Chemical Industry and Engineering Progress ›› 2024, Vol. 43 ›› Issue (3): 1506-1523.DOI: 10.16085/j.issn.1000-6613.2023-0376

• Resources and environmental engineering • Previous Articles    

Research progress of polyethyleneimine crosslinked polymer gel system in water-drive reservoirs

WANG Kai1(), LUO Mingliang1(), LI Mingzhong1, HUANG Feifei2, PU Chunsheng1, PU Jingyang3, FAN Qiao1   

  1. 1.College of Petroleum Engineering, China University of Petroleum (East China), Qingdao 266580, Shandong, China
    2.School of Petroleum Engineering and Environmental Engineering, Yan’an University, Yan’an 716000, Shaanxi, China
    3.College of Carbon Neutral Energy, China University of Petroleum (Beijing), Beijing 102249, China
  • Received:2023-03-13 Revised:2023-04-12 Online:2024-04-11 Published:2024-03-10
  • Contact: LUO Mingliang

水驱油藏聚乙烯亚胺交联聚合物凝胶体系研究进展

王凯1(), 罗明良1(), 李明忠1, 黄飞飞2, 蒲春生1, 蒲景阳3, 樊乔1   

  1. 1.中国石油大学(华东)石油工程学院,山东 青岛 266580
    2.延安大学石油工程与环境工程学院,陕西 延安 716000
    3.中国石油大学(北京)碳中和示范性能源学院,北京 102249
  • 通讯作者: 罗明良
  • 作者简介:王凯(1995—),男,博士研究生,研究方向为化学法提高采收率。E-mail:13689288083@163.com
  • 基金资助:
    国家自然科学基金(51874334);陕西省自然科学基础研究计划(2023-JC-QN-0540)

Abstract:

Polyethyleneimine (PEI) is an environment-friendly and low toxic material. PEI and polymer crosslinked gel system has the advantages of controllable gelation time, high strength of mature gel, high-temperature resistance, long-time stability, and almost unaffected by minerals of reservoir. This paper reviewed the research of various polymer gel systems with PEI as crosslinker. The crosslinking mechanism and the characteristics of those gel systems were clarified. The influence of various factors on the gel system was analyzed. And, the methods to improve the gel performance and successful filed trial were listed, the methods to improve the crosslinking activity of gel system were emphatically analyzed. Finally, it was pointed out that polyacrylamide(PAM)/PEI gel system, as an environment-friendly system, had great application prospects in conformance control and water shutoff of medium and low temperature reservoirs, and it was suggested that the method and the corresponding mechanism of improving the crosslinking efficiency of PAM/PEI system should be studied more extensively and deeply to reduce the loading amount of polymer and crosslinker, and provided a theoretical basis and experimental basis for the promotion and application of this system.

Key words: polymers, gels, polyethyleneimine(PEI), crosslinker, viscosity, conformance control and water shutoff

摘要:

聚乙烯亚胺(PEI)是一种低毒性环保材料,它与聚合物交联的凝胶体系具有适用温度范围广、成胶时间可控、成胶后强度大、高温稳定时间长、几乎不受储层岩石矿物影响等优点。本文回顾了以PEI作为交联剂的各类凝胶体系的研究动态,阐明了PEI与各类聚合物的交联反应机理及其凝胶体系特点,分析了各类因素对凝胶性能的影响,并列举了改善凝胶性能的方法和成功的矿场应用实例,重点分析了提高凝胶体系交联活性的方法研究。最后,提出聚丙烯酰胺(PAM)/PEI凝胶体系作为环保型调驱体系在中低温油藏深部调控方面具有非常大的应用前景,应继续深入研究提高PAM/PEI凝胶体系交联效率的方法及其作用机理,以降低聚合物与交联剂用量,为这一体系的推广应用提供理论依据与实验基础。

关键词: 聚合物, 凝胶, 聚乙烯亚胺, 交联剂, 黏度, 调剖堵水

CLC Number: 

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