秦跻龙, 王非, 蔡金鹏, 胡建恒, 刘雯雯, 姜兴茂. 共沸蒸馏法制备Ni/Al₂O₃催化剂及其肉桂醛加氢反应性能[J]. 化工进展, 2017, 36(12): 4468-4474.

References

[1] YUAN Y,YAO S Y,WANG M N,et al. Recent progress in chemoselective hydrogenation of α,β-unsaturated aldehyde to unsaturated alcohol over nanomaterials[J]. Current Organic Chemistry,2013,17(4):400-413.
[2] BERTOLINI G R,CABELLO C I,MUÑOZ M,et al. Catalysts based on Rh(Ⅲ)-hexamolybdate/γ-Al₂O₃ and their application in the selective hydrogenation of cinnamaldehyde to hydrocinnamaldehyde[J]. Journal of Molecular Catalysis A:Chemical,2013,366:109-115.
[3] STANKOVICH S,DIKIN D A,DOMMETT G H B,et al. Graphene-based composite materials[J]. Nature,2006,442(7100):282-286.
[4] GEIM A K,NOVOSELOV K S. The rise of graphene[J]. Nature Materials,2007,6(3):183-191.
[5] HE L,YU F J,LOU X B,et al. A novel gold-catalyzed chemoselective reduction of α,β-unsaturated aldehydes using CO and H₂O as the hydrogen source[J]. Chemical Communications,2010,46(9):1553-1555.
[6] ZHU Y,QIAN H F,DRAKE B A,et al. Atomically precise Au25(SR) 18 nanoparticles as catalysts for the selective hydrogenation of α,β-unsaturated ketones and aldehydes[J]. Angewandte Chemie,2010,122(7):1317-1320.
[7] MERLO A B,MACHADO B F,VETERE V,et al. PtSn/SiO₂ catalysts prepared by surface controlled reactions for the selective hydrogenation of cinnamaldehyde[J]. Applied Catalysis A:General,2010,383(1):43-49.
[8] DELBECQ F,SAUTET P. Competitive C==C and C==O adsorption of α,β-unsaturated aldehydes on Pt and Pd surfaces in relation with the selectivity of hydrogenation reactions:a theoretical approach[J]. Journal of Catalysis,1995,152(2):217-236.
[9] NOLLER H,LIN W M. Activity and selectivity of Ni-Cu/Al₂O₃ catalysts for hydrogenation of crotonaldehyde and mechanism of hydrogenation[J]. Journal of Catalysis,1984,85(1):25-30.
[10] 李辉,马春景,李和兴. Ni-Co-B非晶态合金催化肉桂醛常压加氢制3-苯丙醛的研究[J]. 化学学报,2006,64(19):1947-1953. LI H,MA C J,LI H X. Study on cinnamaldehyde hydrogenation to 3-phenylpropyl aldehydeat atmospheric pressure over Ni-Co-B amorphous alloys[J]. Acta Chimica Sinica,2006,64(19):1947-1953.
[11] 韩晓祥,周仁贤,郑小明. 负载Pt催化剂在卤代硝基苯氢化反应中的催化性能研究[J]. 复旦学报(自然科学版),2003,42(3):428-430. HAN X X,ZHOU R X,ZHENG X M. Study on the hydrogenation properties of chloronitrobenzenne over supported platinum catalysts[J]. Journal of Fudan University(Natural Science),2003,42(3):428-430.
[12] HAMMOUDEH A,Mahmoud S. Selective hydrogenation of cinnamaldehyde over Pd/SiO₂,catalysts:selectivity promotion by alloyed Sn[J]. Journal of Molecular Catalysis A:Chemical,2003,203(1/2):231-239.
[13] CHIN S Y,LIN F J,KO A N. Vapour phase hydrogenation of cinnamaldehyde over Ni/γ-Al₂O₃ catalysts:interesting reaction network[J]. Catalysis Letters,2009,132(3/4):389-394.
[14] SATTERFIELD C N. 实用多相催化[M]. 庞礼,译. 北京:北京大学出版社,1990:98-102. SATTERFIELD C N. Heterogeneous catalysis in practice[M]. Pang L,Trans. Beijing:Peking University Press,1990:98-102.
[15] WANG F,REN J,CAI Y L,et al. Palladium nanoparticles confined within ZSM-5 zeolite with enhanced stability for hydrogenation of p-nitrophenol to p-aminophenol[J]. Chemical Engineering Journal,2016,283:922-928.

Synthesis of Ni/Al₂O₃ catalysts by azeotropic distillation for hydrogenation of cinnamaldehyde

共沸蒸馏法制备Ni/Al₂O₃催化剂及其肉桂醛加氢反应性能

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