Chemical Industry and Engineering Progress ›› 2025, Vol. 44 ›› Issue (5): 2563-2576.DOI: 10.16085/j.issn.1000-6613.2025-0014
• Renewable energy utilization • Previous Articles
Received:2025-01-03
Revised:2025-02-12
Online:2025-05-20
Published:2025-05-25
Contact:
SUN Lili
通讯作者:
孙丽丽
作者简介:魏志强(1984—),男,博士,正高级工程师,研究方向为炼化工程技术开发与设计。E-mail:weizhiqiang.sei@sinopec.com。
CLC Number:
WEI Zhiqiang, SUN Lili. Current status and challenges of ethanol production technology from industrial carbon-rich gas fermentation[J]. Chemical Industry and Engineering Progress, 2025, 44(5): 2563-2576.
魏志强, 孙丽丽. 工业富碳气体发酵制备燃料乙醇技术现状与挑战[J]. 化工进展, 2025, 44(5): 2563-2576.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2025-0014
| 微生物 | 气体底物 | 产物 | 适宜温度/℃ | 适宜pH | 参考文献 |
|---|---|---|---|---|---|
| Acetobacterium woodii | CO2/H2、CO/CO2/H2 | 乙酸 | 30 | 7.0 | [ |
| Butyribacteriaum methylotrophic | CO、CO2/H2 | 乙酸、乙醇、丁酸、丁醇 | 37 | 7.5 | [ |
| Clostridium autoethanogenum | CO、CO2/H2 | 乙酸、乙醇、2,3-丁二醇 | 37 | 6.0 | [ |
| Clostridium carboxidivorans | CO、CO2/H2 | 乙酸、乙醇、丁酸、丁醇、己酸、己醇 | 38 | 5.0~7.0 | [ |
| Clostridium ljungdahlii | CO、CO2/H2 | 乙酸、乙醇、2,3-丁二醇 | 37 | 6.0 | [ |
| Clostridium ragsdalei | CO、CO2/H2 | 乙酸、乙醇、2,3-丁二醇 | 37 | 6.3 | [ |
| Moorella thermoacetica | CO、CO2/H2 | 乙酸 | 55~60 | 6.5~6.8 | [ |
| 微生物 | 气体底物 | 产物 | 适宜温度/℃ | 适宜pH | 参考文献 |
|---|---|---|---|---|---|
| Acetobacterium woodii | CO2/H2、CO/CO2/H2 | 乙酸 | 30 | 7.0 | [ |
| Butyribacteriaum methylotrophic | CO、CO2/H2 | 乙酸、乙醇、丁酸、丁醇 | 37 | 7.5 | [ |
| Clostridium autoethanogenum | CO、CO2/H2 | 乙酸、乙醇、2,3-丁二醇 | 37 | 6.0 | [ |
| Clostridium carboxidivorans | CO、CO2/H2 | 乙酸、乙醇、丁酸、丁醇、己酸、己醇 | 38 | 5.0~7.0 | [ |
| Clostridium ljungdahlii | CO、CO2/H2 | 乙酸、乙醇、2,3-丁二醇 | 37 | 6.0 | [ |
| Clostridium ragsdalei | CO、CO2/H2 | 乙酸、乙醇、2,3-丁二醇 | 37 | 6.3 | [ |
| Moorella thermoacetica | CO、CO2/H2 | 乙酸 | 55~60 | 6.5~6.8 | [ |
| 反应器类型 | 气源组成(质量比) | 反应条件 | 菌种 | 乙醇浓度 | 乙醇合成速率 | 参考文献 |
|---|---|---|---|---|---|---|
| MBR① | CO∶H2∶CO2∶N2= 20∶5∶15∶60 | 37℃ | C.carboxidivorans P7 | 4.89g/L | 2.35g/(L·d) | [ |
| BCR② | CO∶H2∶CO2∶N2= 20∶5∶15∶60 | 37℃ | C. carboxidivorans P7 | 3.20g/L | 1.54g/(L·d) | [ |
| STR③ | CO∶H2∶CO2∶N2= 20∶5∶15∶60 | 37℃ 150r/min | C. ragsdalei P11 | 25.26g/L (59天) | — | [ |
| CSTR-BCR | CO∶H2∶CO2= 60∶35∶5 | 200r/min (BCR) | C. ljungdahlii ERI-2 | 450mmol/L (2.1%) | 0.37g/(L·h) | [ |
| CSTR④ | CO∶H2∶CO2∶Ar= 55∶20∶10∶15 | 33℃, 300~500r/min | C. ljungdahlii | 48g/L(560h) | — | [ |
| CSTR | CO∶H2∶CO2∶Ar= 55∶20∶10∶15 | 37℃ 500r/min | C. ljungdahlii | 6.5g/L (3周) | — | [ |
| HFMBR⑤ | CO∶H2∶CO2∶Ar= 20∶5∶15∶60 | 37℃ | C. carboxidivorans P7 | 23.93g/L | 3.34g/(L·d) | [ |
| TBR⑥ | CO∶H2∶CO2∶N2= 38∶28.5∶28.5∶5 | 37℃ | Clostridium ragsdalei | 5.7g/L (1662h) | 0.80mmol/(L·h) | [ |
| CSTR | CO∶H2∶CO2∶N2= 15∶5∶15∶60 | 37℃ 150r/min | Clostridium strain P11 | 9.6g/L (360h) | 0.58mmol/(L·h) | [ |
| TBR | CO∶H2∶CO2∶N2= 38∶28.5∶28.5∶5 | 37℃ | Clostridium ragsdalei | 4.3g/L (909h) | 3.43mmol/(L·h) | [ |
| 反应器类型 | 气源组成(质量比) | 反应条件 | 菌种 | 乙醇浓度 | 乙醇合成速率 | 参考文献 |
|---|---|---|---|---|---|---|
| MBR① | CO∶H2∶CO2∶N2= 20∶5∶15∶60 | 37℃ | C.carboxidivorans P7 | 4.89g/L | 2.35g/(L·d) | [ |
| BCR② | CO∶H2∶CO2∶N2= 20∶5∶15∶60 | 37℃ | C. carboxidivorans P7 | 3.20g/L | 1.54g/(L·d) | [ |
| STR③ | CO∶H2∶CO2∶N2= 20∶5∶15∶60 | 37℃ 150r/min | C. ragsdalei P11 | 25.26g/L (59天) | — | [ |
| CSTR-BCR | CO∶H2∶CO2= 60∶35∶5 | 200r/min (BCR) | C. ljungdahlii ERI-2 | 450mmol/L (2.1%) | 0.37g/(L·h) | [ |
| CSTR④ | CO∶H2∶CO2∶Ar= 55∶20∶10∶15 | 33℃, 300~500r/min | C. ljungdahlii | 48g/L(560h) | — | [ |
| CSTR | CO∶H2∶CO2∶Ar= 55∶20∶10∶15 | 37℃ 500r/min | C. ljungdahlii | 6.5g/L (3周) | — | [ |
| HFMBR⑤ | CO∶H2∶CO2∶Ar= 20∶5∶15∶60 | 37℃ | C. carboxidivorans P7 | 23.93g/L | 3.34g/(L·d) | [ |
| TBR⑥ | CO∶H2∶CO2∶N2= 38∶28.5∶28.5∶5 | 37℃ | Clostridium ragsdalei | 5.7g/L (1662h) | 0.80mmol/(L·h) | [ |
| CSTR | CO∶H2∶CO2∶N2= 15∶5∶15∶60 | 37℃ 150r/min | Clostridium strain P11 | 9.6g/L (360h) | 0.58mmol/(L·h) | [ |
| TBR | CO∶H2∶CO2∶N2= 38∶28.5∶28.5∶5 | 37℃ | Clostridium ragsdalei | 4.3g/L (909h) | 3.43mmol/(L·h) | [ |
| 类型 | CO/% | CO2/% | H2/% | N2/% | 参考文献 |
|---|---|---|---|---|---|
| 高炉煤气 | 20~35 | 20~30 | 2~4 | 50~60 | [ |
| 转炉煤气 | 50~70 | 10~20 | 1~2 | 15~30 | [ |
| 铁合金尾气 | 65~75 | 0~5 | 5~10 | 5~10 | [ |
| 电石尾气 | 74~85 | 2~10 | 5~10 | 1~8 | [ |
| 黄磷尾气 | 87~92 | 1~4 | 1~8 | 2~5 | [ |
| 生物质气化合成气 | 31~34 | 3~10 | 37~43 | 10~20 | [ |
| 类型 | CO/% | CO2/% | H2/% | N2/% | 参考文献 |
|---|---|---|---|---|---|
| 高炉煤气 | 20~35 | 20~30 | 2~4 | 50~60 | [ |
| 转炉煤气 | 50~70 | 10~20 | 1~2 | 15~30 | [ |
| 铁合金尾气 | 65~75 | 0~5 | 5~10 | 5~10 | [ |
| 电石尾气 | 74~85 | 2~10 | 5~10 | 1~8 | [ |
| 黄磷尾气 | 87~92 | 1~4 | 1~8 | 2~5 | [ |
| 生物质气化合成气 | 31~34 | 3~10 | 37~43 | 10~20 | [ |
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