固体酸催化制备生物柴油研究进展

doi:10.16085/j.issn.1000-6613.2016.09.021

化工进展 ›› 2016, Vol. 35 ›› Issue (09): 2783-2789.DOI: 10.16085/j.issn.1000-6613.2016.09.021

固体酸催化制备生物柴油研究进展

王婷, 蔡文静, 刘熠斌, 杨朝合

中国石油大学(华东)重质油国家重点实验室, 山东青岛 266580

收稿日期:2015-12-18 修回日期:2016-03-18 出版日期:2016-09-05 发布日期:2016-09-05
通讯作者: 刘熠斌,副教授,主要从事催化裂化方面的研究。E-mail:liuyibin@upc.edu.cn。
作者简介:王婷(1991-),女,硕士研究生,从事生物柴油催化剂方面的研究。
基金资助:
山东省自然科学基金联合专项项目（ZR2014BL015）。

Research progress in preparation of biodiesel with solid acid catalyst

WANG Ting, CAI Wenjing, LIU Yibin, YANG Chaohe

State Key Laboratory of Heavy Oil Processing, China University of Petroleum(East China), Qingdao 266580, Shandong, China

Received:2015-12-18 Revised:2016-03-18 Online:2016-09-05 Published:2016-09-05

摘要/Abstract

摘要： 生物柴油是一种绿色的可再生能源，主要通过酯交换反应生产。催化剂在酯交换反应中起重要作用，固体酸催化剂因污染少、效率高、易分离而成为研究热点。本文介绍了固体酸催化制备生物柴油的反应机理，综述了国内外近几年生物柴油制备中所用固体酸催化剂的研究进展，分为固体杂多酸、无机酸盐、金属氧化物及其复合物、沸石分子筛及阳离子交换树脂等，分析了催化剂的制备流程、反应操作条件和反应结果等，得出固体酸在催化含有大量水分和游离酸的油脂酯交换反应方面具有独特的优势，且符合生物柴油绿色生产的要求，是需要进一步研究和开发的方向。

关键词: 生物柴油, 固体酸, 酯交换

Abstract: Biodiesel is a green renewable energy resource, and is mainly produced through transesterification,in which catalyst plays an important role.Solid acid catalyst has become a hot topic due to the advantages of little pollution,high efficiency and easy separation.This paper introduces the reaction mechanism for biodiesel production with solid acid catalysts,and reviews the recent research progress of the catalysts,including heteropolyacids,inorganic acid salts,metal oxides and complexes, zeolites,cation exchange resins,et al.Also,the preparation methods,reaction conditions and results of those catalysts are analyzed.It is concluded that solid acid catalysts can meet the requirement of green production of biodiesel,especially for transesterification of the oils containing massive water and free fatty acid,and therefore deserve further research.

Key words: biodiesel, solid acid, transesterification

中图分类号:

TE667
TQ426

王婷, 蔡文静, 刘熠斌, 杨朝合. 固体酸催化制备生物柴油研究进展[J]. 化工进展, 2016, 35(09): 2783-2789.

WANG Ting, CAI Wenjing, LIU Yibin, YANG Chaohe. Research progress in preparation of biodiesel with solid acid catalyst[J]. Chemical Industry and Engineering Progree, 2016, 35(09): 2783-2789.

参考文献

[1] ZABETI M,DAUD W M A W,AROUA M K.Activity of solid catalysts for biodiesel production:a review[J].Fuel Processing Technology,2009,90(6):770-777.
[2] 杨振强,谢文磊,李海涛.酸催化油脂酯交换反应研究进展[J].粮食与油脂,2006(3):13-15.
[3] LOTERO E,LIU Y,LOPEZ D E,et al.Synthesis of biodiesel via acid catalysis[J].Industrial & Engineering Chemistry Research, 2005,44(14):5353-5363.
[4] ZHANG G M,HUANG J,HUANG G R,et al.Molecular cloning and heterologous expression of a new xylanase gene from Plectosphaerella cucumerina[J]. Applied Microbiology and Biotechnology,2007,74(2):339-346.
[5] MELERO J A,IGLESIAS J,MORALES G.Heterogeneous acid catalysts for biodiesel production:current status and future challenges[J].Green Chemistry,2009,11(9):1285-1308.
[6] 李翔宇,蒋剑春,王奎,等.生物柴油酯交换反应机理和影响因素分析[J].生物质化学工程,2010,44(3):1-5.
[7] 李会鹏,姜玉琦,赵华.介孔分子筛负载HPWA催化合成生物柴油[J].工业催化,2010(8):56-60.
[8] NGU T A,LI Z.Phosphotungstic acid-functionalized magnetic nanoparticles as an efficient and recyclable catalyst for the one-pot production of biodiesel from grease via esterification and transesterification[J].Green Chemistry,2014,16(3):1202-1210.
[9] ZHANG S,ZU Y G,FU Y J,et al.Rapid microwave-assisted transesterification of yellow horn oil to biodiesel using a heteropolyacid solid catalyst[J].Bioresource Technology,2010,101(3):931-936.
[10] BADDAY A S,ABDULLAH A Z,LEE K T.Optimization of biodiesel production process from Jatropha oil using supported heteropolyacid catalyst and assisted by ultrasonic energy[J].Renewable Energy,2013,50:427-432.
[11] TALEBIAN-Kiakalaieh A, AMIN N A S, ZAREI A, et al.Transesterification of waste cooking oil by heteropoly acid(HPA) catalyst:optimization and kinetic model[J].Applied Energy,2013, 102:283-292.
[12] RAMACHANDRAN K, SIVAKUMAR P, SUGANYA T, et al.Production of biodiesel from mixed waste vegetable oil using an aluminium hydrogen sulphate as a heterogeneous acid catalyst[J].Bioresource Technology,2011,102(15):7289-7293.
[13] 曹宏远,曹维良,张敬畅.固体酸Zr(SO₄)₂·4H₂O催化制备生物柴油[J].北京化工大学学报,2005,32(6):61-63.
[14] LAM M K,LEE K T,MOHAMED A R.Sulfated tin oxide as solid superacid catalyst for transesterification of waste cooking oil:an optimization study[J].Applied Catalysis B:Environmental,2009, 93(1):134-139.
[15] 王志华,孙小嫚,孙桂芳,等.固体超强酸SO₄^2-/Fe₂O₃催化制备生物柴油的研究[J].中国油脂,2007,32(8):59-62.
[16] 王志华,孙小嫚,孙桂芳,等.固体超强酸S₂O₈^2-/Fe₂O₃-ZrO₂-La₂O₃催化制备生物柴油[J].北京化工大学学报(自然科学版),2007, 34(5):544-548.
[17] YOO S J,LEE H,VERIANSYAH B,et al.Synthesis of biodiesel from rapeseed oil using supercritical methanol with metal oxide catalysts[J].Bioresource Technology,2010,101(22):8686-8689.
[18] FURUTA S,MATSUHASHI H,ARATA K.Biodiesel fuel production with solid superacid catalysis in fixed bed reactor under atmospheric pressure[J].Catalysis Communications,2004,5(12):721-723.
[19] PARK Y M,LEE J Y,CHUNG S H,et al.Esterification of used vegetable oils using the heterogeneous WO₃/ZrO₂ catalyst for production of biodiesel[J].Bioresource Technology,2010,101(1):S59-S61.
[20] 王春蓉.沸石分子筛的性能与应用研究[J].化学与粘合,2010(4):76-78.
[21] PUROVA R,NARASIMHARAO K,AHMED N S I,et al.Pillared HMCM-36 zeolite catalyst for biodiesel production by esterification of palmitic acid[J].Journal of Molecular Catalysis A:Chemical, 2015,406:159-167.
[22] CARMO A C,SOUZA L K C,COSTA C E F,et al.Production of biodiesel by esterification of palmitic acid over mesoporous aluminosilicate Al-MCM-41[J].Fuel,2009,88(3):461-468.
[23] 兰战伟,耿欢欢,王姗姗,等.改性MCM-41催化高酸值油脂制备生物柴油[J].石油化工应用,2014,33(11):80-83.
[24] 兰战伟,耿欢欢,王姗姗,等.改性4A分子筛催化高酸值油脂制备生物柴油[J].化工技术与开发,2014(11):1-3.
[25] CHUNG K H,CHANG D R,PARK B G.Removal of free fatty acid in waste frying oil by esterification with methanol on zeolite catalysts[J].Bioresource Technology,2008,99(16):7438-7443.
[26] 张秋云,杨松,李虎.制备生物柴油的固体酸催化剂研究进展[J].化工进展,2013,32(3):575-583.
[27] FENG Y,HE B,CAO Y,et al.Biodiesel production using cation-exchange resin as heterogeneous catalyst[J]. Bioresource Technology,2010,101(5):1518-1521.
[28] TEO H T R,SAHA B.Heterogeneous catalysed esterification of acetic acid with isoamyl alcohol:kinetic studies[J].Journal of Catalysis,2004,228(1):174-182.
[29] SON S M,KIMURA H,KUSAKABE K.Esterification of oleic acid in a three-phase,fixed-bed reactor packed with a cation exchange resin catalyst[J].Bioresource Technology,2011,102(2):2130-2132.
[30] 霍稳周,史作然,刘野,等.耐高温强酸性阳离子交换树脂催化桐油酯化反应性能研究[J].中国油脂,2014,39(12):58-61.
[31] LIU Y,WANG L.Bio-diesel preparation from waste oil using cation exchange resin as heterogeneous catalyst[J]. Chemistry and Technology of Fuels and Oils,2009,45(6):417-424.
[32] 奚立民,柯中炉,陈建军.固定床中树脂催化油脂副产物制备生物柴油[J].离子交换与吸附,2007,23(3):223-229.
[33] JIANG Y,LU J,SUN K,et al.Esterification of oleic acid with ethanol catalyzed by sulfonated cation exchange resin:experimental and kinetic studies[J].Energy Conversion and Management,2013, 76:980-985.
[34] FU J,CHEN L,LV P,et al.Free fatty acids esterification for biodiesel production using self-synthesized macroporous cation exchange resin as solid acid catalyst[J].Fuel,2015,154:1-8.

固体酸催化制备生物柴油研究进展

Research progress in preparation of biodiesel with solid acid catalyst

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	金鑫, 李玉姗, 解青青, 王梦雨, 夏星帆, 杨朝合. 多孔材料催化丙酮缩甘油合成研究进展[J]. 化工进展, 2023, 42(2): 731-743.
[2]	秦振芳, 廖日红, 马伟芳. 吸收-微藻法固定燃气电厂低浓度CO₂同步产油技术研究进展[J]. 化工进展, 2023, 42(1): 94-106.
[3]	黄伟, 储政, 任磊, 李珊. 碳基固体酸在硝基苯加氢制备对氨基苯酚中的应用[J]. 化工进展, 2023, 42(1): 272-281.
[4]	赵建兵, 杨丹, 舒原草, 朱俊波, 普仕萍, 宋晓丹, 刘守庆, 柴希娟, 李雪梅. Na₂CO₃/CF固体碱对菜籽油酯交换反应的催化性能[J]. 化工进展, 2022, 41(7): 3608-3614.
[5]	邹鹏程, 金光远, 李臻峰, 宋春芳, 韩太柏, 祝玉莲. 一种具有模式搅拌的微波反应釜内多物理场特性分析[J]. 化工进展, 2022, 41(5): 2301-2310.
[6]	陈丹阳, 朱建宇, 吴勤, 王自庆, 张金利. KF/MgO催化甘油和碳酸二甲酯酯交换合成甘油碳酸酯[J]. 化工进展, 2022, 41(4): 2082-2089.
[7]	马鑫, 王霜, 李法社, 张逸水, 蒋上. 生物柴油雾化特性仿真模拟及实验研究[J]. 化工进展, 2022, 41(2): 655-665.
[8]	纪淑兰, 李迅, 王飞. 丝瓜络固定化米根霉催化光皮树油制备生物柴油[J]. 化工进展, 2022, 41(10): 5381-5389.
[9]	朱长辉, 朱文超, 罗嘉, 田保河, 孙佳琳, 邹志云. 微波强化酯交换反应制备生物柴油研究进展[J]. 化工进展, 2022, 41(10): 5145-5154.
[10]	岳倩倩, 高李璟, 肖国民, 魏瑞平, 雷严. 生物柴油连续化生产设备及工艺进展[J]. 化工进展, 2021, 40(S2): 81-88.
[11]	邹帅, 李玉芹, 马怡然, 齐振华, 贾权威. 二乙醇胺强化胶球藻Coccomyxa subellipsoidea C-169固定CO₂和积累油脂[J]. 化工进展, 2021, 40(9): 5222-5230.
[12]	包文君, 李子富, 王雪梅, 高瑞岭, 程世昆, 门玉. 产油酵母利用廉价原料合成油脂的研究进展[J]. 化工进展, 2021, 40(5): 2484-2495.
[13]	陶宁, 徐亚津, 冯宇辰, 吕建华, 刘继东. ZrO₂-Al₂O₃复合氧化物催化反应精馏合成碳酸二甲酯[J]. 化工进展, 2021, 40(5): 2603-2612.
[14]	陆佳, 刘伟, 王欣, 苏小红, 范超. 玉米秸秆衍生碳基固体酸的制备及其催化纤维素水解糖化[J]. 化工进展, 2020, 39(9): 3635-3642.
[15]	孟心宇, 徐杰, 万杰, 刘雁军, 王晓丽, 张君, 郑锋, 阚建飞, 吴功德. 碳酸甘油酯的合成研究及产业化进展[J]. 化工进展, 2020, 39(9): 3739-3749.