Research progress of preparation and utilization of perovskite-type photocatalyst in romoval of typical gaseous pollutants

doi:10.16085/j.issn.1000-6613.2021-0711

Abstract

Abstract:

In recent years, developing and utilizing catalysts with wide spectral response, high adsorption capacity and strong catalytic activity for photocatalytic removal of gaseous pollutants was widely concerned. In this work, the preparation and modification of perovskite-type photocatalysts were elaborated in detail, and then the research status, reaction mechanism and future research directions of perovskite-type photocatalysts for removing typical atmospheric emissions were summarized and reviewed systematically. The perovskite-type photocatalyst prepared by citric acid complexation method has the characteristics of small particle size and high photocatalytic activity, hereafter its visible light response ability can be further improved by ion doping or composite modification. The catalysts show high photocatalytic activity in the removal of NO, Hg⁰ and VOCs from flue gas, and the feasibility of synergistic catalytic oxidation of Hg⁰ and NO has been theoretically demonstrated. Furthermore, the perovskite-type photocatalyst derived from titanium-bearing blast furnace slag has a good application prospect in the purification of gaseous pollutants. However, the application of perovskite-type photocatalyst in simultaneous removal of multiple gaseous pollutants and the enrichment of perovskite-type components from titanium-bearing blast furnace slag need to be further studied, so as to provide a reference for the optimal preparation of perovskite-type photocatalyst and the improvement of its photocatalytic removal efficiency of gaseous pollutants.

Key words: catalyst, preparation, flue gas, photocatalysis, modification, radicals

摘要：

近年来，开发宽光谱响应、高吸附性能和强催化活性的钙钛矿型催化剂用于气态污染物的光催化脱除受到广泛关注。本文全面梳理了钙钛矿型光催化剂的制备和改性方法，并对其光催化脱除典型气态污染物的反应机理、研究现状及未来研究方向进行了系统归纳和评述。文中指出：柠檬酸络合法制备所得钙钛矿型光催化剂具有粒径小和光催化活性高的特点，经离子掺杂或复合改性后可进一步提升其可见光响应能力。该类催化剂在光催化脱除烟气中的NO、Hg⁰和挥发性有机化合物（VOCs）方面表现出较高的催化反应性，其协同催化氧化Hg⁰和NO的可行性也得以初步的理论论证。此外，含钛高炉渣衍生的钙钛矿型光催化剂在气态污染物净化方面表现出良好的应用前景。然而，钙钛矿型光催化剂用于气态多污染物协同脱除及含钛高炉渣中钙钛矿型组分的富集等方面的研究有待进一步深化。本文以期为钙钛矿型光催化剂的优化制备及气态污染物光催化脱除效率的提升提供参考。

关键词: 催化剂, 制备, 烟道气, 光催化, 改性, 自由基

CLC Number:

X511

MA Haofei, YUAN Peng, SHEN Boxiong. Research progress of preparation and utilization of perovskite-type photocatalyst in romoval of typical gaseous pollutants[J]. Chemical Industry and Engineering Progress, 2022, 41(2): 721-729.

马颢菲, 苑鹏, 沈伯雄. 钙钛矿型光催化剂的制备及脱除典型气态污染物的研究进展[J]. 化工进展, 2022, 41(2): 721-729.

Figures/Tables 1

References 55

1	XIE A J, ZHOU X M, HUANG X Y, et al. Cerium-loaded MnO_x/attapulgite catalyst for the low-temperature NH₃-selective catalytic reduction[J]. Journal of Industrial and Engineering Chemistry, 2017, 49: 230-241.
2	ABBAS N, HUSSAIN M, RUSSO N, et al. Studies on the activity and deactivation of novel optimized TiO₂ nanoparticles for the abatement of VOCs[J]. Chemical Engineering Journal, 2011, 175: 330-340.
3	杨景瑞, 王莹, 陈虎, 等. 烟气中NO_x脱除技术的研究进展[J]. 化工环保, 2020, 40(5): 461-466.
	YANG J R, WANG Y, CHEN H, et al. Research progresses on NO_x removal from flue gas[J]. Environmental Protection of Chemical Industry, 2020, 40(5): 461-466.
4	杜如鹏. 臭氧注入-活性炭吸附联用工艺脱除燃煤烟气中SO₂、NO和Hg⁰的小试化研究[D]. 厦门: 厦门大学, 2019.
	DU R P. Small-scale experiment study on removal of SO₂, NO and Hg⁰ from coal-fired flue gas by ozone injection-activated carbon adsorption combined process[D]. Xiamen: Xiamen University, 2019.
5	KONG J J, YANG T, RUI Z B, et al. Perovskite-based photocatalysts for organic contaminants removal: current status and future perspectives[J]. Catalysis Today, 2019, 327: 47-63.
6	UYGUNER-DEMIREL C S, BIRBEN N C, BEKBOLET M. Elucidation of background organic matter matrix effect on photocatalytic treatment of contaminants using TiO₂: a review[J]. Catalysis Today, 2017, 284: 202-214.
7	冯彦梅. 钙钛矿型铌/钛酸盐复合光催化剂的制备、性能及机理研究[D]. 太原: 中北大学, 2019.
	FENG Y M. Study on preparation, photocatalytic properties and mechanism of niobium/titanate composite photocatalysts[D]. Taiyuan: North University of China, 2019.
8	王建强. 钙钛矿型钽（铌）酸盐纳米光催化剂的制备及性能研究[D]. 北京: 北京理工大学, 2015.
	WANG J Q. Synthesis and property study of perovskite-type tantalite and niobate nano-sized photocatalysts[D]. Beijing: Beijing Institute of Technology, 2015.
9	黄浩, 赵韦人, 李杨, 等. 金属卤化物钙钛矿光催化材料研究进展[J]. 发光学报, 2020, 41(9): 1058-1081.
	HUANG H, ZHAO W R, LI Y, et al. Research advances of metal halide perovskites for photocatalysis[J]. Chinese Journal of Luminescence, 2020, 41(9): 1058-1081.
10	高永华. 钙钛矿型复合氧化物催化剂的制备及其在环境催化中的应用[D]. 太原: 太原理工大学, 2017.
	GAO Y H. Synthesis of perovskite-type composite oxide catalyst and its application in environmental catalysis[D]. Taiyuan: Taiyuan University of Technology, 2017.
11	张欣. La-Mn钙钛矿催化剂同时催化去除NO_x和碳烟的研究[D]. 哈尔滨: 哈尔滨工程大学, 2018.
	ZHANG X. Research on simultaneous catalytic removal of NO_x and soot by La-Mn perovskite catalyst[D]. Harbin: Harbin Engineering University, 2018.
12	李红花, 汪浩, 严辉. ABO₃钙钛矿型复合氧化物光催化剂设计评述[J]. 化工进展, 2006, 25(11): 1309-1313.
	LI Honghua, WANG Hao, YAN Hui. Review of designing ABO₃ pervoskite photocatalysis[J]. Chemical Industry and Enginering Progress, 2006, 25(11): 1309-1313.
13	谭廷文. 金属掺杂镧钴钙钛矿催化剂制备及去除NO与PM研究[D]. 广州: 广州大学, 2018.
	TANG T W. The study of preparation of metal doped LaCoO₃ perovskite catalysts for simultaneous removal NO and PM[D]. Guangzhou: Guangzhou University, 2018.
14	陈璐, 俞小花, 谢刚, 等. 模板法制备钙钛矿型复合氧化物催化剂的研究进展[J]. 中国稀土学报, 2021, 39(4): 531-542.
	CHEN L, YU X H, XIE G, et al. Research progress in preparation of perovskite-type composite oxide catalyst by template method[J]. Chineserare Earth Journal, 2021, 39(4): 531-542.
15	雍志清. g-C₃N₄/ABO₃复合材料的制备及光催化性能研究[D]. 天津: 天津大学, 2014.
	YONG Z Q. g-C₃N₄/ABO₃ nanocomposites: preparation and photocatalytic activities[D]. Tianjin: Tianjin University, 2014.
16	陈宸. 改性钙钛矿型光催化剂去除水体中有机污染物的研究[D]. 北京: 中央民族大学, 2020.
	CHEN C. Study on removal of organic pollutants in water by modified perovskite photocatalyst[D]. Beijing: Central University for Nationalities, 2020.
17	HADJARAB B, BOUGUELIA A, TRARI M. Optical and transport properties of lanthanum-doped stannate BaSnO₃[J]. Journal of Physics D: Applied Physics, 2007, 40(19): 5833-5839.
18	IRIE H, MARUYAMA Y, HASHIMOTO K. Ag⁺- and Pb²⁺-doped SrTiO₃ photocatalysts. A correlation between band structure and photocatalytic activity[J]. The Journal of Physical Chemistry C, 2007, 111(4): 1847-1852.
19	陈国强. A₃B₂X₉型非铅基钙钛矿材料的光催化应用研究[D]. 济南: 山东大学, 2020.
	CHEN G Q. Investigation on the photocatalytic application of lead-free perovskite materials of A₃B₂X₉[D]. Jinan: Shandong University, 2020.
20	唐利娜. 石墨相氮化碳光催化和镧铁钙钛矿电催化分解水的性能研究[D]. 昌吉: 昌吉学院, 2020.
	TANG L N. Study on the water splitting via photocatalysis using graphite phase carbon nitride and electrocatalysis using lanthanum iron perovskite materials[D]. Changji: Changji University, 2020.
21	汪哲铖. YFe_1-_xCr_xO₃的合成及磁性、光催化性能研究[D]. 淮南: 安徽理工大学, 2019.
	WANG Z C. Study on synthesis, magnetic and photocatalytic properties of YFe_1-_xCr_xO₃[D]. Huainan: Anhui University of Science & Technology, 2019.
22	BORSE P H, LEE J S, KIM H G. Theoretical band energetics of Ba(M_0.5Sn_0.5)O₃ for solar photoactive applications[J]. Journal of Applied Physics, 2006, 100(12): 124915.
23	郭少红. 卤素钙钛矿和金属有机框架的制备及其CO₂光催化还原性能研究[D]. 长春: 吉林大学, 2020.
	GUO S H. Preparation of halide perovskites and metal organic frameworks for studying their photocatalytic CO₂ reduction performance[D]. Changchun: Jilin University, 2020.
24	JI S M, BORSE P H, KIM H G GYU, et al. Photocatalytic hydrogen production from water-methanol mixtures using N-doped Sr₂Nb₂O₇ under visible light irradiation: effects of catalyst structure[J]. Physical Chemistry Chemical Physics, 2005, 7(6): 1315-1321.
25	ALAMMAR T, HAMM I, WARK M, et al. Low-temperature route to metal titanate perovskite nanoparticles for photocatalytic applications[J]. Applied Catalysis B: Environmental, 2015, 178: 20-28.
26	UEDA K, KATO H, KOBAYASHI M, et al. Control of valence band potential and photocatalytic properties of Na_xLa_1-_xTaO₁₊₂_xN_2-2_x oxynitride solid solutions[J]. Journal of Materials Chemistry A, 2013, 1(11): 3667.
27	SU Y, WANG S, MENG Y, et al. Dual substitutions of single dopant Cr³⁺ in perovskite NaTaO₃: synthesis, structure, and photocatalytic performance[J]. RSC Advances, 2012, 2(33): 12932.
28	GARCÍA-LÓPEZ E, MARCÌ G, PULEO F, et al. La_1-_xSr_xCo_1-_yFe_yO_3-_δ perovskites: preparation, characterization and solar photocatalytic activity[J]. Applied Catalysis B: Environmental, 2015, 178: 218-225.
29	WANG D F, KAKO T, YE J H. Efficient photocatalytic decomposition of acetaldehyde over a solid-solution perovskite (Ag_0.75Sr_0.25)(Nb_0.75Ti_0.25)O₃ under visible-light irradiation[J]. Journal of the American Chemical Society, 2008, 130(9): 2724-2725.
30	COMES R B, SUSHKO P V, HEALD S M, et al. Band-gap reduction and dopant interaction in epitaxial La, Cr co-doped SrTiO₃ thin films[J]. Chemistry of Materials, 2014, 26(24): 7073-7082.
31	SUN X M, WU J, TIAN F G, et al. Synergistic effect of surface defect and interface heterostructure on TiO₂/BiOIO₃ photocatalytic oxide gas-phase mercury[J]. Materials Research Bulletin, 2018, 103: 247-258.
32	PAN C S, XU J, WANG Y J, et al. Dramatic activity of C₃N₄/BiPO₄ photocatalyst with core/shell structure formed by self-assembly[J]. Advanced Functional Materials, 2012, 22(7): 1518-1524.
33	KUBACKA A, FERNÁNDEZ-GARCÍA M, COLÓN G. Advanced nanoarchitectures for solar photocatalytic applications[J]. Chemical Reviews, 2012, 112(3): 1555-1614.
34	张仁杰. Bi₄Ti₃O₁₂基可见光催化剂的制备与光催化性能研究[D]. 青岛: 青岛大学, 2020.
	ZHANG R J. Preparation and photocatalytic performance of Bi₄Ti₃O₁₂ based visible light photocatalyst[D]. Qingdao: Qingdao University, 2020.
35	ZHANG D D, QI J J, JI H D, et al. Photocatalytic degradation of ofloxacin by perovskite-type NaNbO₃ nanorods modified g-C₃N₄ heterojunction under simulated solar light: theoretical calculation, ofloxacin degradation pathways and toxicity evolution[J]. Chemical Engineering Journal, 2020, 400: 125918.
36	CHEN W, HU Y, BA M W. Surface interaction between cubic phase NaNbO₃ nanoflowers and Ru nanoparticles for enhancing visible-light driven photosensitized photocatalysis[J]. Applied Surface Science, 2018, 435: 483-493.
37	LI X Z, SHI H Y, WANG T S, et al. Photocatalytic removal of NO by Z-scheme mineral based heterojunction intermediated by carbon quantum dots[J]. Applied Surface Science, 2018, 456: 835-844.
38	ZHANG Q, HUANG Y, PENG S Q, et al. Perovskite LaFeO₃-SrTiO₃ composite for synergistically enhanced NO removal under visible light excitation[J]. Applied Catalysis B: Environmental, 2017, 204: 346-357.
39	ZHANG Z L, LYU H, LI X Z, et al. Conversion of CaTi_1-_xMn_xO_3-_δ-based photocatalyst for photocatalytic reduction of NO via structure-reforming of Ti-bearing blast furnace slag[J]. ACS Sustainable Chemistry & Engineering, 2019, 7(12): 10299-10309.
40	肖娟, 张浩力. 新型有机-无机杂化钙钛矿发光材料的研究进展[J]. 物理化学学报, 2016, 32(8): 1894-1912.
	XIOA J, ZHANG H L. Recent progress in organic-inorganic hybrid perovskite materials for luminescence applications[J]. Acta Physico-Chimica Sinica, 2016, 32(8): 1894-1912.
41	ZHANG Y L, ZHAO Y C, XIONG Z, et al. Elemental mercury removal by I^--doped Bi₂WO₆ with remarkable visible-light-driven photocatalytic oxidation[J]. Applied Catalysis B: Environmental, 2021, 282: 119534.
42	ARDIZZONE S, BIANCHI C L, CAPPELLETTI G, et al. Photocatalytic degradation of toluene in the gas phase: relationship between surface species and catalyst features[J]. Environmental Science & Technology, 2008, 42(17): 6671-6676.
43	AO C H, LEE S C, YU J Z, et al. Photodegradation of formaldehyde by photocatalyst TiO₂: effects on the presences of NO, SO₂ and VOCs[J]. Applied Catalysis B: Environmental, 2004, 54(1): 41-50.
44	李佳芮. 宽带隙半导体光催化降解VOCs的增强性能及反应机理研究[D]. 重庆: 重庆工商大学, 2020.
	LI J R. Photocatalytic VOCs oxidation enhancement performance and reaction mechnism of wide bandgap semiconductor photocatalysts[D]. Chongqing: Chongqing Technology and Business University, 2020.
45	LEE Y E, CHUNG W C, CHANG M B. Photocatalytic oxidation of toluene and isopropanol by LaFeO₃/black-TiO₂[J]. Environmental Science and Pollution Research, 2019, 26(20): 20908-20919.
46	CHEN J Y, HE Z G, LI G Y, et al. Visible-light-enhanced photothermocatalytic activity of ABO₃-type perovskites for the decontamination of gaseous styrene[J]. Applied Catalysis B: Environmental, 2017, 209: 146-154.
47	ZHOU P Y, ZHANG A C, ZHANG D, et al. Efficient removal of Hg⁰ from simulated flue gas by novel magnetic Ag₂WO₄/BiOI/CoFe₂O₄ photocatalysts[J]. Chemical Engineering Journal, 2019, 373: 780-791.
48	敖冉, 马丽萍, 王立春, 等. 钙钛矿协同催化氧化烟气中Hg⁰和NO的研究进展[J]. 环境工程, 2019, 37(S1): 562-567.
	AO R, MA L P, WANG L C, et al. Research progress for synergetic catalytic oxidation removal of Hg⁰ and NO over perovskite in flue gas[J]. Environmental Engineering, 2019, 37(S1): 562-567.
49	AO C H, LEE S C, ZOU S C, et al. Inhibition effect of SO₂ on NO_x and VOCs during the photodegradation of synchronous indoor air pollutants at parts per billion(ppb) level by TiO₂[J]. Applied Catalysis B: Environmental, 2004, 49(3): 187-193.
50	LIN F W, SHAO J M, TANG H R, et al. Enhancement of NO oxidation activity and SO₂ resistance over LaMnO₃₊_δ perovskites catalysts with metal substitution and acid treatment[J]. Applied Surface Science, 2019, 479: 234-246.
51	HODJATI S, PETIT C, PITCHON V, et al. Absorption/desorption of NO_x process on perovskites: impact of SO₂ on the storage capacity of BaSnO₃ and strategy to develop thioresistance[J]. Applied Catalysis B: Environmental, 2001, 30(3/4): 247-257.
52	ZHANG-STEENWINKEL Y, CASTRICUM H L, BECKERS J, et al. Dielectric heating effects on the activity and SO₂ resistance of La_0.8Ce_0.2MnO₃ perovskite for methane oxidation[J]. Journal of Catalysis, 2004, 221(2): 523-531.
53	XIAN H, LI F L, LI X G, et al. Influence of preparation conditions to structure property, NO_x and SO₂ sorption behavior of the BaFeO_3-_x perovskite catalyst[J]. Fuel Processing Technology, 2011, 92(9): 1718-1724.
54	XIA D H, HU L L, HE C, et al. Simultaneous photocatalytic elimination of gaseous NO and SO₂ in a BiOI/Al₂O₃-padded trickling scrubber under visible light[J]. Chemical Engineering Journal, 2015, 279: 929-938.
55	LIU Y, NING P, LI K, et al. Simultaneous removal of NO_x and SO₂ by low-temperature selective catalytic reduction over modified activated carbon catalysts[J]. Russian Journal of Physical Chemistry A, 2017, 91(3): 490-499.

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