碳化物衍生碳及其在吸附领域中的应用研究进展

doi:10.16085/j.issn.1000-6613.2017-1012

化工进展 ›› 2018, Vol. 37 ›› Issue (02): 637-643.DOI: 10.16085/j.issn.1000-6613.2017-1012

碳化物衍生碳及其在吸附领域中的应用研究进展

王红妍^1,2,3, 王宝冬¹, 李俊华³, 朱天乐²

1 北京低碳清洁能源研究所, 北京 102209;
2 北京航空航天大学空间与环境学院, 北京 100191;
3 清华大学环境学院, 北京 100084

收稿日期:2017-05-27 修回日期:2017-08-16 出版日期:2018-02-05 发布日期:2018-02-05
通讯作者: 王宝冬,博士,教授级高级工程师,研究方向为环境催化、电厂污染物控制;朱天乐,教授,研究方向为大气污染控制技术与工程。
作者简介:王红妍(1986-),女,博士后。
基金资助:
青年千人启动经费-洁净煤（燃煤电厂）污染物控制项目（GB9300120001）及中国博士后科学基金项目（2017M610724）。

Research progress of carbide-derived carbon and its application in adsorption

WANG Hongyan^1,2,3, WANG Baodong¹, LI Junhua³, ZHU Tianle²

1 National Institute of Clean-and-Low-Carbon Energy, Beijing 102209, China;
2 School of Space and Environment, Beihang University, Beijing 100191, China;
3 School of Environment, Tsinghua University, Beijing 100084, China

Received:2017-05-27 Revised:2017-08-16 Online:2018-02-05 Published:2018-02-05

摘要/Abstract

摘要： 碳化物衍生碳（CDC）是近年来开发的一种具有纳米结构的新型多孔碳材料。该材料是将碳化物前体通过物理（如热分解等）或化学（如卤化等）过程，由表及里逐层刻蚀掉非碳原子得到的，可以实现原子水平上的调控。本文介绍了CDC的制备工艺、性质（孔和形貌）及其在吸附领域中的应用。结果表明，可以通过控制刻蚀温度、碳化物前体、后处理等合成条件实现CDC比表面积大范围可调、孔径及孔径分布等微观结构精确可控，得到从无定形碳到高度有序的石墨、碳纳米管或石墨烯等多种结构。最后指出了解制备过程-结构-性质之间的关系有利于精确调控CDC以满足特定应用的要求。

关键词: 碳化物衍生碳, 纳米材料, 吸附

Abstract: Carbide-derived carbon(CDC) is a new kind of porous carbon materials with nanostructure. CDC is produced by selective extraction of metal atoms via physical (e.g., thermal decomposition) or chemical(e.g., halogenation) processes, and transforming the carbide structure into pure carbon. Its nanostructure can be controlled at atom level. This paper summarizes the synthesis and properties CDC, including its pore and structure, and applications in adsorption. It is shown that its structure such as the specific surface area, pore size and pore size distribution can be controlled accurately by the change of synthesis parameters, resulting in the structure ranges from amorphous carbon to graphite, carbon nanotubes or graphene. Understanding of the processing-structure-properties relationships facilitates tuning of the CDC to meet the requirements of certain application.

Key words: carbide-derived carbon, nanomaterial, adsorption

中图分类号:

TB321
TQ424

王红妍, 王宝冬, 李俊华, 朱天乐. 碳化物衍生碳及其在吸附领域中的应用研究进展[J]. 化工进展, 2018, 37(02): 637-643.

WANG Hongyan, WANG Baodong, LI Junhua, ZHU Tianle. Research progress of carbide-derived carbon and its application in adsorption[J]. Chemical Industry and Engineering Progress, 2018, 37(02): 637-643.

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碳化物衍生碳及其在吸附领域中的应用研究进展

Research progress of carbide-derived carbon and its application in adsorption

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