化工进展 ›› 2018, Vol. 37 ›› Issue (05): 1823-1830.DOI: 10.16085/j.issn.1000-6613.2017-1444

• 工业催化 • 上一篇    下一篇

SO42-/TiO2-SnO2固体酸催化剂的制备及其催化合成丙烯酸苄酯

潘柳依1,2, 淡勇1, 王军峰3, 牛梦龙4, 范铮4, 李稳宏1   

  1. 1 西北大学化工学院, 陕西 西安 710069;
    2 宝鸡文理学院化学化工学院, 陕西 宝鸡 721013;
    3 陕西延长石油(集团)有限责任公司, 陕西 西安 710075;
    4 西安石油大学化学化工学院, 陕西 西安 710065
  • 收稿日期:2017-07-13 修回日期:2017-12-10 出版日期:2018-05-05 发布日期:2018-05-05
  • 通讯作者: 淡勇,教授,硕士生导师,研究方向为能源化工和化工机械。
  • 作者简介:潘柳依(1990-),女,博士研究生,研究方向为催化合成。E-mail:liuyi88611@163.com。

Preparation of SO42-/TiO2-SnO2 solid acid catalyst and its catalytic activity in synthesis of benzyl acrylate

PAN Liuyi1,2, DAN Yong1, WANG Junfeng3, NIU Menglong4, FAN Zheng4, LI Wenhong1   

  1. 1 School of Chemical Engineering, Northwest University, Xi'an 710069, Shaanxi, China;
    2 School of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721013, Shaanxi, China;
    3 Shaanxi Yanchang Petroleum(Group) Co., Ltd., Xi'an 710075, Shaanxi, China;
    4 College of Chemistry & Chemical Engineering, Xi'an Shiyou University, Xi'an 710065, Shaanxi, China
  • Received:2017-07-13 Revised:2017-12-10 Online:2018-05-05 Published:2018-05-05

摘要: 采用共沉淀法制备了SO42-/TiO2-SnO2固体酸催化剂,利用SEM-EDS、XRD、FTIR、Py-IR、XPS等技术对其进行了表征,结果表明:Sn掺杂会改变催化剂晶型结构与酸性中心的数量和分布情况。在Sn掺杂量为5%、焙烧温度为500℃条件下,将其用于丙烯酸苄酯合成,显示了良好的催化活性。通过对反应条件进行优化,结果表明:酸醇摩尔比为1.3∶1、催化剂用量3%、反应温度120℃时,反应苯甲醇的转化率为93.1%,产物选择性为98.8%。与SO42-/TiO2相比,其反应活性与稳定性显著提高,抗结焦能力增强。

关键词: 固体酸催化剂, 锡掺杂, 丙烯酸苄酯

Abstract: SO42-/TiO2-SnO2 solid acid catalysts prepared by co-precipitation method and then were characterized by SEM-EDS,XRD,FTIR,Pyridine-IR and XPS. The result showed that crystal structure of the catalyst,and the quantity and distribution of the acid centers were changed by doping Sn. The catalyst doped with 5% Sn and calcined at 500℃ showed excellent catalytic activity in the synthesis of benzyl acrylate. Under the optimal conditions of 3% catalyst,reaction temperature of 120℃,and ratio of acid and olefin of 1.3:1,the conversion of phenylcarbinol was 93.1% and the selectivity of the product was 98.8%. Compared with SO42-/TiO2,the reactivity,stability and the anticaking ability were significantly improved.

Key words: solid acid catalyst, Sn doping, benzyl acrylate

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