熔融纺丝速度对中间相沥青炭纤维性能的影响

doi:10.16085/j.issn.1000-6613.2017.03.029

化工进展 ›› 2017, Vol. 36 ›› Issue (03): 985-988.DOI: 10.16085/j.issn.1000-6613.2017.03.029

熔融纺丝速度对中间相沥青炭纤维性能的影响

李伏虎¹, 迟伟东², 沈曾民², 刘辉², 于建民²

1 安徽理工大学化学工程学院, 安徽淮南 232001;
2 北京化工大学炭纤维及复合材料研究所, 北京 100029

收稿日期:2016-07-26 修回日期:2016-10-09 出版日期:2017-03-05 发布日期:2017-03-05
通讯作者: 李伏虎(1970-),男,博士,主要从事炭材料制备与应用的研究。
作者简介:李伏虎(1970-),男,博士,主要从事炭材料制备与应用的研究。E-mail:lifuhu2003@163.com。
基金资助:
华东理工大学煤气化及能源化工教育部重点实验室开放基金项目（WB1014046-36）。

Effects of melt spinning speed on performance of mesophase pitch based carbon fibres

LI Fuhu¹, CHI Weidong², SHEN Zengmin², LIU Hui², YU Jianmin²

1 College of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, Anhui, China;
2 Institute of Carbon Fiber and Composites, Beijing University of Chemical Technology, Beijing 100029, China

Received:2016-07-26 Revised:2016-10-09 Online:2017-03-05 Published:2017-03-05

摘要/Abstract

摘要：

以AR中间相沥青为原料，采用熔融纺丝法制备出中间相沥青纤维，再经预氧化和炭化处理得到中间相炭纤维。采用光学显微镜、扫描电镜（SEM）及纤维拉力仪等手段，研究了熔融纺丝速度对中间相炭纤维直径、内部微观结构、纤维表面微观形貌及纤维力学性能的影响。研究结果表明，随着纺丝速度的增大，中间相沥青纤维平均直径减小，可纺性逐渐下降；当纺丝速度大于330m/min时，中间相炭纤维表面出现纵向纹理缺陷，纤维内部微观结构变得无序；在纺丝速度为330m/min时，炭纤维拉伸强度达到最大值1786MPa，此时纤维直径为11μm。

关键词: 中间相沥青, 炭纤维, 纺丝速度, 力学性能

Abstract:

Mesophase pitch based fibres(MPF) are prepared by melt spinning method from AR-mesophase pitch. After oxidation and carbonization,mesophase pitch based carbon fibres(MPCF) are obtained. The effects of spinning speed on the diameter,microstructure,surface micro-morphology and mechanical properties of carbon fibres are investigated by means of optical microscope,scanning electron microscope(SEM) and fibre strength tester,respectively. The results show that the average diameter of MPF decreases and its spinnability decline gradually with the increase of spinning speed. When the spinning speed is higher than 330m/min,the lengthwise texture flaws appear on the surface of MPCF and the internal microstructure becomes more disordered. Moreover,the tensile strength of MPCF with 11μm in diameter reaches the maximum of 1786MPa at spinning speed of 330m/min.

Key words: mesophase pitch, carbon fibre, spinning speed, mechanical properties

中图分类号:

TQ342

李伏虎, 迟伟东, 沈曾民, 刘辉, 于建民. 熔融纺丝速度对中间相沥青炭纤维性能的影响[J]. 化工进展, 2017, 36(03): 985-988.

LI Fuhu, CHI Weidong, SHEN Zengmin, LIU Hui, YU Jianmin. Effects of melt spinning speed on performance of mesophase pitch based carbon fibres[J]. Chemical Industry and Engineering Progress, 2017, 36(03): 985-988.

参考文献

[1] 沈曾民.新型炭材料[M].北京:化学工业出版社,2003:98-126. SHEN Z M. New carbon materials[M].Beijing:Chemical Industry Press,2003:98-126.
[2] 肖南,邱介山.煤沥青基功能碳材料的研究现状及前景[J].化工进展,2016,35(6):1804-1811. XIAO N,QIU J S. Progress in synthesis and applications of functional carbon materials from coal tar pitch[J].Chemical Industry and Engineering Progress,2016,35(6):1804-1811.
[3] 周颖,安光, 王六平,等.中间相沥青及其应用研究进展[J].化工进展,2011,30(11):2456-2460. ZHOU Y,AN G,WANG L P,et al.Progress in mesophase pitch research and its application[J].Chemical Industry and Engineering Progress,2011,30(11):2456-2460.
[4] WATANABE F,KORAI Y,MOCHIDA I.Structure of melt-blown mesophase pitch-based carbon fiber[J].Carbon,2000,38(5):741-747.
[5] HONG S H,KORAI Y,MOCHIDA I.Mesoscopic texture at the skin area of mesophase pitch-based carbon fiber[J].Carbon,2000,38(6):805-815.
[6] MATSUMOTO T,MOCHIDA I.A structural study on oxidative stabilization of mesophase pitch fibers derived from coaltar[J].Carbon,1992,30(7):1041-1046.
[7] MOCHIDA I,ZENG S M,KORAI Y.The introduction of a skin-core structure in mesophase pitch fibers by oxidative stabilization[J]. Carbon,1990,28(1):193-198.
[8] 宁亮,迟伟东,刘辉,等.中间相沥青基碳纤维电化学氧化表面处理的正交优化设计[J].化工进展,2009,28(9):1600-1604. NING L,CHI W D,LIU H,et al.Orthogonal experimental design on the surface treatment of mesophase pitch-based carbon fiber with electrochemical oxidation[J].Chemical Industry and Engineering Progress,2009,28(9):1600-1604.
[9] 穆翠红,刘辉,迟伟东,等. 中间相沥青基碳纤维表面TaC涂层的研究[J]. 化工进展,2010,29(8):1521-1524. MU C H,LIU H,CHI W D,et al.TaC surface coating on mesophase pitch-based carbon fibers[J].Chemical Industry and Engineering Progress,2010,29(8):1521-1524.
[10] 袁靖,迟伟东,沈曾民,等.采用加压-真空两段热缩聚法制备中间相沥青炭纤维的原料[J].炭素,2002(4):8-14. YUAN J,CHI W D,SHEN Z M,et al.Manufacture raw of mesophase-pitch carbon fiber by two-stage thermal condensation method under pressure-vacuum[J].Carbon,2002,(4):8-14.
[11] 孟志芬,胡学超.纺丝速度对Lyocell纤维结构的影响[J].河南师范大学学报(自然科学版),2004,32(4):74-77. MENG X F,HU X C.Effects of spinning speed on structure of Lyocell fiber[J].Journal of Henan Normal University(Natural Science),2004,32(4):74-77.
[12] 马雷,徐梁华. 纺丝速度对干湿法PAN纤维形貌和结构的影响[J]. 高科技纤维与应用,2014,39(2):29-32. MA L,XU L H.The effect of dry-jet wet spinning speed on the structure of PAN-based carbon fiber[J].Hi-Tech Fiber & Application, 2014,39(2):29-32.
[13] 张勇,相鹏伟,张蕊萍,等.纺丝速度对聚苯硫醚纤维结构与性能的影响[J].高分子材料科学与工程,2015,31(7):114-118. ZHANG Y,XIANG P W,ZHANGR P,et al.Effect of spinning speed on structure and properties of poly-phenylene sulfide fiber[J].Polymer Materials Science and Engineering,2015,31(7):114-118.
[14] 李伏虎,沈曾民,迟伟东,等.两种不同原料中间相沥青分子结构的研究[J].炭素技术,2009,28(1):4-8. LI F H,SHEN Z M,CHI W D,et al.Molecular structures of mesophase pitches prepared from different raw materials[J].Carbon Techniques,2009,28(1):4-8.
[15] MOCHIDA I,KORAI Y,KU C H,et al.Chemistry of synthesis, structure,preparation and application of aromatic-derived mesophase pitch[J].Carbon,2000,38(2):305-328.

熔融纺丝速度对中间相沥青炭纤维性能的影响

Effects of melt spinning speed on performance of mesophase pitch based carbon fibres

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王家庆, 宋广伟, 李强, 郭帅成, DAI Qingli. 橡胶混凝土界面改性方法及性能提升路径[J]. 化工进展, 2023, 42(S1): 328-343.
[2]	刘大晨, 杜明慧, 王衡. 交联型特辛基酚醛树脂酚羟基间位的溴化改性[J]. 化工进展, 2022, 41(S1): 382-388.
[3]	刘竞, 郑新国, 李铁军, 王财平, 赵彦旭, 李颖, 楼梁伟, 沈伟. 可再分散乳化沥青粉末改性水泥砂浆的力学性能和微观形貌[J]. 化工进展, 2022, 41(4): 2015-2021.
[4]	马星星, 冯亚凯. 偶联剂改性氧化铈提高硅凝胶的耐热氧性能[J]. 化工进展, 2022, 41(2): 874-880.
[5]	尹洪贺, 沈绍传, 齐亮, 姚克俭. 新型多降液管塔板的流体力学性能及其流场CFD模拟[J]. 化工进展, 2022, 41(2): 601-608.
[6]	杨立宁, 郑东昊, 王立新, 杨光. 基于蜻蜓翅脉结构的连续碳纤维增强树脂基复合材料仿生设计与增材制造[J]. 化工进展, 2022, 41(11): 5961-5967.
[7]	金浩, 刘杏, 林咏梅. 植酸改性的明胶复合膜制备及其结构与性能分析[J]. 化工进展, 2021, 40(7): 3847-3853.
[8]	张璐, 孙金鹏, 俞青源, 李如燕, 张云浩, 王文俊. 木粉疏水改性对HDPE基木塑复合材料性能的影响[J]. 化工进展, 2020, 39(9): 3487-3493.
[9]	王文玉, 董瑞宝, 李志波, 潘广勤. 液体低分子聚异戊二烯改性丁腈橡胶发泡材料[J]. 化工进展, 2020, 39(8): 3230-3235.
[10]	郑帼,苗同梦,吴波,周存. 高强高模维纶纤维的表面修饰及其在水泥中的分散性[J]. 化工进展, 2020, 39(1): 250-256.
[11]	杨世诚, 孙琦, 谌伦建, 张玉龙, 薛晓晓, 仪桂云. 赤泥改性及其对丁苯橡胶复合材料微观结构和力学性能的影响[J]. 化工进展, 2019, 38(07): 3297-3303.
[12]	李思漩, 夏蕾, 李靖宇, 刘晓刚, 孙巾茹, 迟姚玲, 王虹, 李翠清, 宋永吉. 成型条件对Co/ZSM-5催化剂催化分解N₂O性能影响[J]. 化工进展, 2019, 38(04): 1746-1752.
[13]	姚彬彬, 阚泽. 天然虾青素改性白炭黑/天然橡胶复合材料的制备与性能[J]. 化工进展, 2019, 38(04): 1872-1878.
[14]	张政和,杨卫民,谭晶,李好义. 碳纤维石墨化技术研究进展[J]. 化工进展, 2019, 38(03): 1434-1442.
[15]	迟长云, 李英杰. 钙基碳载体造粒的捕集CO特性及力学性能[J]. 化工进展, 2018, 37(12): 4908-4916.