Electrode materials of metal compound for supercapacitors

doi:10.16085/j.issn.1000-6613.2016.s2.034

Abstract

Abstract: The metal compound is a kind of pseudocapacitor electrode material which has ideal capacitance properties.However,due to it's disadvantages such as poor conductivity and easy agglomeration,the capacitance properties are decreased.In this paper,based on summarizing recent research findings,the applications of metal compounds and the methods to improve capacitance properties of metal compounds was discussed.The results show that conductivity can be effectively improved and agglomeration can be prevented by many methods such as the composite of metal compounds and various materials,electrodeposition,the directional synthesis of the compound's structure and so on.With the disadvantages of metal compounds being conquered,metal compounds' application will be continual.The metal compound materials in supercapacitors have injected new vitality for the new energy storage devices.

Key words: supercapacitor, metal compound, capacitance properties, agglomeration, nanostructure, composites

摘要： 金属化合物是理想的赝电容电极材料，但是其拥有导电性差且易团聚的缺点，使得电容性能显著下降。本文通过总结近年来的研究成果，阐述了金属化合物在超级电容器中的应用以及提高各类金属化合物电容性能的方法。研究表明，金属化合物与各类材料的复合、电沉积法、化合物结构的定向合成等多种方法均可有效提高金属化合物导电性，防止团聚现象的发生。随着金属化合物缺点的不断攻克，其在超级电容器的应用也将逐渐频繁起来，同时金属化合物赝也为新兴的储能元件注入了新的活力。

关键词: 超级电容器, 金属化合物, 电容性能, 团聚, 纳米结构, 复合材料

CLC Number:

O614
O646.21

YIN Quan, LI Hongjuan, QIN Zhanbin, SUN Yi, WANG Zhiyan, GAO Yun, WANG Yatao, PENG Sheng. Electrode materials of metal compound for supercapacitors[J]. Chemical Industry and Engineering Progree, 2016, 35(S2): 200-208.

殷权, 李洪娟, 秦占斌, 孙怡, 王志彦, 高筠, 王亚涛, 彭胜. 金属化合物超级电容器电极材料[J]. 化工进展, 2016, 35(S2): 200-208.

References

[1] 刘洋,艾常春,胡意,等.碳包覆金属氧化物作为超级电容器电极材料的研究进展[J].化工进展,2013,32(8):1849-1854.
[2] CHOI B G,YANG M H,HONG W H,et al.3D macroporous graphene frameworks for supercapacitors with high energy and power densities[J].ACS Nano,2012,6(5):4020-4028.
[3] JIANG Y,LIN L.A two-stage,self-aligned vertical densification process for as-grown CNT forests in supercapacitor applications[J]. Sensors & Actuators A Physical,2012,188(12):261-267.
[4] DONG Y,LIN H,ZHOU D,et al.Synthesis of mesoporous graphitic carbon fibers with high performance for supercapacitor[J].Electrochimica Acta,2015,159:116-123.
[5] KESKINEN J,TUURALA S,SJÖDIN M,et al. Asymmetric and symmetric supercapacitors based on polypyrrole and activated carbon electrodes[J].Synthetic Metals,2015,203:192-199.
[6] 冯辉霞,王滨,谭琳,等.导电聚合物基超级电容器电极材料研究进展[J].化工进展,2014,33(3):689-695.
[7] ZHANG Y Q,LI L,SHI S J,et al.Synthesis of porous Co₃O₄ nanoflake array and its temperature behavior as pseudo-capacitor electrode[J].Journal of Power Sources,2015,60(3):1-6.
[8] XIAO H,GUO W,SUN B,et al.Mesoporous TiO₂ and Co-doped TiO₂ nanotubes/reduced graphene oxide composites as electrodes for supercapacitors[J].Electrochimica Acta,2016,190:104-117.
[9] 史雪,高婷婷,周国伟.过渡金属化合物多壳空心球的制备及其应用研究进展[J].化工进展,2015,34(11):3951-3958.
[10] MA W,CHEN S,YANG S,et al.Hierarchical MnO₂ nanowire/graphene hybrid fibers with excellent electrochemical performance for flexible solid-state supercapacitors[J].Journal of Power Sources,2016,306:481-488.
[11] CHEN J,WANG Y,CAO J,et al.Flexible and solid-state asymmetric supercapacitor based on ternary graphene/MnO₂/carbon black hybrid film with high power performance[J].Electrochimica Acta,2015,182:861-870.
[12] LUAN Y,HUANG Y,WANG L,et al.Porous carbon@MnO₂ and nitrogen-doped porous carbon from carbonized loofah sponge for asymmetric supercapacitor with high energy and power density[J].Journal of Electroanalytical Chemistry,2016,763:90-96.
[13] PAN C,GU H,DONG L.Synthesis and electrochemical performance of polyaniline@MnO₂/graphene ternary composites for electrochemical supercapacitors[J].Journal of Power Sources,2016,303:175-181.
[14] XU G R,WEN Y,MIN X P,et al.Construction of MnO₂/3-dimensional porous crack Ni for high-performance supercapacitors[J].Electrochimica Acta,2015,186:133-141.
[15] XIONG C,LI T,DANG A,et al.Two-step approach of fabrication of three-dimensional MnO₂-graphene-carbon nanotube hybrid as a binder-free supercapacitor electrode[J]. Journal of Power Sources,2016,306:602-610.
[16] QIAO YQ,SUN QJ,XI JY,et al.A modified solvothermal synthesis of porous Mn₃O₄ for supercapacitor with excellent rate capability and long cycle life[J].Journal of Alloys & Compounds,2015,660:416-422.
[17] YANG S,SONG X,ZHANG P,et al.Crumpled nitrogen-doped graphene-ultrafine Mn₃O₄ nanohybrids and their application in supercapacitors[J].J.Mater.Chem.A,2013,1(45):14162-14169.
[18] JIN G,XIAO X,LI S,et al.Strongly coupled graphene/Mn₃O₄ composite with enhanced electrochemical performance for supercapacitor electrode[J].Electrochimica Acta,2015,178:689-698.
[19] YANG X,HE Y,BAI Y,et al.Mn₃O₄ nanocrystalline/graphene hybrid electrode with high capacitance[J]. Electrochimica Acta,2015,188:398-405.
[20] XIAO H,QU F,WU X.Ultrathin NiO nanoflakes electrode materials for supercapacitors[J].Applied Surface Science,2016,360:8-13.
[21] SUN X,SI W,LIU X,et al.Multifunctional Ni/NiO hybrid nanomembranes as anode materials for high-rate Li-ion batteries[J].Nano Energy,2014,9:168-175.
[22] ZENG Y,WANG L,WANG Z,et al.Facile synthesis of self-assembled porous NiO nanostructures and their application to supercapacitor electrodes[J].Materials Today Communications,2015,5:70-74.
[23] XIAO H,QU F,WU X.Ultrathin NiO nanoflakes electrode materials for supercapacitors[J].Applied Surface Science,2016,360:8-13.
[24] HUANG M L,GU C D,GE X,et al.NiO nanoflakes grown on porous graphene frameworks as advanced electrochemical pseudocapacitor materials[J].Journal of Power Sources,2014,259(7):98-105.
[25] HAKAMADA M,ABE T,MABUCHI M.Electrodes from carbon nanotubes/NiO nanocomposites synthesized in modified Watts bath for supercapacitors[J].Journal of Power Sources,2016,325:670-674.
[26] LIU A,CHE H,MAO Y,et al.Template-free synthesis of one-dimensional hierarchical NiO nanotubes self-assembled by nanosheets for high-performance supercapacitors[J]. Ceramics International,2016,42(9):11435-11441.
[27] WANG X,CHEN X,GAO L,et al.One-dimensional arrays of Co₃O₄ nanoparticles:synthesis,characterization,and optical and electrochemical properties[J]. J. Phys.Chem.B,2004,108(42):16401-16404.
[28] 范书琼,孔令斌,王儒涛,等.Co₃O₄的制备及电化学性能[J].化工进展,2013,32(s1):168-173.
[29] LIU W,LI X,ZHU M,et al.High-performance all-solid state asymmetric supercapacitor based on Co₃O₄ nanowires and carbon aerogel[J].Journal of Power Sources,2015,282:179-186.
[30] LIN H,HUANG Q,WANG J,et al.Self-assembled graphene/polyaniline/Co₃O₄ ternary hybrid aerogels for supercapacitors[J]. Electrochimica Acta,2016,191:444-451.
[31] FAN H,QUAN L,YUAN M,et al.Thin Co₃O₄ nanosheet array on 3D porous graphene/nickel foam as a binder-free electrode for high-performance supercapacitors[J]. Electrochimica Acta,2015,188:222-229.
[32] PAN X,CHEN X,LI Y,et al.Facile synthesis of Co₃O₄ nanosheets electrode with ultrahigh specific capacitance for electrochemical supercapacitors[J].Electrochimica Acta,2015,182:1101-1106.
[33] QIU K,LU Y,CHENG J,et al.Ultrathin mesoporous Co₃O₄,nanosheets on Ni foam for high-performance supercapacitors[J].Electrochimica Acta,2014,157:62-68.
[34] WANG X,XIA H,WANG X,et al.Facile synthesis ultrathin mesoporous Co₃O₄ nanosheets for high-energy asymmetric supercapacitor[J].Journal of Alloys & Compounds,2016,686:969-975.
[35] CHEN J,XU J,ZHOU S,et al.Template-grown graphene/porous Fe₂O₃ nanocomposite:a high-performance anode material for pseudocapacitors[J].Nano Energy,2015,15:719-728.
[36] QUAN H,CHENG B,XIAO Y,et al.One-pot synthesis of α-Fe₂O₃ nanoplates-reduced graphene oxide composites for supercapacitor application[J].Chemical Engineering Journal,2015,286:165-173.
[37] LI X,ZHANG L,HE G..Fe₃O₄ doped double-shelled hollow carbon spheres with hierarchical pore network for durable high-performance supercapacitor[J].Carbon,2015,99:514-522.
[38] SHINDE S K,DUBAL D P,GHODAKE G S,et al.Morphological tuning of CuO nanostructures by simple preparative parameters in SILAR method and their consequent effect on supercapacitors[J].Nano-Structures & Nano-Objects,2016,6:5-13.
[39] ZHU S,WU M,GE M H,et al.Design and construction of three-dimensional CuO/polyaniline/rGO ternary hierarchical architectures for high performance supercapacitors[J]. Journal of Power Sources,2016,306:593-601.
[40] SARAVANAKUMAR B,PURUSHOTHAMAN K K,MURALIDHARAN G.High performance supercapacitor based on carbon coated V₂O₅ nanorods[J].Journal of Electroanalytical Chemistry,2015,758:111-116.
[41] HUANG X,ZHANG W,TAN Y,et al.Facile synthesis of rod-like Bi₂O₃ nanoparticles as an electrode material for pseudocapacitors[J].Ceramics International,2016,42(1):2099-2105.
[42] VIJAYAKUMAR S,LEE S H,RYU K S.Hierarchical CuCo₂O₄ nanobelts as a supercapacitor electrode with high areal and specific capacitance[J].Electrochimica Acta,2015,182:979-986.
[43] ZHANG B,LI W,SUN J,et al.NiO/MnO₂ core/shell nanocomposites for high-performance pseudocapacitors[J]. Materials Letters,2014,114(1):40-43.
[44] NGUYEN V H,TRAN V C,KHARISMADEWI D,et al. Ultralong MnO₂ nanowires intercalated graphene/Co₃O₄ composites for asymmetric supercapacitors[J].Materials Letters,2015,147:123-127.
[45] LIU T,CHAI H,JIA D,et al.Rapid microwave-assisted synthesis of mesoporous NiMoO₄ nanorod/reduced graphene oxide composites for high-performance supercapacitors[J]. Electrochimica Acta,2015,180:998-1006.
[46] SU L,WANG Y,SHA Y,et al.Ternary active site Co₃O₄/NiO/MnO₂ electrode with enhanced capacitive performances[J].Journal of Alloys & Compounds,2016,656:585-589.
[47] FAN D B,WANG H,ZHANG Y C,et al.Preparation of crystalline MnS thin films by chemical bath deposition[J]. Materials Chemistry and Physics,2003,80(1):44-47.
[48] PUJARI R B,LOKHANDE A C,YADAV A A,et al. Synthesis of MnS microfibers for high performance flexible supercapacitors[J].Materials and Design,2016,108:510-517.
[49] QUAN H,CHENG B,CHEN D,et al.One-pot synthesis of α-MnS/nitrogen-doped reduced graphene oxide hybrid for high-performance asymmetric supercapacitors[J]. Electrochimica Acta,2016,210:557-566.
[50] LI X,SHEN J,LI N,et al.Fabrication of γ-MnS/rGO composite by facile one-pot solvothermal approach for supercapacitor applications[J].Journal of Power Sources,2015,282:194-201.
[51] LI X,SHEN J,LI N,et al.Template-free solvothermal synthesis of NiS₂ microspheres on graphene sheets for high-performance supercapacitors[J].Materials Letters,2015,139:81-85.
[52] LIN H,LIU F,WANG X,et al.Graphene-coupled flower-like Ni₃S₂ for a free-standing 3D aerogel with an ultra-high electrochemical capacity[J].Electrochimica Acta,2016,191:705-715.
[53] YU L,YANG B,LIU Q,et al.Interconnected NiS nanosheets supported by nickel foam:soaking fabrication and supercapacitors application[J].Journal of Electroanalytical Chemistry,2015,739(739):156-163.
[54] PATIL A M,LOKHANDE A C,CHODANKAR N R,et al. Engineered morphologies of β-NiS thin films via anionic exchange process and their supercapacitive performance[J]. Materials & Design,2016,97:407-416.
[55] YAN X,TONG X,MA L,et al.Synthesis of porous NiS nanoflake arrays by ion exchange reaction from NiO and their high performance supercapacitor properties[J].Materials Letters,2014,124(6):133-136.
[56] TANG J,SHEN J,LI N,et al.A free template strategy for the synthesis of CoS₂-reduced graphene oxide nanocomposite with enhanced electrode performance for supercapacitors[J].Ceramics International,2014,40(10):15411-15419.
[57] LIN T W,DAI C S,TASI T T,et al.High-performance asymmetric supercapacitor based on Co₉S₈/3D graphene composite and graphene hydrogel[J].Chemical Engineering Journal,2015,279:241-249.
[58] ZHANG Q,XU C,LU B.Super-long life supercapacitors based on the construction of Ni foam/graphene/Co₃S₄,composite film hybrid electrodes[J].Electrochimica Acta,2014,132(3):180-185.
[59] XING J C,ZHU Y L,LI M Y,et al.Hierarchical mesoporous CoS₂ microspheres:morphology-controlled synthesis and their superior pseudocapacitive properties[J]. Electrochimica Acta,2014,149:285-292.
[60] YANG Z,CHEN C Y,LIU C W,et al.Quantum dot-sensitized solar cells featuring CuS/CoS electrodes provide 4.1% efficiency[J].Advanced Energy Materials,2011,1(2):259-264.
[61] CHEN Y,DAVOISNE C,TARASCON J M,et al. Growth of single-crystal copper sulfide thin films via electrodeposition in ionic liquid media for lithium ion batteries[J].J.Mater.Chem.,2012,22(12):5295-5299.
[62] HUANG K J,ZHANG J Z,KE X.One-step synthesis of layered CuS/multi-walled carbon nanotube nanocomposites for supercapacitor electrode material with ultrahigh specific capacitance[J].Electrochimica Acta,2014,149(149):28-33.
[63] YAN T,LI R,ZAIJUN L.Facile construction of three-dimensional NiCo₂S₄ with tremella-like morphology for high performance supercapacitors[J].Materials Letters,2016,167:234-237.
[64] ZHANG J,GAO H,ZHANG M Y,et al.NiCo₂S₄/Ni(OH)₂ core-shell heterostructured nanotube arrays on carbon-fabric as high-performance pseudocapacitor electrodes[J].Applied Surface Science,2015,349:870-875.
[65] VADIVEL S,NAVEEN A N,KAMALAKANNAN V P,et al.Facile large scale synthesis of Bi₂S₃ nano rods-graphene composite for photocatalytic photoelectrochemical and supercapacitor application[J].Applied Surface Science,2015,351(1):283-290.
[66] PATIL S J,LOKHANDE A C,LOKHANDE C D.Effect of aqueous electrolyte on pseudocapacitive behavior of chemically synthesized La₂S₃ electrode[J].Materials Science in Semiconductor Processing,2016,41:132-136.
[67] KONG D S,WANG J M,SHAO H B,et al. Electrochemical fabrication of a porous nanostructured nickel hydroxide film electrode with superior pseudocapacitive performance[J].Journal of Alloys & Compounds,2011,509(18):5611-5616.
[68] WANG C,QU H,PENG T,et al.Large scale α-Co(OH)₂ needle arrays grown on carbon nanotube foams as free standing electrodes for supercapacitors[J].Electrochimica Acta,2016,191:133-141.
[69] FU W,GONG Y,WANG M,et al.β-Ni(OH)₂ nanosheets grown on graphene as advanced electrochemical pseudocapacitor materials with improved rate capability and cycle performance[J]. Materials Letters,2014,134:107-110.
[70] WU Q,WEN M,CHEN S,et al.Lamellar-crossing-structured Ni(OH)₂/CNTs/Ni(OH)₂,nanocomposite for electrochemical supercapacitor materials[J].Journal of Alloys & Compounds,2015,646:990-997.
[71] YANG S,CHENG K,YE K,et al.A novel asymmetric supercapacitor with buds-like Co(OH)₂ used as cathode materials and activated carbon as anode materials[J].Journal of Electroanalytical Chemistry,2015,741(5):93-99.
[72] CHEN K,XUE D.Water-soluble inorganic salt with ultrahigh specific capacitance:Ce(NO₃)₃ can be designed as excellent pseudocapacitor electrode[J].Journal of Colloid & Interface Science,2014,416(3):172-176.
[73] XU C,CHEN K,HAO W,et al.Functionality of Fe(NO₃)₃ salts as both positive and negative pseudocapacitor electrodes in alkaline aqueous electrolyte[J].Electrochimica Acta,2014,147:216-224.