Advances in copper-based catalyst for the methanol synthesis from CO2 hydrogenation

doi:10.16085/j.issn.1000-6613.2016.s1.027

Abstract

Abstract: The methanol synthesis from CO₂ hydrogenation is the most promising research direction in the utilization of CO₂, in which the research of catalysts is the key point.This review focuses on the copper-based catalysts and summarizes the effect factors including copper dispersion, copper particle diameter and the interaction between metal copper and support on the activity, methanol selectivity and stability of copper-based catalyst.The preparation methods have huge influences on the copper dispersion, copper particle diameter and the interaction between metal copper and support which could then affect the catalytic performance.Developments based on the co-precipitation are the research trend of catalysts preparation in nowadays.Improving copper dispersion, decreasing copper particle diameter and increasing interaction between metal copper and support have different effects on the catalytic performance of this reaction.This review of the researches above provides the references for the development of high activity, high methanol selectivity and good stability new catalysts.

Key words: carbon dioxide, methanol, hydrogenation, catalysts

摘要： 二氧化碳加氢合成甲醇反应是二氧化碳利用的重要途径,其中催化剂的研究是技术的关键。本文针对反应采用的铜基催化剂,从铜基催化剂的制备方法、活性组分铜的分散度、铜粒径以及铜与载体间界面作用等方面,分别对其影响催化剂的活性、甲醇的选择性以及稳定性作用进行研究综述。通过分析认为:催化剂的制备方法影响催化剂的铜分散度、铜粒径及铜与载体间的作用,从而影响催化剂催化性能。其中在共沉淀法的基础上进行改进是目前催化剂制备方法的研究趋势,且增加铜分散度、减小铜粒径及增大铜与载体间作用对二氧化碳加氢合成甲醇反应铜基催化剂的催化性能有不同程度的影响。该综述为进一步研制高活性、高甲醇选择性和优异稳定性的新型催化剂提供参考。

关键词: 二氧化碳, 甲醇, 加氢, 催化剂

CLC Number:

TQ426

FAN Yujia, WU Sufang. Advances in copper-based catalyst for the methanol synthesis from CO₂ hydrogenation[J]. Chemical Industry and Engineering Progree, 2016, 35(S1): 159-166.

樊钰佳, 吴素芳. 二氧化碳加氢合成甲醇反应铜基催化剂研究进展[J]. 化工进展, 2016, 35(S1): 159-166.

References

[1] 孙锦宜.CO₂制甲醇及所用催化剂[J].化学工业与工程技术,1996,17(3):50-52.
[2] HASZELDINE R S.Carbon capture and storage:how green can black be?[J].Science,2009,325(5948):1647-1652.
[3] KINTISCH E.US Carbon plan relies on uncertain capture technology[J].Science,2013,341(6153):1438-1439.
[4] KINTISCH E.Climate crossroads[J].Science,2015,350(6264):1016-1017.
[5] REED T B,LERNER R M.Methanol:a versatile fuel for immediate use[J].Science,1973,182(4119):1299-1304.
[6] 乔治A·奥拉,阿兰·戈佩特,G K苏耶·普拉卡西.夏磊,胡金波译.跨越油气时代:甲醇经济(精)[M].北京:化学工业出版社,2011.
[7] JADHAV S G,VAIDYA P D,BHANAGE B M,et al. Catalytic carbon dioxide hydrogenation to methanol:a review of recent studies[J].Chemical Engineering Research and Design,2014,92(11):2557-2567.
[8] KARELOVIC A,BARGIBANT A,FERNANDEZ C,et al. Effect of the structural and morphological properties of Cu/ZnO catalysts prepared by citrate method on their activity toward methanol synthesis from CO₂ and H₂ under mild reaction conditions[J].Catalysis Today,2012,197(1):109-118.
[9] BANSODE A,URAKAWA A.Towards full one-pass conversion of carbon dioxide to methanol and methanol-derived products[J].Journal of Catalysis,2014,309:66-70.
[10] TIDONA B,KOPPOLD C,BANSODE A,et al.CO₂ hydro-genation to methanol at pressures up to 950 bar[J].The Journal of Supercritical Fluids,2013,78:70-77.
[11] WITOON T,BUMRUNGSALEE S,CHAREONPANICH M,et al.Effect of hierarchical meso-macroporous alumina-supported copper catalyst for methanol synthesis from CO₂ hydrogenation[J].Energy Conversion and Management,2015,103:886-894.
[12] GAO P,LI F,XIAO F K,et al.Effect of hydrotalcite-containing precursors on the performance of Cu/Zn/Al/Zr catalysts for CO₂ hydrogenation:Introduction of Cu ²⁺ at different formation stages of precursors[J].Catalysis Today,2012,194(1):9-15.
[13] GUO X M,MAO D S,LU G Z,et al.Glycine-nitrate combustion synthesis of CuO-ZnO-ZrO₂ catalysts for methanol synthesis from CO₂ hydrogenation[J].Journal of Catalysis,2010,271(2):178-185.
[14] 许文娟,马丽萍,黄彬,等.CO₂催化加氢研究进展[J].化工进展,2009,28(s1):284-289.
[15] 马晓然,王康军,吴静.Cu-ZnO-Al₂O₃-ZrO₂催化二氧化碳加氢合成甲醇的研究[J].沈阳化工大学学报,2013,26(4):314-317.
[16] 韩冲,高文桂,王华,等.铜,锌,铝,锆物质的量比对CuO-ZnO-Al₂O₃-ZrO₂系催化剂催化CO₂加氢合成甲醇的影响[J].材料导报,2012,26(24):89-92.
[17] ZHUANG H D,BAI S F,LIU X M,et al.Structure and performance of Cu/ZrO₂ catalyst For the synthesis of methanol from CO₂ hydrogenation[J].Journal of Fuel Chemistry and Technology,2010,38(4):462-467.
[18] ARENA F,ITALIANO G,BARBERA K,et al.Solid-state interactions,adsorption sites and functionality of Cu-ZnO/ZrO₂ catalysts in the CO₂ hydrogenation to CH₃OH[J].Applied Catalysis A:General,2008,350(1):16-23.
[19] BONURA G,CORDARO M,CANNILLA C,et al.The changing nature of the active site of Cu-Zn-Zr catalysts for the CO₂ hydrogenation reaction to methanol[J].Applied Catalysis B:Environmental,2014,152/153:152-161.
[20] 王尚弟.催化剂工程导论[M].北京:化学工业出版社,2007:38.
[21] CAI W J,DE LA PISCINA P R,TOYIR J,et al.CO₂ hydrogenation to methanol over CuZnGa catalysts prepared using microwave-assisted methods[J].Catalysis Today,2015,242:193-199.
[22] LI L,MAO D S,YU J,et al.Highly selective hydrogenation of CO₂ to methanol over CuO-ZnO-ZrO₂ catalysts prepared by a surfactant-assisted co-precipitation method[J].Journal of Power Sources,2015,279:394-404.
[23] UD DIN I,SHAHARUN M S,SUBBARAO D,et al. Synthesis,characterization and activity pattern of carbon nanofibers based copper/zirconia catalysts for carbon dioxide hydrogenation to methanol:Influence of calcination temperature[J].Journal of Power Sources,2015,274:619-628.
[24] KARELOVIC A,RUIZ P.The role of copper particle size in low pressure methanol synthesis via CO₂ hydrogenation over Cu/ZnO catalysts[J].Catalysis Science & Technology,2015,5(2):869-881.
[25] WITOON T,PERMSIRIVANICH T,DONPHAI W,et al. CO₂ hydrogenation to methanol over Cu/ZnO nanocatalysts prepared via a chitosan-assisted co-precipitation method[J].Fuel Processing Technology,2013,116:72-78.
[26] AHOUARI H,SOUALAH A,LE VALANT A,et al. Methanol synthesis from CO₂ hydrogenation over copper based catalysts[J].Reaction Kinetics Mechanisms and Catalysis,2013,110(1):131-145.
[27] GUO X M,MAO D S,LU G Z,et al.CO₂ hydrogenation to methanol over Cu/ZnO/ZrO₂ catalysts prepared via a route of solid-state reaction[J].Catalysis Communications,2011,12(12):1095-1098.
[28] GUO X M,MAO D S,WANG S,et al.Combustion synthesis of CuO-ZnO-ZrO₂ catalysts for the hydrogenation of carbon dioxide to methanol[J].Catalysis Communications,2009,10(13):1661-1664.
[29] AN X,ZUO Y Z,ZHANG Q,et al.Methanol Synthesis from CO₂ Hydrogenation with a Cu/Zn/Al/Zr Fibrous Catalyst[J].Chinese Journal of Chemical Engineering,2009,17(1):88-94.
[30] ZHAN H J,LI F,GAO P,et al.Methanol synthesis from CO₂ hydrogenation over La-M-Cu-Zn-O(M=Y,Ce,Mg,Zr)catalysts derived from perovskite-type precursors[J].Journal of Power Sources,2014,251:113-121.
[31] LADERA R,PEREZ-ALONSO F J,GONZALEZ-CARBALLO J M,et al.Catalytic valorization of CO₂ via methanol synthesis with Ga-promoted Cu-ZnO-ZrO₂ catalysts[J].Applied Catalysis B:Environmental,2013,142/143:241-248.
[32] GAO P,LI F,ZHAN H J,et al.Influence of Zr on the performance of Cu/Zn/Al/Zr catalysts via hydrotalcite-like precursors for CO₂ hydrogenation to methanol[J].Journal of Catalysis,2013,298:51-60.
[33] SAMEI E,TAGHIZADEH M,BAHMANI M.Enhancement of stability and activity of Cu/ZnO/Al₂O₃ catalysts by colloidal silica and metal oxides additives for methanol synthesis from a CO₂-rich feed[J].Fuel Processing Technology,2012,96:128-133.
[34] LI C M,YUAN X D,FUJIMOTO K.Development of highly stable catalyst for methanol synthesis from carbon dioxide[J].Applied Catalysis A:General,2014,469:306-311.
[35] GAO P,LI F,ZHAN H J,et al.Fluorine-modified Cu/Zn/Al/Zr catalysts via hydrotalcite-like precursors for CO₂ hydrogenation to methanol[J].Catalysis Communications,2014,50:78-82.
[36] XIAO J,MAO D S,GUO X M,et al.Methanol Synthesis from CO₂ Hydrogenation over CuO-ZnO-TiO₂ Catalysts:The Influence of TiO₂ Content[J].Energy Technology,2015,3(1):32-39.
[37] BONURA G,ARENA F,MEZZATESTA G,et al.Role of the ceria promoter and carrier on the functionality of Cu-based catalysts in the CO₂-to-methanol hydrogenation reaction[J].Catalysis Today,2011,171(1):251-256.
[38] XIAO J,MAO D S,GUO X M,et al.Effect of TiO₂,ZrO₂,and TiO₂-ZrO₂ on the performance of CuO-ZnO catalyst for CO₂ hydrogenation to methanol[J].Applied Surface Science,2015,338:146-153.
[39] GAO P,LI F,XIAO F K,et al.Preparation and activity of Cu/Zn/Al/Zr catalysts via hydrotalcite-containing precursors for methanol synthesis from CO₂ hydrogenation[J].Catalysis Science & Technology,2012,2(7):1447-1454.
[40] GAO P,LI F,ZHANG L N,et al.Influence of fluorine on the performance of fluorine-modified Cu/Zn/Al catalysts for CO₂ hydrogenation to methanol[J].Journal of CO₂ Utilization,2013,2:16-23.
[41] NATESAKHAWAT S,OHODNICKI JR P R,HOWARD B H,et al.Adsorption and deactivation characteristics of Cu/ZnO-based catalysts for methanol synthesis from carbon dioxide[J].Topics in Catalysis,2013,56(18/19/20):1752-1763.
[42] LIU H L,HUANG Z W,HAN Z B,et al.Efficient production of methanol and diols via the hydrogenation of cyclic carbonates using copper-silica nanocomposite catalysts[J].Green Chemistry,2015,17(8):4281-4290.
[43] NATESAKHAWAT S,LEKSE J W,BALTRUS J P,et al.Active sites and structure-activity relationships of copper-based catalysts for carbon dioxide hydrogenation to methanol[J].ACS Catalysis,2012,2(8):1667-1676.
[44] GRACIANI J,MUDIYANSELAGE K,XU F,et al. Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO₂[J].Science,2014,345(6196):546-550.
[45] LIAO F L,HUANG Y Q,GE J W,et al.Morphology-Dependent Interactions of ZnO with Cu Nanoparticles at the Materials' Interface in Selective Hydrogenation of CO₂ to CH₃OH[J].Angewandte Chemie International Edition,2011,50(9):2162-2165.
[46] ARENA F,ITALIANO G,BARBERA K,et al.Basic evidences for methanol-synthesis catalyst design[J].Catalysis Today,2009,143(1):80-85.
[47] 李玉敏.工业催化原理[M].天津:天津大学出版社,1992:231.

Advances in copper-based catalyst for the methanol synthesis from CO₂ hydrogenation

二氧化碳加氢合成甲醇反应铜基催化剂研究进展

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	YANG Hanyue, KONG Lingzhen, CHEN Jiaqing, SUN Huan, SONG Jiakai, WANG Sicheng, KONG Biao. Decarbonization performance of downflow tubular gas-liquid contactor of microbubble-type [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 197-204.
[2]	SHI Yongxing, LIN Gang, SUN Xiaohang, JIANG Weigeng, QIAO Dawei, YAN Binhang. Research progress on active sites in Cu-based catalysts for CO₂ hydrogenation to methanol [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 287-298.
[3]	ZHENG Qian, GUAN Xiushuai, JIN Shanbiao, ZHANG Changming, ZHANG Xiaochao. Photothermal catalysis synthesis of DMC from CO₂ and methanol over Ce_0.25Zr_0.75O₂ solid solution [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 319-327.
[4]	XU Jiaheng, LI Yongsheng, LUO Chunhuan, SU Qingquan. Optimization of methanol steam reforming process [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 41-46.
[5]	SUN Yuyu, CAI Xinlei, TANG Jihai, HUANG Jingjing, HUANG Yiping, LIU Jie. Optimization and energy-saving of a reactive distillation process for the synthesis of methyl methacrylate [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 56-63.
[6]	SHU Bin, CHEN Jianhong, XIONG Jian, WU Qirong, YU Jiangtao, YANG Ping. Necessity analysis of promoting the development of green methanol under the goal of carbon neutrality [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4471-4478.
[7]	MAO Shanjun, WANG Zhe, WANG Yong. Group recognition hydrogenation: From concept to application [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 3917-3922.
[8]	WANG Yaogang, HAN Zishan, GAO Jiachen, WANG Xinyu, LI Siqi, YANG Quanhong, WENG Zhe. Strategies for regulating product selectivity of copper-based catalysts in electrochemical CO₂ reduction [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4043-4057.
[9]	LIU Yi, FANG Qiang, ZHONG Dazhong, ZHAO Qiang, LI Jinping. Cu facets regulation of Ag/Cu coupled catalysts for electrocatalytic reduction of carbon dioxide [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4136-4142.
[10]	WANG Lanjiang, LIANG Yu, TANG Qiong, TANG Mingxing, LI Xuekuan, LIU Lei, DONG Jinxiang. Synthesis of highly dispersed Pt/HY catalyst by rapid pyrolysis of platinum precursors and its performance for deep naphthalene hydrogenation [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4159-4166.
[11]	HUANG Yufei, LI Ziyi, HUANG Yangqiang, JIN Bo, LUO Xiao, LIANG Zhiwu. Research progress on catalysts for photocatalytic CO₂ and CH₄ reforming [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4247-4263.
[12]	WANG Xiaohan, ZHOU Yasong, YU Zhiqing, WEI Qiang, SUN Jinxiao, JIANG Peng. Synthesis and hydrocracking performance of Y molecular sieves with different crystal sizes [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4283-4295.
[13]	CHU Tiantian, LIU Runzhu, DU Gaohua, MA Jiahao, ZHANG Xiao’a, WANG Chengzhong, ZHANG Junying. Preparation and chemical degradability of organoguanidine-catalyzed dehydrogenation type RTV silicone rubbers [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3664-3673.
[14]	LI Jia, FAN Xing, CHEN Li, LI Jian. Research progress of simultaneous removal of NO _x and N₂O from the tail gas of nitric acid production [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3770-3779.
[15]	LOU Baohui, WU Xianhao, ZHANG Chi, CHEN Zhen, FENG Xiangdong. Advances in nanofluid for CO₂ absorption and separation [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3802-3815.