无机盐阴阳离子对稠油水包油型乳状液稳定性的影响

doi:10.16085/j.issn.1000-6613.2015.08.034

化工进展 ›› 2015, Vol. 34 ›› Issue (08): 3118-3123.DOI: 10.16085/j.issn.1000-6613.2015.08.034

无机盐阴阳离子对稠油水包油型乳状液稳定性的影响

孙娜娜¹, 敬加强^1,2, 丁晔³, 臧欣欣⁴, 邹亮⁵

1 西南石油大学油气藏地质及开发工程国家重点实验室, 四川成都 610500;
2 油气消防四川省重点实验室, 四川成都 611731;
3 新疆油田公司凤城油田作业区, 新疆克拉玛依 834000;
4 青海油田采油二厂开发室, 青海海西 816400;
5 中海石油有限公司天津分公司渤西作业公司, 天津 300452

收稿日期:2015-03-02 修回日期:2015-03-26 出版日期:2015-08-05 发布日期:2015-08-05
通讯作者: 孙娜娜(1987—),女,博士研究生。E-mail bingyuxuan6666@126.com。
作者简介:孙娜娜(1987—),女,博士研究生。E-mail bingyuxuan6666@126.com。
基金资助:
西南石油大学研究生创新基金暨“挑战杯”培育项目(CXJJ 2015030)。

Effects of cationic/anionic electrolytes on the stability of heavy oil-in-water emulsions

SUN Nana¹, JING Jiaqiang^1,2, DING Ye³, ZANG Xinxin⁴, ZOU Liang⁵

1 State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu 610500, Sichuan, China;
2 Oil and Gas Fire Protection Key Laboratory of Sichuan Province, Chengdu 611731, Sichuan, China;
3 Fengcheng Zero of Xinjiang Oilfield, Karamay 834000, Xinjiang, China;
4 The Second Oil Extraction Plant of Qinghai Oilfield, Haixi 816400, Qinghai, China;
5 Tianjin Branch of China National Offshore Oil Corporation, Tianjin 300452, China

Received:2015-03-02 Revised:2015-03-26 Online:2015-08-05 Published:2015-08-05

摘要/Abstract

摘要： 考察了两性/非离子复配表面活性剂浓度、无机/有机复配碱浓度、不同价态正负离子对稠油水包油型乳状液稳定性的影响规律。实验结果表明:随着复配表面活性剂浓度的增加,乳状液的分水率先急剧降低后缓慢下降;复配碱对乳状液的稳定性存在最优浓度;无机盐对乳状液的稳定性具有双重作用,低浓度盐提高乳状液的稳定性,高浓度盐降低乳状液的稳定性;一价阳离子对乳状液的稳定性影响顺序为KCl> NaCl> LiCl;二价阳离子对乳状液稳定性的影响程度为MgCl₂> CaCl₂;一价阴离子对分水率的影响顺序为NaCl> NaBr> NaI;高价阴离子对乳状液稳定性的影响程度为Na₂SO₄> NaCl> Na₃PO₄。

关键词: 两性表面活性剂, 有机碱, 单价盐, 高价盐, 乳状液稳定性

Abstract: The effects of the concentrations of amphoteric/nonionic surfactant, inorganic/organic alkali and anionic/cationic electrolyte on the stability of heavy oil-in-water emulsions were researched. The experimental results show that the water separation rates first sharply decrease with the increase of surfactant concentrations, and then reduce gradually till the minimum value. The compositional alkali has an optimal concentration. Inorganic salts show a twofold effect on the stability of emulsions, increasing within the low salt concentration and decreasing above the high concentration of salt. The magnitude of the effects of univalent cations on water separation rates is as follows:KCl> NaCl> LiCl. And the influence of MgCl₂ on the stability of emulsions is greater than that of CaCl₂. The magnitude of the effects of univalent anions on water separation rates is as follows: NaCl> NaBr> NaI, and that of polyvalent is Na₂SO₄> NaCl> Na₃PO₄.

Key words: amphoteric surfactant, organic alkali, univalent salt, polyvalent salt, emulsions stability

中图分类号:

TE357.46

孙娜娜, 敬加强, 丁晔, 臧欣欣, 邹亮. 无机盐阴阳离子对稠油水包油型乳状液稳定性的影响[J]. 化工进展, 2015, 34(08): 3118-3123.

SUN Nana, JING Jiaqiang, DING Ye, ZANG Xinxin, ZOU Liang. Effects of cationic/anionic electrolytes on the stability of heavy oil-in-water emulsions[J]. Chemical Industry and Engineering Progree, 2015, 34(08): 3118-3123.

参考文献

[1] Lanier D. Heavy oil——A major energy source for the 21st century[C]// Proceedings of the 7th Unitar International Conference on Heavy Crude & Tar Sands. Beijing, 1998.
[2] Saniere A, Henaut I, Argillier J F. Pipeline transportation of heavy oils, a strategic, economic and technological challenge[J]. Oil & Gas Science and Technology, 2004, 59(5): 455-466.
[3] Mario I. Process for producing low-density low sulfur crude oil: US, 4092238A[P]. 1978-05-30.
[4] Macwilliams W A, Eadie W. Process and apparatus for partial upgrading: CA, 1313639C[P]. 1993-02-16.
[5] Ralph S, Poynter W G. Pipelining oil/water mixtures: US, 3519006[P]. 1970-07-07.
[6] Ahmed N S, Nassar A M, Zaki N N, et al. Formation of fluid heavy oil-in-water emulsions for pipeline transportation[J]. Fuel, 1999, 78(5): 593-600.
[7] 敬加强, 孙娜娜, 安云朋, 等. 两性表面活性剂与阴离子聚丙烯酰胺复配体系的抗盐性[J]. 高分子学报, 2015(1): 88-96.
[8] Tang M G, Zhang G C, Ge J J, et al. Investigation into the mechanisms of heavy oil recovery by novel alkali flooding[J]. Colloids Surface A: Physicochem. Eng. Aspects, 2013, 421: 91-100.
[9] Berger P D, Lee C H. SPE/DOE: Symposium on improved oil recovery[R]. USA: Oklahoma, 2002.
[10] Zhao X T, Bai Y R, Wang Z B, et al. Low interfacial tension behavior between organic alkali/surfactant/polymer system and crude oil[J]. Journal of Dispersion Science and Technology, 2013, 34: 756-763.
[11] Mercado R A, Salager J L, Sadtler V, et al. Breaking of a cationic amine oil-in-water emulsion by pH increasing: Rheological monitoring to modelize asphalt emulsion rupture[J]. Colloids Surface A: Physicochem. Eng. Aspects, 2014, 458: 63-68.
[12] Qiao W H, Cui Y C, Zhu Y Y, et al. Dynamic interfacial tension behaviors between Guerbet bataine surfactants solution and Daqing crude oil[J]. Fuel, 2012, 102: 746-750.
[13] 翟会波, 林梅钦, 徐学芹, 等. 大庆油田三元复合驱碱与原油长期作用研究[J]. 大庆石油地质与开发, 2011(4): 114-118.
[14] Tansel B, Sager J, Retor T. Significance of hydrated radius and hydration shells on ionic permeability during nanofiltration in dead end and cross flow modes[J]. Separation and Purification Technology, 2006, 50(1): 40-47.
[15] 冯建国, 张小军, 范腾飞, 等. 体系pH值、乳化温度和电解质离子对异丙甲草胺水乳剂稳定性的影响[J]. 高等学校化学学报, 2012, 33(11): 2521-2525.
[16] Yang Q Q, Ke D, Yang M L, et al. Effect of salt concentration on the phase separation of bitumen emulsions[J]. Colloids Surface A: Physicochem. Eng. Aspects, 2013, 425: 1-5.
[17] Harris D C. Quantitative Chemical Analysis[M]. 3nd ed. New York: W. H. Freeman and Company, 1991: 123-125.
[18] Allred A L. Electronegativity values from thermochemical data[J]. Journal of Inorganic and Nuclear Chemistry, 1961, 17(3-4): 215-221.
[19] Kang W L, Liu Y, Qi B Y, et al. Interactions between alkali/surfactant/ polymer and their effects on emulsion stability[J]. Colloids Surface A: Physicochem. Eng. Aspects, 2000, 175: 243-247.
[20] Kundu P, Agrawal A, Mateen H, et al. Stability of oil-in-water macro-emulsion with anionic surfactant : Effect of electrolytes and temperatures[J]. Chemical Engineering Science, 2013, 102: 176-185.

无机盐阴阳离子对稠油水包油型乳状液稳定性的影响

Effects of cationic/anionic electrolytes on the stability of heavy oil-in-water emulsions

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