麦羟硅钠石/聚合物纳米复合材料研究进展

doi:10.16085/j.issn.1000-6613.2018-0875

化工进展 ›› 2019, Vol. 38 ›› Issue (03): 1452-1460.DOI: 10.16085/j.issn.1000-6613.2018-0875

麦羟硅钠石/聚合物纳米复合材料研究进展

戈明亮^1,^2,³(),王旭斌¹,梁国栋²

1. 华南理工大学，聚合物成型加工工程教育部重点实验室，聚合物新型成型装备国家工程研究中心，广东广州 510641
2. 中山大学聚合物复合材料及功能材料教育部重点实验室，广东广州 510275
3. 贵州民族大学材料科学与工程学院，贵州贵阳 550025

收稿日期:2018-04-28 修回日期:2018-11-12 出版日期:2019-03-05 发布日期:2019-03-05
作者简介:戈明亮（1970—），男，博士，副教授，研究方向为纳米复合材料及功能材料。E-mail：gml@scut.edu.cn。
基金资助:
广东省自然科学基金(2016A030313520);广东省水利科技创新项目(2017-24);中山大学聚合物复合材料及功能材料教育部重点实验室开放基金(PCFM-2017-02);广东省教育厅特色创新类项目(2017KTSCX007)

Research progress of magadiite/polymer nanocomposites

Mingliang GE^1,^2,³(),Xubin WANG¹,Guodong LIANG²

1. Key Laboratory of Polymer Processing Engineering of Ministry of Education, National Engineering Research Center of Novel Equipment for Polymer Processing, South China University of Technology, Guangzhou 510641, Guangdong, China
2. Key Laboratory for Polymeric Composite & Functional Materials of Ministry of Education, Sun Yat-sen University, Guangzhou 510275, Guangdong, China
3. School of Materials Science and Engineering, Guizhou Minzu University, Guiyang 550025, Guizhou, China

Received:2018-04-28 Revised:2018-11-12 Online:2019-03-05 Published:2019-03-05

摘要/Abstract

摘要：

麦羟硅钠石（magadiite）是一种新型的层状纳米硅酸盐材料，由于其具有制备工艺简单、比表面积大、阳离子交换性能高、吸附性能强、层间膨胀性能好等优点，成为纳米材料提升聚合物性能最具有发展潜力的材料之一。本文主要综述了麦羟硅钠石/聚合物纳米复合材料的常用制备方法及其优缺点，包括聚合物插层法、单体原位插层聚合法、锚固插层聚合法。浅谈了国内外利用3种方法制备的基于聚苯乙烯、聚丙烯、环氧树脂、尼龙6、聚己内酯和聚甲基丙烯酸甲酯等多种聚合物的麦羟硅钠石/聚合物纳米复合材料，对在纳米复合材料结构中出现界面不相容、麦羟硅钠石分布不均匀的问题提出了解决方法，并阐述了麦羟硅钠石对纳米复合材料结构和性能的影响，最后展望了麦羟硅钠石/聚合物纳米复合材料的发展前景。

关键词: 麦羟硅钠石, 聚合物纳米复合材料, 表面改性, 结构, 性能

Abstract:

Magadiite is a new type of layered nano-silicate material, which has the advantages of large specific surface area, high cation exchange, strong adsorption and good inter-layer swelling performance. It has become one of the most promising potential for nano-material modified polymers. This article mainly summarized the common preparation methods of magadiite/polymer nanocomposites, including polymer intercalation, monomer in-situ intercalation polymerization and anchor intercalation polymerization. The magadiite/polymer nanocomposites prepared by three methods at home and abroad based on polystyrene, polypropylene, epoxy resin, nylon 6, polycaprolactone and polymethylmethacrylate were discussed. The solution to the incompatibility of the interface and the uneven distribution of magadiite in the nanocomposite structure was proposed, and the influence of magadiite on the structure and properties of the nanocomposite was explained. Finally, the outlook for the development of magadiite/polymer nanocomposites was presented.

Key words: magadiite, polymer nanocomposites, surface modification, structure, properties

中图分类号:

TB332

戈明亮,王旭斌,梁国栋. 麦羟硅钠石/聚合物纳米复合材料研究进展[J]. 化工进展, 2019, 38(03): 1452-1460.

Mingliang GE,Xubin WANG,Guodong LIANG. Research progress of magadiite/polymer nanocomposites[J]. Chemical Industry and Engineering Progress, 2019, 38(03): 1452-1460.

图/表 12

图1 SEM不同倍数下的麦羟硅钠石[16]

图2 麦羟硅钠石的三维结构[18]

图3 聚合物熔融插层法制备麦羟硅钠石/聚合物复合材料

图4 单体原位插层聚合法制备麦羟硅钠石/聚合物复合材料

图5 锚固插层聚合法制备麦羟硅钠石/聚合物复合材料

图6 5% 麦羟硅钠石引发剂在聚合过程中不同反应时间的XRD图[44]

图7 MAG/PP、Org-MAG/PP纳米复合材料的TEM图[37]

图8 MAG/PA和Org-MAG/PA6纳米复合材料的TEM图(MAG和Org-MAG质量分数均为3%)[38]

图9 MAG、DTMA-MAG、γ-MPS-MAG和γ-MPS-MAG/PMMA的SEM图[46]

图10 在不同溶剂中离子交换后制备的MAG/PS纳米复合材料的TEM[41]

图11 锚固插层聚合法制备MAG/PS纳米复合材料过程[44]

图12 含5.0% 麦羟硅钠石引发剂的MAG/PS纳米复合材料的TEM[44]

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麦羟硅钠石/聚合物纳米复合材料研究进展

Research progress of magadiite/polymer nanocomposites

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