中国油页岩干馏技术现状与发展趋势

doi:10.16085/j.issn.1000-6613.2015.05.002

化工进展 ›› 2015, Vol. 34 ›› Issue (05): 1191-1198.DOI: 10.16085/j.issn.1000-6613.2015.05.002

中国油页岩干馏技术现状与发展趋势

秦宏, 岳耀奎, 刘洪鹏, 王擎

东北电力大学油页岩综合利用教育部工程研究中心, 吉林吉林 132012

收稿日期:2014-10-24 修回日期:2015-02-06 出版日期:2015-05-05 发布日期:2015-05-05
通讯作者: 王擎,教授,博士生导师,研究方向为油页岩综合利用项目及循环流化床燃烧及污染物控制等.E-mailrlx888@126.com.
作者简介:秦宏(1970—),男,博士,教授,从事污染物排放控制,油页岩综合利用等方面的研究.E-mailqinhong01@163.com.
基金资助:
国家自然科学基金(51276034)、长江学者和创新团队发展计划(IRT13052)及吉林省科技发展计划(20150204012SF,20130522067JH)项目.

Current status and prospect of oil shale retorting technologies in China

QIN Hong, YUE Yaokui, LIU Hongpeng, WANG Qing

Engineering Research Centre of Ministry of Education for Comprehensive Utilization of Oil Shale, Northeast Dianli University, Jilin 132012, Jilin, China

Received:2014-10-24 Revised:2015-02-06 Online:2015-05-05 Published:2015-05-05

摘要/Abstract

摘要： 中国油页岩资源丰富,换算成页岩油储量高达476亿吨.目前中国页岩油生产企业仍然采用以抚顺炉为主的干馏技术,该技术成熟稳定,但油收率不高.本文介绍了目前国内已投产运行和即将工业化的干馏技术以及曾经投入生产、后因多种原因停产的干馏技术.分析表明,我国油页岩产业正处于技术快速发展和产业成长阶段:为显著提高油收率,针对抚顺炉的改进技术已有一些进展,自主研发的成大气体热载体干馏工艺已经开始商业化运行,我国自主知识产权的固体热载体干馏技术出现.但依然存在诸多问题:国内干馏炉单炉处理量小、油收率偏低、半焦无法利用等问题亟需解决,国内固体热载体干馏自主技术依然处于试验阶段,引进国外先进的干馏技术尚没有实质性进展,国内页岩油回收技术亟待改进,油洗技术亟需完善和推广.

关键词: 油页岩, 干馏, 油收率, 气体热载体, 固体热载体, 油洗工艺

Abstract: China has abundant oil shale resources,which amount to 47.6×10⁹t shale oil. Now,the domestic enterprises produce shale oil mainly by the Fushun retort,which is characterized as mature technology,steady operation,but low oil recovery and limited capacity. In this paper several retorting technologies are introduced,including the technology being used,the technology to be commercialized,and the technology which was put into operation but discontinued. Analyses show that oil shale retorting in China is developing rapidly and growth of the industry is expected. The modified Fushun retort could increase oil recovery. Self-developed Chengda gas heat carrier retort has begun commercialized operation. Proprietary solid heat carrier retort has been developed. However,there are still many problems to be resolved,such as small single unit capacity,low oil recovery,utilization of semi-coke. Furthermore,the proprietary solid heat carrier retort is still in the experimental stage. No substantial progress has been made in import of foreign advanced retorting technology. In addition,oil recovery needs to be improved,and oil washing is still immature in China.

Key words: oil shale, retort, oil yield, gas heat carrier, solid heat carrier, oil washing process

中图分类号:

TE662

秦宏, 岳耀奎, 刘洪鹏, 王擎. 中国油页岩干馏技术现状与发展趋势[J]. 化工进展, 2015, 34(05): 1191-1198.

QIN Hong, YUE Yaokui, LIU Hongpeng, WANG Qing. Current status and prospect of oil shale retorting technologies in China[J]. Chemical Industry and Engineering Progree, 2015, 34(05): 1191-1198.

参考文献

[1] 钱家麟,王剑秋,李术元. 世界油页岩综述[J]. 中国能源,2006,28(8):16-19.

[2] Qian Jialin,Wang Jianqiu. World's oil shale available retorting technologies and the forecast of shale oil production[C]//Proceedings of the Eighteenth (2008) International Offshore and Polar Engineering,Conference,Vancouver B C,2008.

[3] Soone J,Riisalu H,Kekisheva L,et al. Environmentally sustainable use of energy and chemical potential of oil shale[C]//International Oil Shale Conference,Amman,Jordan:Jordanian Natural Resources Authority,2006.

[4] Soone J,Doilov S. Sustainable utilization of oil shale resources and comparison of contemporary technologies used for oil shale processing[J]. Oil Shale,2003,20(3):311-323.

[5] Jaber J O,Sladek T A,Mernitz S,et al. Future policies and strategies for oil shale development in Jordan[J]. Jordan Journal of Mechanical and Industrial Engineering,2008,2(1):31-44.

[6] 高书香,曹克广,孟庆萍. 油页岩生产技术研究[J]. 吉林地质,2007,26(1):45-48.

[7] 刘德勋,王红岩,郑德温,等. 世界油页岩原位开采技术进展[J]. 天然气工业,2009,29(5):128-132,148.

[8] 韩晓辉,卢桂萍,孙朝辉,等. 国外油页岩干馏工艺研究开发进展[J]. 中外能源,2011,16(4):69-74.

[9] Qian Jialin,Yin Liang. Oil Shale:Petroleum Alternative[M]. Beijing:China Petrochemical Press,2010,173-175.

[10] Andrews,Anthony. Oil shale:History,incentives,and policy[C]// Congressional Research Service the Library of Congress 101 Independence Ave,Washington DC,2006.

[11] 高健. 世界各国油页岩干馏技术简介[J]. 煤炭加工与综合利用,2003(2):44-46.

[12] Fowler T D,Vinegar H J. Oil shale ICP-Colorado field pilots[C]//SPE Western Regional Meeting,San Jose,California. 2009.

[13] Qian Jialin,Wang Jianqiu. World oil shale retorting technologies[C]//International Conference on Oil Shale :“Recent Trends In Oil Shale”,Amman,Jordan,2006.

[14] Chen Shuzhao,Guo Liwen,Xiao Cangyan,et al. Utilization of oil shale retorting technology and underground overview[C]//Computer Distributed Control and Intelligent Environmental Monitoring(CDCIEM). Institude of Electrical and Electronics Engineers,Changsha,2011.

[15] Peter C,Biglarbigi K,Dammer A,et al. Advances in world oil-shale production technologies[C]//SPE Annual Technical Conference and Exhibition,Denver,Colorado,2008.

[16] K B A,R M J. Comparison of the Acceptability of Various Oil Shale Processes[M]. United States:Department of Energy,2006:1-11.

[17] Hou Jili,Li Shuyuan,Qian Jialin,et al. Resurces and development status of Chinese oil shale[C]//34th Oil Shale Symposium,Colorado School of Mines:Golden,Colorado,2014.

[18] Qian Jialin,Wang Jianqiu,Li Shuyuan. Oil shale development in China[J]. Oil Shale,2003,20(3S):346-359.

[19] 李术元,何继来,侯吉礼,等. 世界油页岩勘探开发加工利用现状——并记2014年国外两次油页岩国际会议[J]. 中外能源,2014,20(1):25-32.

[20] 中国石油新闻中心. 工程建设华东设计分公司完成小颗粒油页岩炼油项目[EB/OL].(2014-11-25)[2014-12-3]http://news.cnpc.com. cn/system/2014/11/25/001517288.shtml

[21] 施国泉. 石油替代路在何方[C]//中国油页岩产业发展交流会,龙口,2011.

[22] He Y G. Mining and utilization of Chinese Fushun oil shale[J]. Oil Shale,2004,21(3):259-264.

[23] Wang Qing,Bai J R,Sun B J. Strategy of Huadian oil shale comprehensive utilization[J]. Oli shale,2005,22(3):305-316.

[24] 陈国超,高筠. 传统页岩低温干馏技术改造研究[J]. 当代化工,2013,42(5):608-610.

[25] 刘连兴,康玉波. 抚顺式油页岩干馏炉型改进探究[J]. 能源与节能,2011(11):79-80,94.

[26] 高健,鲍明福,韩放. 高效环保型油页岩干馏工艺的研究与开发[J]. 煤炭加工与综合利用,2012(1):52-54.

[27] 曹东方. 瓦斯全循环油页岩分级干馏技术及应用[J]. 石油和化工设备,2013,16(10):23-27,35.

[28] 吴启成,曹庆喜,王鸿治,等. 瓦斯全循环油页岩分级干馏工艺及装置:中国,2008100130885[P]. 2009.

[29] 孙建新,黄诚,段永宏. SJ型干馏方炉在窑街油页岩炼油技术领域的开发与应用[J]. 中外能源,2010,15(12):80-83.

[30] 熊耀,马名杰,黄山秀,等. 国内油页岩干馏炼油技术发展现状[J]. 现代化工,2013,33(8):40-44.

[31] 侯祥麟. 中国页岩油加工[M]. 北京:石油工业出版社,1984.

[32] 罗荣陶. 改进茂名页岩干馏工艺的建议[J]. 茂名石油加工,1991(2):17-32.

[33] Y H L. Oil shale retorting technology in Maoming[C]//International Conference on Oil Shale and Shale Oil. Beijing:Chemical Industry Press,1988.

[34] 钱家麟,李术元. 油页岩干馏炼油工艺[M]. 北京:中国石化出版社,2014.

[35] 钱家麟,尹亮. 油页岩——石油的替代能源[M]. 北京:中国石化出版社,2008.

[36] Geng Cengceng,Li Shuyuan,Qian Jialin. New development and utilization of chinese oil shale[C]//33thOil Shale Symposium,Colorado School of Mines,Golden,Colorado,2013.

[37] 刘德勋,赵群,王红岩,等. 国内外小颗粒油页岩干馏工艺现状与展望[J]. 广州化工,2010,38(12):7-11.

[38] 王守峰,陈兆然,吕子胜,等. 油页岩类物质流化床干馏及脱碳工艺:中国. 2003101166877[P]. 2005-06-01.

[39] 中煤能源黑龙江煤化工公司. 中煤能源黑龙江煤化工公司2011年油页岩项目进展[J]. 中国油母页岩,2011(1):6.

[40] 姜殿臣,邹春玉,张海永. 粉末页岩流化干馏中试试验[J]. 化工进展,2012,31(s1):380-383.

[41] 王波,陈娟娟,刘永卫,等. 油页岩干馏的冷凝回收系统研究现状与发展趋势[J]. 化工进展,2011,30(6):1205-1212,1218.

[42] 黄建宁,李森林. 运用冶金焦化生产技术开发油页岩炼制新工艺[J]. 重型机械,2009(4):12-15.

中国油页岩干馏技术现状与发展趋势

Current status and prospect of oil shale retorting technologies in China

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