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Progress in SO42-/MxOysolid superacid catalysts

SONG Hua,YANG Dongming,LI Feng,LIU Quanfu,Xu Qian   

  1. College of Chemistry and Chemical Engineering,Daqing Petroleum Institute
  • Online:2007-02-25 Published:2007-02-25

SO42-/MxOy型固体超强酸催化剂的研究进展

宋 华,杨东明,李 锋,刘全夫,徐 骞   

  1. 大庆石油学院化学化工学院

Abstract: In this paper the catalytic mechanism of SO /MxOy solid superacid catalyst was summarized, and the effects of the preparation methods, including nano-technique, low-temperature aging, coprecipitation impregnation, solid titanium oxide, on catalytic activity were analysed. Meanwhile the research progress in modification of catalysts on carriers, metals or ions, accelerants was discribed in detail. Finally the prospects of the research and applications of superacid catalysts were predicted.

Key words: solid superacid, catalyst, catalyst support, preparation, modification, application

摘要: 概述了SO /MxOy型固体超强酸催化剂的催化机理;分析比较了纳米技术法、低温陈化法、沉淀–混合共沉淀浸渍法、浓硫酸活化钛白粉法等制备出的催化剂对催化性能的影响;介绍了催化剂载体改性、引入金属或离子、促进剂等改性方面的研究进展;展望了固体超强酸催化剂的研究和应用前景。

关键词: 固体超强酸, 催化剂, 催化剂载体, 制备, 改性, 应用

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