Synthesis，properties and application of protein based surfactants:a review

doi:10.16085/j.issn.1000-6613.2016-2275

Abstract

Abstract: Protein based surfactants,a class of environmental-friendly biomass-based surfactants,possess excellent surface active properties and particular performances including low toxicity and easy biodegradability compared with traditional surfactants.This article firstly discussed the methods of synthesizing protein based surfactants,based on hydrolysates of animal proteins such as collagen,silk protein and keratin.This part was focused on the influence of molecular weight and hydrolysis methods on the properties of collagen hydrolysate as hydrophilic domains,and methods for preparing collagen based surfactants using hydrocarbon chain or siloxane chain as hydrophobic domains.Then,their surface properties were summarized and compared,such as surface tension,critical micell concentration,foaming and emulsifying properties.And the diverse applications in the fields of leather manufacturing,printing and dyeing,daily chemicals and biological medicine were also introduced on the basis of their surface properties and environmental-friendly features.Finally,some issues of preparation and application of protein based surfactants were pointed out,and in particular the developing trends in the new type surfactants,such as Bola and Gemini,were prospected.

Key words: collagen, keratin, silk protein, surfactants, synthesis

摘要： 蛋白基表面活性剂是一类环境友好的生物质基表面活性剂，具有良好的表面活性，与传统表面活性剂相比，还具有低毒、易生物降解等特性。本文首先讨论了基于胶原蛋白、丝蛋白、角蛋白等动物蛋白水解物制备表面活性剂的方法，其中重点阐述了分子量和水解方法对作为表面活性剂亲水端的胶原蛋白水解物性质的影响，以及分别以脂肪碳链和硅氧烷链为疏水端的胶原基表面活性剂的合成方法。随后，总结并比较了蛋白基表面活性剂的表面张力、临界胶束浓度、起泡力和乳化力等表面性质。依据蛋白基表面活性剂的表面性质和环境友好等特性，介绍了它们在制革印染、日用化工、生物医药等领域的应用。最后，指出了蛋白基表面活性剂制备和应用中存在的一些问题，对新型表面活性剂（如Bola型、Gemini型）发展方向进行了展望。

关键词: 胶原, 角蛋白, 丝蛋白, 表面活性剂, 合成

CLC Number:

TQ423

WANG Baochuan, LI Yupeng, DAI Guochen, LI Zhengjun, YANG Qinhuan. Synthesis，properties and application of protein based surfactants:a review[J]. Chemical Industry and Engineering Progress, 2017, 36(07): 2607-2614.

汪保川, 李宇鹏, 戴国琛, 李正军, 杨秦欢. 蛋白基表面活性剂的合成、性能与应用进展[J]. 化工进展, 2017, 36(07): 2607-2614.

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