聚苯乙烯磺酸钠对掺混聚偏氟乙烯阴离子交换膜的改性表征

doi:10.16085/j.issn.1000-6613.2021-1552

化工进展 ›› 2021, Vol. 40 ›› Issue (S2): 290-294.DOI: 10.16085/j.issn.1000-6613.2021-1552

聚苯乙烯磺酸钠对掺混聚偏氟乙烯阴离子交换膜的改性表征

陈志华¹^,²(), 周键¹^,²(), 王三反¹^,²

^1.甘肃省黄河水环境重点实验室，兰州交通大学，甘肃兰州 730070
^2.兰州交通大学环境与市政工程学院，甘肃兰州 730070

收稿日期:2021-07-21 修回日期:2021-08-01 出版日期:2021-11-12 发布日期:2021-11-12
通讯作者: 周键
作者简介:陈志华（1994—），男，硕士研究生，研究方向为离子交换膜的改性、水资源综合利用。E-mail：329543089@qq.com。
基金资助:
甘肃省科技计划(20JR2RA002);国家自然科学基金(51804150);国家十二五科技支撑计划(2015BAE04B01);兰州交通大学“天佑青年托举人才计划”

Modified characterization of sodium polystyrene sulfonate to a mixed PVDF anion exchange membrane

CHEN Zhihua¹^,²(), ZHOU Jian¹^,²(), WANG Sanfan¹^,²

^1.Key laboratory of Yellow River Water Environment in Gansu Province, Lanzhou Jiaotong University, Lanzhou 730070, Gansu, China
^2.School of Environment and Manicipal Enginnering, Lanzhou Jiaotong University, Lanzhou 730070, Gansu, China

Received:2021-07-21 Revised:2021-08-01 Online:2021-11-12 Published:2021-11-12
Contact: ZHOU Jian

摘要/Abstract

摘要：

聚苯乙烯磺酸钠（PSS）因含有强电离作用的负电荷基团（磺酸基团）可以和聚偏氟乙烯（PVDF）一起改性阴离子交换膜，使膜在提高稳定性的前提下，保证其他性能。本实验采用浸润改性法，用PSS浸润改性添加了PVDF的阴离子交换膜。探讨了PSS含量对膜性能的影响，如膜电阻、离子交换容量、含水率和选择透过性。利用红外光谱仪及扫描电子显微镜表征手段对膜表面性质和结构进行了分析。结果表明，当PSS含量增加时，膜面电阻先降低后升高，离子交换容量和含水率升高，离子选择透过性先升高后降低。虽然PVDF的添加使阴离子交换膜除稳定性外的其他性能下降，但PSS的浸润改性弥补了这一缺陷，这使得PSS与PVDF复合改性的阴离子交换膜具有一定的实用价值。

关键词: 聚苯乙烯磺酸钠, 聚偏氟乙烯, 离子交换, 选择性, 膜

Abstract:

The negative charge group (sulfonic acid group) can modify the sulfonic exchange membrane together with PVDF, so that the film ensures other properties under the premise of improving stability. The PVDF anion exchange membrane was added with sodium polystyrene sulfonate. The effects of sodium polystyrene sulfonate on membrane properties, such as membrane resistance, ion exchange capacity, water content and selective permeability are discussed. The surface properties and structure of PVDF films were analyzed by infrared spectrometer and scanning electron microscopy. The results show that when the content of sodium polystyrene sulfonate increases, the membrane resistance decreases, the ion exchange capacity and water content increases, and the permeability of antiion selection increases. Although the addition of PVDF reduces the anion exchange film performance except stability, the infiltration modification of sodium polystyrene sulfonate compensates for this defect, which makes the sodium polystyrene sulfonate and PVDF composite modified stress ion exchange film useful.

Key words: sodium polystyrene sulfonate, polyvinyl partial fluoride, ion exchange, selectivity, membrane

中图分类号:

TQ028

陈志华, 周键, 王三反. 聚苯乙烯磺酸钠对掺混聚偏氟乙烯阴离子交换膜的改性表征[J]. 化工进展, 2021, 40(S2): 290-294.

CHEN Zhihua, ZHOU Jian, WANG Sanfan. Modified characterization of sodium polystyrene sulfonate to a mixed PVDF anion exchange membrane[J]. Chemical Industry and Engineering Progress, 2021, 40(S2): 290-294.

图/表 5

图1 测量膜电阻等效装置

图2 PSS含量对离子交换容量和含水率的影响

图3 不同PSS含量对膜电阻和选择透过性的影响

图4 不同PSS含量膜的FTIR光谱图

图5 不同PSS含量下膜截面SEM图

参考文献 16

1	VASELBEHAGH M, KARKHANECHI H, TAKAGI R, et al. Effect of polydopamine coating and direct electric current application on anti-biofouling properties of anion exchange membranes in electrodialysis[J]. Journal of Membrane Science, 2016, 515: 98-108.
2	魏慧, 吴学昊, 管佳, 等. 离子交换膜改性的研究现状及发展趋势[J]. 无机盐工业, 2016, 48(6): 1-4.
	WEI Hui, WU Xuehao, GUAN Jia, et al. Present status and development trend of modification of ion-exchange membranes[J]. Inorganic Chemicals Industry, 2016, 48(6): 1-4.
3	李健, 徐燕青, 阮慧敏, 等. 单价选择性阳离子交换膜的研究进展[J]. 膜科学与技术, 2015, 35(3): 113-120.
	LI Jian, XU Yanqing, RUAN Huimin, et al. Monovalent cation selective membranes: state and development perspective[J]. Membrane Science and Technology, 2015, 35(3): 113-120.
4	ZHANG Xuemin, ZHOU Jian, ZOU Xin, et al. Preparation of nano-SiO₂/Al₂O₃/ZnO-blended PVDF cation-exchange membranes with improved membrane permselectivity and oxidation stability[J]. Materials, 2018, 11(12): 2465.
5	STENINA I, GOLUBENKO D, NIKONENKO V, et al. Selectivity of transport processes in ion-exchange membranes: relationship with the structure and methods for its improvement[J]. International Journal of Molecular Sciences, 2020, 21(15): 5517.
6	PAWLOWSKI S, CRESPO J G, VELIZAROV S. Profiled ion exchange membranes: a comprehensible review[J]. International Journal of Molecular Sciences, 2019, 20(1): 165.
7	MUBITA T, PORADA S, AERTS P, et al. Heterogeneous anion exchange membranes with nitrate selectivity and low electrical resistance[J]. Journal of Membrane Science, 2020, 607: 118000.
8	唐致远, 薛建军, 李建刚, 等. 聚合物电解质离子迁移数的测定方法[J]. 化学通报, 2001, 64(5): 308, 312-315.
	TANG Zhiyuan, XUE Jianjun, LI Jiangang, et al. The progress of measurement of transference number in solid polymer electrolyte[J]. Chemistry, 2001, 64(5): 308, 312-315.
9	ZHAO Zhijuan, SHI Shaoyuan, CAO Hongbin, et al. Layer-by-layer assembly of anion exchange membrane by electrodeposition of polyelectrolytes for improved antifouling performance[J]. Journal of Membrane Science, 2018, 558: 1-8.
10	ZHAO Zhijuan, CAO Hongbin, SHI Shaoyuan, et al. Characterization of anion exchange membrane modified by electrodeposition of polyelectrolyte containing different functional groups[J]. Desalination, 2016, 386: 58-66.
11	CHANDRA A, BHUVANESH E, MANDAL P, et al. Surface modification of anion exchange membrane using layer-by-layer polyelectrolytes deposition facilitating monovalent organic acid transport[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2018, 558: 579-590.
12	张学敏. PVDF磺化阳离子交换膜的制备、表征与应用研究[D]. 兰州: 兰州交通大学, 2019.
	ZHANG Xuemin. Preparation, characterization and application of cation exchange membranes based sulfonated PVDF[D]. Lanzhou: Lanzhou Jiatong University, 2019.
13	张亚涛, 李启明, 王三反, 等. ZrP/PVDF杂化阳离子交换膜的制备及性能[J]. 有色金属工程, 2019, 9(3): 13-18.
	ZHANG Yatao, LI Qiming, WANG Sanfan, et al. Preparation and properties of ZrP/PVDF hybrid cationic exchange membranes[J]. Nonferrous Metals Engineering, 2019, 9(3): 13-18.
14	余宗学, 曾广勇, 潘洋, 等. 纳米Al₂O₃和TiO₂对PVDF膜结构与性能的影响[J]. 工程塑料应用, 2015, 43(2): 11-15.
	YU Zongxue, ZENG Guangyong, PAN Yang, et al. Effects of Al₂O₃ and TiO₂ nanoparticles on structure and performance of PVDF membrane[J]. Engineering Plastics Application, 2015, 43(2): 11-15.
15	BENGANI-LUTZ P, CONVERSE E, CEBE P, et al. Self-assembling zwitterionic copolymers as membrane selective layers with excellent fouling resistance: effect of zwitterion chemistry[J]. ACS Applied Materials & Interfaces, 2017, 9(24): 20859-20872.
16	ZHAO Yan, LI Yi, YUAN Shushan, et al. A chemically assembled anion exchange membrane surface for monovalent anion selectivity and fouling reduction[J]. Journal of Materials Chemistry A, 2019, 7(11): 6348-6356.

[1]	张祚群, 高扬, 白超杰, 薛立新. 二次界面聚合同步反扩散原位生长ZIF-8纳米粒子制备聚酰胺混合基质反渗透（RO）膜[J]. 化工进展, 2023, 42(S1): 364-373.
[2]	王乐乐, 杨万荣, 姚燕, 刘涛, 何川, 刘逍, 苏胜, 孔凡海, 朱仓海, 向军. SCR脱硝催化剂掺废特性及性能影响[J]. 化工进展, 2023, 42(S1): 489-497.
[3]	李化全, 王明华, 邱贵宝. 硫酸酸解钙钛矿相精矿的行为[J]. 化工进展, 2023, 42(S1): 536-541.
[4]	邓丽萍, 时好雨, 刘霄龙, 陈瑶姬, 严晶颖. 非贵金属改性钒钛基催化剂NH₃-SCR脱硝协同控制VOCs[J]. 化工进展, 2023, 42(S1): 542-548.
[5]	王晋刚, 张剑波, 唐雪娇, 刘金鹏, 鞠美庭. 机动车尾气脱硝催化剂Cu-SSZ-13的改性研究进展[J]. 化工进展, 2023, 42(9): 4636-4648.
[6]	朱传强, 茹晋波, 孙亭亭, 谢兴旺, 李长明, 高士秋. 固体高分子脱硝剂选择性非催化还原NO _x 特性[J]. 化工进展, 2023, 42(9): 4939-4946.
[7]	徐杰, 夏隆博, 罗平, 邹栋, 仲兆祥. 面向膜蒸馏过程的全疏膜制备及其应用进展[J]. 化工进展, 2023, 42(8): 3943-3955.
[8]	李雪佳, 李鹏, 李志霞, 晋墩尚, 郭强, 宋旭锋, 宋芃, 彭跃莲. 亲水和疏水改性膜的抗结垢和润湿能力的对比[J]. 化工进展, 2023, 42(8): 4458-4464.
[9]	毛善俊, 王哲, 王勇. 基团辨识加氢：从概念到应用[J]. 化工进展, 2023, 42(8): 3917-3922.
[10]	王报英, 王皝莹, 闫军营, 汪耀明, 徐铜文. 聚合物包覆膜在金属分离回收中的研究进展[J]. 化工进展, 2023, 42(8): 3990-4004.
[11]	向阳, 黄寻, 魏子栋. 电催化有机合成反应的活性和选择性调控研究进展[J]. 化工进展, 2023, 42(8): 4005-4014.
[12]	王耀刚, 韩子姗, 高嘉辰, 王新宇, 李思琪, 杨全红, 翁哲. 铜基催化剂电还原二氧化碳选择性的调控策略[J]. 化工进展, 2023, 42(8): 4043-4057.
[13]	王晓晗, 周亚松, 于志庆, 魏强, 孙劲晓, 姜鹏. 不同晶粒尺寸Y分子筛的合成及其加氢裂化反应性能[J]. 化工进展, 2023, 42(8): 4283-4295.
[14]	潘宜昌, 周荣飞, 邢卫红. 高效分离同碳数烃的先进微孔膜：现状与挑战[J]. 化工进展, 2023, 42(8): 3926-3942.
[15]	李佳, 樊星, 陈莉, 李坚. 硝酸生产尾气中NO _x 和N₂O联合脱除技术研究进展[J]. 化工进展, 2023, 42(7): 3770-3779.

聚苯乙烯磺酸钠对掺混聚偏氟乙烯阴离子交换膜的改性表征

Modified characterization of sodium polystyrene sulfonate to a mixed PVDF anion exchange membrane

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 5

参考文献 16

相关文章 15

编辑推荐

Metrics

本文评价