新型磺酸基Gemini表面活性剂的合成及其在油气井中的应用性能

doi:10.16085/j.issn.1000-6613.2017-1322

化工进展 ›› 2018, Vol. 37 ›› Issue (05): 1956-1961.DOI: 10.16085/j.issn.1000-6613.2017-1322

新型磺酸基Gemini表面活性剂的合成及其在油气井中的应用性能

赖小娟^1,2, 汪洁¹, 王磊^1,2, 范华波³, 赵倩云³, 穆瑞花⁴

1 陕西科技大学化学与化工学院, 陕西西安 710021;
2 陕西农产品加工技术研究院, 陕西西安 710021;
3 中国石油长庆油田分公司油气工艺研究院, 陕西西安 710021;
4 西安工程大学环境与化学工程学院, 陕西西安 710048

收稿日期:2017-06-30 修回日期:2017-07-30 出版日期:2018-05-05 发布日期:2018-05-05
通讯作者: 赖小娟(1984-),女,博士,教授。
作者简介:赖小娟(1984-),女,博士,教授。E-mail:3578466@163.com。
基金资助:
陕西省工业科技攻关项目（2016GY-241，2016GY-193）及陕西省协同创新项目（2015XT-58）。

Synthesis of a novel sulfate Gemini surfactant and its application in oilfield

LAI Xiaojuan^1,2, WANG Jie¹, WANG Lei^1,2, FAN Huabo³, ZHAO Qianyun³, MU Ruihua⁴

1 College of Chemistry & Chemical Engineering, Shaanxi University of Science & Tecnology, Xi'an 710021, Shaanxi, China;
2 Shaanxi Research Institute of Agricultural Products Processing Technology, Xi'an 710021, Shaanxi, China;
3 Research Institute of Oil/Gas Technology, Changqing Oilfield Branch Company, PetroChina, Xi'an 710021, Shaanxi, China;
4 School of Environmental and Chemical Engineering, Xi'an Polytechnic University, Xi'an 710048, Shaanxi, China

Received:2017-06-30 Revised:2017-07-30 Online:2018-05-05 Published:2018-05-05

摘要/Abstract

摘要： 以油酸酰胺丙基叔胺、3-氯-2-羟基丙磺酸钠和1，4-二溴丁烷为原料，通过两步反应合成了一种甜菜碱双子表面活性剂B18-4-18，通过傅里叶变换红外光谱仪和核磁共振波谱仪对合成产物进行了结构表征，用表面张力仪测定不同浓度下的双子表面活性剂（B18-4-18）的表面张力，用携液率装置测定了其在清水中、矿化水中、凝析油溶液中、甲醇溶液中的携液率，用罗氏泡高仪测定不同类型表面活性剂的泡沫高度。结果表明：合成产物与预期目标产物结构一致，在25℃时，B18-4-18的临界胶束浓度CMC为5.0×10^-6mol/L，相应的表面张力γ_cmc为31.67mN/m；质量分数为0.5%的B18-4-18在清水、矿化水、凝析油溶液、甲醇溶液中的最高携液率分别可以达到90%、87%、78%、87%；对比不同的表面活性剂的泡沫性能，优选出在泡沫酸中使用最佳的起泡剂为B18-4-18。

关键词: 甜菜碱, 双子表面活性剂, 泡排剂, 泡沫酸, 起泡剂

Abstract: A type of betaine Gemini surfactant (B18-4-18)was synthesized by two-step reaction with N-(3-dimethylaminopropyl) oleoylamide,3-chloro-2-hydroxypropanesulfonate,and 1,4-dibromobutane as main raw materials. The structure of the product was characterized by Fourier transform infrared spectroscopy and ¹H nuclear magnetic resonance spectrum. The surface tension curve and related parameters were acquired by surface tension measurements. Liquid carrying rates of B18-4-18 were measured by carrying capacity ratio measurement device in water,mineralized water,methanol solution,and condensate solution,respectively. The foam heights with different types of surfactants were determined by a Roche bubble instrument. The experimental results showed that the structure of the synthesized compounds was in conformity with the expected structure of surfactant. The critical micelle concentration of B18-4-18 was 5.0×10^-6 mol/L;the corresponding surface tension was 31.67mN/m at 25℃. The highest carrying capacities of the B18-4-18 with the mass fraction of 0.5% were 90%,87%,78% and 87% in water,in mineral water,in methanol solution and in condensate solution,respectively. In contrast to the foaming properties of other surfactants,for the foam acid, the best foaming agent is the B18-4-18.

Key words: betaine, Gemini surfactant, foam drainage agent, foam acid, foaming agent

中图分类号:

TQ423.9

赖小娟, 汪洁, 王磊, 范华波, 赵倩云, 穆瑞花. 新型磺酸基Gemini表面活性剂的合成及其在油气井中的应用性能[J]. 化工进展, 2018, 37(05): 1956-1961.

LAI Xiaojuan, WANG Jie, WANG Lei, FAN Huabo, ZHAO Qianyun, MU Ruihua. Synthesis of a novel sulfate Gemini surfactant and its application in oilfield[J]. Chemical Industry and Engineering Progress, 2018, 37(05): 1956-1961.

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新型磺酸基Gemini表面活性剂的合成及其在油气井中的应用性能

Synthesis of a novel sulfate Gemini surfactant and its application in oilfield

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