化工进展 ›› 2016, Vol. 35 ›› Issue (S2): 340-346.DOI: 10.16085/j.issn.1000-6613.2016.s2.061

• 资源与环境化工 • 上一篇    下一篇

过氧化钙在城镇黑臭水体修复中的作用

李亮1,2, 武成辉1,2, 陈涛1, 林翰志1,2, 晏波1, 肖贤明1   

  1. 1. 中国科学院广州地球化学研究所有机国家重点实验室和广东省环境资源利用与保护重点实验室, 广东 广州 510640;
    2. 中国科学院大学, 北京 100049
  • 收稿日期:2016-06-27 修回日期:2016-07-28 出版日期:2016-12-31 发布日期:2016-12-22
  • 通讯作者: 晏波,博士,研究方向为水污染治理与资源回收。E-mail:yanbo2007@gig.ac.cn。
  • 作者简介:李亮(1990-),男,硕士研究生。
  • 基金资助:
    广州市科学(技术)研究专项重点项目(201505192330218)、广东省科技计划(2014B090901040,2014B030301060)及广东省省级环保专项资金项目(粤财工2014-176号)。

Effect of calcium peroxide on the restoration of black and odorous water in towns

LI Liang1,2, WU Chenghui1,2, CHEN Tao1, LIN Hanzhi1,2, YAN Bo1, XIAO Xianming1   

  1. 1. State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China;
    2. University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2016-06-27 Revised:2016-07-28 Online:2016-12-31 Published:2016-12-22

摘要: 我国城镇水体污染严重,本文根据城镇黑臭水体污染与生态修复治理技术现状,分析得出水体缺氧是导致城镇水体黑臭污染的主要原因以及复氧措施在治理黑臭水体时的重要性,介绍了水体原位复氧具有对水体扰动小、修复效果明显和不产生二次污染等优点,但常规复氧措施存在工程规模大、设备运行昂贵和后期仪器维护贵等问题。结合CaO2在黑臭水体原位治理过程的高效释氧、强化微生物活性及释放羟基自由基等特性,简述了CaO2对黑臭水体中有机物、重金属、氮磷营养元素及硫化物等污染物的去除机理与修复效果;通过归纳CaO2在黑臭水体修复过程中的不足,建议在CaO2对污染物的降解机理和缓释型CaO2复合释氧剂等方面应加强研究;指出缓释型CaO2复合释氧剂在城镇黑臭水体生态修复治理中具有重要实际意义。

关键词: 黑臭水体, 过氧化钙, 需氧, 原位修复

Abstract: Based on the current situation about black and odorous water and the technology of ecological restoration in towns of our country.The primary cause of black and odorous waste water is hypoxia status in water and the important of reoxygenation measures in repairing black and odorous water are obtained.The advantages of in-situ remediation are introduced,such as little disturbance、result is obvious and does not have secondary pollution in water,but the weakness about needing a large scale project,high price and cost of daily operating and maintain of conventional reoxygenation measures are shown.The effect of CaO2 on releasing oxygen efficiently,intensifying the microbial activitily and releasing hydroxyl radicals in restoring the black and odorous water.The removal mechanism and the remediation effect of CaO2 on organic matters,heavy metals,nitrogen and phosphorus nutrition elements and sulfide in black and odorous water are illustrated.The disadvantage of the black and odorous water restored by CaO2 were summared.The mechanism of degradation to pollutants by CaO2,sustained-release compound oxygen release agent are suggested to be more researched.The importance of sustained-release of CaO2 in practical significance is proposed.

Key words: black and odorous waste water, calcium peroxide, aerobic, in-situ remediation

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