华东地区某市重点行业优控环境激素的筛选及分布特征

doi:10.16085/j.issn.1000-6613.2018-0934

摘要/Abstract

摘要：

为筛选华东地区某市重点行业优先控制环境激素，基于美国“内分泌干扰物筛选计划”、欧盟“内分泌干扰物共同体战略”等研究，本文整理得到重点关注环境激素名单，并对其在该市重点行业企业的生产使用情况进行了调查。结果表明，壬基酚、双酚、乙草胺等51种重点关注环境激素中，13种在重点行业企业的生产和使用中被涉及。根据上述13种环境激素的生产、使用量和涉及企业数等，进一步筛选得到4种建议区域优先控制环境激素，分别为苯乙烯、双酚A、邻苯二甲酸二乙酯和邻苯二甲酸二丁酯。从地区分布上看，4种建议区域优先控制环境激素的生产和使用主要集中在工业聚集区，主要涉及的行业为化学原料和化学制品制造业。研究结果为筛选优先控制环境激素、进一步识别其风险、重点突出地加强对其的管理和控制提供了理论依据。

关键词: 环境激素, 优先控制, 地区分布, 行业分布

Abstract:

In order to screen out environmental hormones for priority control in key industries of a city in East China, based on the US “Screening Plan for Endocrine Disruptors” and EU “Community Strategy for Endocrine Disruptors”, a list of environmental hormones including 51 chemicals was sorted out and the production and use of enterprises in key industries in the city were investigated. The results showed that among key 51 environmental hormones, including nonylphenol, bisphenol and ethoxamine, 13 of them were involved in the production and use of investigated key industrial enterprises. Furthermore, four of them, namely styrene, bisphenol A, diethyl phthalate and dibutyl phthalate, were screened as regional priority control environmental hormones, based on their production and consumption, as well as the enterprises involved in this city. The enterprises refer to four recommended regional priority environmental hormones are mainly located in chemical industrial park, and mainly involving chemical materials and chemical products industry. The results provide a theoretical basis for screening environmental hormones, further identifying their risks, and emphatically strengthening their management and control.

Key words: environmental hormones, priority control, regional distribution, industrial distribution

中图分类号:

X321

侯爽,隋倩. 华东地区某市重点行业优控环境激素的筛选及分布特征[J]. 化工进展, 2019, 38(02): 1140-1145.

Shuang HOU,Qian SUI. Screening and distribution of priority environmental hormones in the key industrial sectors in a city of East China[J]. Chemical Industry and Engineering Progress, 2019, 38(02): 1140-1145.

图/表 5

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序号	环境激素	欧盟	日本	美国	WHO	《我们被偷走的未来》网站
1	乙草胺	√		√	√	√
2	甲草胺	√	√	√	√	√
3	苯并(a)芘	√	√		√	√
4	六氯苯	√	√	√	√
5	五氯酚	√	√		√	√
6	全氟辛烷磺酸酯	√	√	√	√	√

序号	环境激素	欧盟	日本	美国	WHO	《我们被偷走的未来》网站
1	乙草胺	√		√	√	√
2	甲草胺	√	√	√	√	√
3	苯并(a)芘	√	√		√	√
4	六氯苯	√	√	√	√
5	五氯酚	√	√		√	√
6	全氟辛烷磺酸酯	√	√	√	√	√

序号	环境激素	欧盟	日本	美国	WHO	《我们被偷走的未来》网站
7	多氯代联苯	√	√	√	√
8	苯乙烯	√	√	√	√
9	乙烯菌核利	√	√	√	√	√
10	福美锌	√	√	√	√	√
11	氯丹		√	√	√	√
12	开蓬		√	√	√	√
13	灭蚊灵		√	√	√	√
14	毒杀芬		√	√	√	√
15	滴滴涕		√	√	√	√
16	代森锰		√	√	√	√
17	代森锌		√	√	√	√
18	莠去津		√	√	√	√
19	除草醚		√	√	√	√
20	邻苯二甲酸丁苄酯		√	√	√	√
21	邻苯二甲酸二正丁酯		√	√	√	√
22	双酚A		√	√	√	√
23	艾氏剂		√	√	√	√
24	狄氏剂		√	√	√	√
25	硫丹		√	√	√	√
26	氧氯丹		√	√	√	√
27	三氯杀螨醇		√	√	√	√
28	马拉硫磷		√	√	√	√
29	七氯		√	√	√	√
30	丁基羟基茴香醚				√	√
31	敌草隆			√	√
32	乙烯硫脲				√	√
33	林丹			√	√	√
34	四氯乙烯			√	√
35	壬基酚			√	√	√
36	多菌灵			√	√	√
37	异狄氏剂		√	√	√
38	2,4-二氯苯氧乙酸		√	√	√
39	异菌脲			√	√	√
40	西玛津		√	√	√
41	三唑酮			√	√	√
42	S-氰戊菊酯		√		√	√
43	甲萘威		√		√	√
44	灭多威		√		√	√
45	氰戊菊酯		√		√	√
46	氯氰菊酯		√		√	√
47	嗪草酮		√		√	√
48	甲氧滴滴涕		√		√	√
49	氟乐灵		√		√	√
50	邻苯二甲酸二乙酯		√		√	√
51	二苯甲酮		√		√	√

序号	环境激素	欧盟	日本	美国	WHO	《我们被偷走的未来》网站
7	多氯代联苯	√	√	√	√
8	苯乙烯	√	√	√	√
9	乙烯菌核利	√	√	√	√	√
10	福美锌	√	√	√	√	√
11	氯丹		√	√	√	√
12	开蓬		√	√	√	√
13	灭蚊灵		√	√	√	√
14	毒杀芬		√	√	√	√
15	滴滴涕		√	√	√	√
16	代森锰		√	√	√	√
17	代森锌		√	√	√	√
18	莠去津		√	√	√	√
19	除草醚		√	√	√	√
20	邻苯二甲酸丁苄酯		√	√	√	√
21	邻苯二甲酸二正丁酯		√	√	√	√
22	双酚A		√	√	√	√
23	艾氏剂		√	√	√	√
24	狄氏剂		√	√	√	√
25	硫丹		√	√	√	√
26	氧氯丹		√	√	√	√
27	三氯杀螨醇		√	√	√	√
28	马拉硫磷		√	√	√	√
29	七氯		√	√	√	√
30	丁基羟基茴香醚				√	√
31	敌草隆			√	√
32	乙烯硫脲				√	√
33	林丹			√	√	√
34	四氯乙烯			√	√
35	壬基酚			√	√	√
36	多菌灵			√	√	√
37	异狄氏剂		√	√	√
38	2,4-二氯苯氧乙酸		√	√	√
39	异菌脲			√	√	√
40	西玛津		√	√	√
41	三唑酮			√	√	√
42	S-氰戊菊酯		√		√	√
43	甲萘威		√		√	√
44	灭多威		√		√	√
45	氰戊菊酯		√		√	√
46	氯氰菊酯		√		√	√
47	嗪草酮		√		√	√
48	甲氧滴滴涕		√		√	√
49	氟乐灵		√		√	√
50	邻苯二甲酸二乙酯		√		√	√
51	二苯甲酮		√		√	√

序号	中文名称	CAS	使用量 /万吨·年^-1	使用企业数/个
1	苯乙烯	100-42-5	38.25	24
2	双酚A	80-05-7	28.37	9
3	邻苯二甲酸二丁酯	84-74-2	0.32	8
4	壬基酚	25154-52-3	0.067	5
5	邻苯二甲酸二乙酯	84-66-2	0.044	7
6	代森锌	12122-67-7	0.02	2
7	多菌灵	10605-21-7	0.012	3
8	四氯乙烯	127-18-4	0.01	3
9	乙草胺	34256-82-1	0.007	1
10	二苯甲酮	119-61-9	0.002	2
11	异菌脲	36734-19-7	0.001	1
12	三唑酮	43121-43-3	0.00005	1
13	乙烯硫脲	96-45-7	0.0000029	1