Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (S1): 328-343.DOI: 10.16085/j.issn.1000-6613.2023-0627
• Materials science and technology • Previous Articles Next Articles
WANG Jiaqing1(), SONG Guangwei1, LI Qiang1(), GUO Shuaicheng2, DAI Qingli3
Received:
2023-04-18
Revised:
2023-05-29
Online:
2023-11-30
Published:
2023-10-25
Contact:
LI Qiang
王家庆1(), 宋广伟1, 李强1(), 郭帅成2, DAI Qingli3
通讯作者:
李强
作者简介:
王家庆(1994—),男,博士,副教授,主要从事可持续交通基础设施材料与结构的研究。E-mail: jiaqingw@njfu.edu.cn。
基金资助:
CLC Number:
WANG Jiaqing, SONG Guangwei, LI Qiang, GUO Shuaicheng, DAI Qingli. Rubber-concrete interface modification method and performance enhancement path[J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 328-343.
王家庆, 宋广伟, 李强, 郭帅成, DAI Qingli. 橡胶混凝土界面改性方法及性能提升路径[J]. 化工进展, 2023, 42(S1): 328-343.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2023-0627
界面改性方法 | 优点 | 缺点 | 作用机理 | 参考文献 |
---|---|---|---|---|
物理改性 | ||||
水洗 | 成本低,环保 | 效果不明显 | 清洗表面杂质,橡胶表面亲水 | [ |
预涂胶凝材料 | 材料易得,改性效果较好 | 预涂工艺,复杂耗时 | 提高橡胶集料的弹性模量,橡胶表面亲水 | [ |
化学改性 | ||||
H2SO4 | 改性效果较好 | 处理复杂耗时 | 去除杂质,橡胶表面亲水 | [ |
KMnO4 | 改性效果较好 | 处理复杂耗时 | 去除杂质,橡胶表面亲水 | [ |
硅烷偶联剂 | 改性效果较好 | 危害环境 | 橡胶和水泥基体间形成化学键,橡胶表面亲水 | [ |
NaOH | 改性效果好,应用广泛 | 处理复杂耗时 | 去除硬脂酸锌和其他杂质,橡胶表面亲水 | [ |
Ca(OH)2 | 成本低 | 应用不广泛 | 去除杂质,橡胶表面亲水 | [ |
部分氧化 | 成本低 | 危害环境,应用不广泛 | 橡胶表面亲水 | [ |
胶乳改性 | 改性效果较好,操作方便 | 成本较高 | 促进橡胶与基体之间的黏合、填充效果好 | [ |
二硫化碳处理 | 成本低,节省材料 | 有毒 | 橡胶表面亲水,促进水泥水化 | [ |
乳化沥青处理 | 改性效果好,经济 | 处理复杂,应用不广泛 | 促进橡胶与基体之间黏合 | [ |
丙酮溶液 | 改性效果较好,操作方便 | 有毒,应用不广泛 | 橡胶表面亲水 | [ |
紫外线辐射 | 成本低,清洁 | 应用不广泛 | 橡胶表面亲水 | [ |
界面改性方法 | 优点 | 缺点 | 作用机理 | 参考文献 |
---|---|---|---|---|
物理改性 | ||||
水洗 | 成本低,环保 | 效果不明显 | 清洗表面杂质,橡胶表面亲水 | [ |
预涂胶凝材料 | 材料易得,改性效果较好 | 预涂工艺,复杂耗时 | 提高橡胶集料的弹性模量,橡胶表面亲水 | [ |
化学改性 | ||||
H2SO4 | 改性效果较好 | 处理复杂耗时 | 去除杂质,橡胶表面亲水 | [ |
KMnO4 | 改性效果较好 | 处理复杂耗时 | 去除杂质,橡胶表面亲水 | [ |
硅烷偶联剂 | 改性效果较好 | 危害环境 | 橡胶和水泥基体间形成化学键,橡胶表面亲水 | [ |
NaOH | 改性效果好,应用广泛 | 处理复杂耗时 | 去除硬脂酸锌和其他杂质,橡胶表面亲水 | [ |
Ca(OH)2 | 成本低 | 应用不广泛 | 去除杂质,橡胶表面亲水 | [ |
部分氧化 | 成本低 | 危害环境,应用不广泛 | 橡胶表面亲水 | [ |
胶乳改性 | 改性效果较好,操作方便 | 成本较高 | 促进橡胶与基体之间的黏合、填充效果好 | [ |
二硫化碳处理 | 成本低,节省材料 | 有毒 | 橡胶表面亲水,促进水泥水化 | [ |
乳化沥青处理 | 改性效果好,经济 | 处理复杂,应用不广泛 | 促进橡胶与基体之间黏合 | [ |
丙酮溶液 | 改性效果较好,操作方便 | 有毒,应用不广泛 | 橡胶表面亲水 | [ |
紫外线辐射 | 成本低,清洁 | 应用不广泛 | 橡胶表面亲水 | [ |
纤维 种类 | 橡胶 替代率 | 纤维 体积率/体积掺量 | 抗压强度 变化 | 劈裂抗拉 强度变化 | 抗弯强度 变化 | 其他性能 | 参考文献 |
---|---|---|---|---|---|---|---|
钢纤维 | 5%,10%,15% | 0.5%,0.75%,1% | 掺量<0.75% 有一定提高 | 随纤维掺量增加 提高8% | 随纤维掺量增加 提高60% | 弹性模量随钢纤维掺量增加而提高 | [ |
0,5%,10%,15% | 0,0.5%,1%,1.5% | 0.5%纤维 增长幅度最大 | 1%纤维 提高28% | — | 10%橡胶+1%钢纤维协同作用较好 | [ | |
5% | 1%,1.5%,2% | 层布式降低 全掺式稳定 | 层布式稳定 全掺式提高 | 层布式提高 全掺式提高 | 体积率不超过1.5%优选层布式 体积率为2%采用全掺式 | [ | |
0,10%,20% | 0,0.25%,0.5%,1% | — | — | — | 纤维用量0~1%时,初始裂纹和最终破坏的抗冲击性分别提高了2.90倍和5.09倍 | [ | |
0~35% | 0,0.35%,1% | — | — | — | 抗剪强度提高,缩小裂纹 | [ | |
10%,20% | 0.5%,1% | — | — | 随纤维掺量增加提高 | 密度和吸收率略有增加,韧性和耐磨性也显著提高,不影响抗滑性 | [ | |
5% | 0,0.5%,1%,1.5% | — | — | — | 提高韧性,初始黏结强度、极限黏结强度等随纤维体积率增加先增大后降低 | [ | |
10% | 0,1%,1.5%,2% | 2%纤维 提高26.6% | — | 随纤维掺量增加提高 | 钢纤维对质量损失率的影响为正,对相对动态弹性模量的影响为负 | [ | |
5%,10% | 1%,1.5% | 提高 | — | — | 纤维与橡胶取代率的增加导致强度对应的轴向应变和侧向应变的增加 | [ | |
10%,15%,25% | 0.2% | — | — | 提高 | 纤维与橡胶结合对提高混凝土的裂纹扩展和耗能具有积极的耦合作用 | [ | |
聚乙烯醇纤维 | 15%,20%,25% | 0.5% | 略有降低 | — | 提高 | 改善力学性能,提高断裂能 良好的冻融性能和长期耐久性 | [ |
4%,8%,12%,16% | 0.1%,0.3%,0.5%,0.7% | — | — | — | 12%橡胶、0.1%纤维、温度20℃时抗渗性最好 | [ | |
5%,10%,15%,20% | 2.4kg/m³ | 28天 强度提高 | — | 降低 | 提高阻尼率,但加剧其界面缺陷 | [ | |
5%,10%,15% | 0.1%,0.2%,0.3% | 提高 | 提高 | 提高 | 玄武岩纤维和PVA纤维复合提高了强度 | [ | |
10%,20%,30% | 0.1%,0.2%,0.3% | 略有提高 | 提高 | 提高 | 混杂纤维复合对混凝土的劈裂抗拉强度和弯曲强度有积极的影响 | [ | |
玄武岩纤维 | 10% | 0.05%,0.1%,0.15%,0.2% | 随纤维掺量增加提高 | — | 随纤维掺量增加提高 | 纤维掺量为0.2%时混凝土强度最大 | [ |
5%~30% | 1~5kg/m³ | 1~3kg/m³ 强度提高 | — | — | 提高试件整体性和抗压强度,提高抗冻性能 | [ | |
15% | 0.08%,0.10%,0.12% | 0.1%纤维 强度提升最佳 | — | — | 纤维进一步提高抗冲击性能 | [ | |
10% | 2kg/m³,4kg/m³ | — | 提高 | 提高 | 较好的强度和变形性能,增韧效果明显 | [ | |
0~1% | 0.1% | 提高 | 提高 | — | 提高干缩性和抗冻性 | [ | |
10% | 4.56kg/m³ | — | — | 提高 | 提高工作性能 | [ | |
聚丙烯纤维 | 2%,6%,10% | 0.1%,0.5%,0.9% | 降低 | 先提高 后降低 | 降低 | 改善韧性,纤维掺量0.5%内最佳 | [ |
20% | 0.6kg/m³,1.2kg/m³ | 1.2kg/m³ 提升11.7% | 1.2kg/m³ 提升13.4% | 1.2kg/m³ 提升19.4% | 1.2kg/m³弹性模量提升15.5% | [ | |
5%,10% | 1%,2% | 提高 | 提高 | 提高 | 韧性和延性随纤维增加而提升 | [ | |
3%,6%, 9%,12% | 0.1%,0.2%,0.3% | 纤维增加 强度提高 | 略有提高 | 略有提高 | 密度略有提高 | [ |
纤维 种类 | 橡胶 替代率 | 纤维 体积率/体积掺量 | 抗压强度 变化 | 劈裂抗拉 强度变化 | 抗弯强度 变化 | 其他性能 | 参考文献 |
---|---|---|---|---|---|---|---|
钢纤维 | 5%,10%,15% | 0.5%,0.75%,1% | 掺量<0.75% 有一定提高 | 随纤维掺量增加 提高8% | 随纤维掺量增加 提高60% | 弹性模量随钢纤维掺量增加而提高 | [ |
0,5%,10%,15% | 0,0.5%,1%,1.5% | 0.5%纤维 增长幅度最大 | 1%纤维 提高28% | — | 10%橡胶+1%钢纤维协同作用较好 | [ | |
5% | 1%,1.5%,2% | 层布式降低 全掺式稳定 | 层布式稳定 全掺式提高 | 层布式提高 全掺式提高 | 体积率不超过1.5%优选层布式 体积率为2%采用全掺式 | [ | |
0,10%,20% | 0,0.25%,0.5%,1% | — | — | — | 纤维用量0~1%时,初始裂纹和最终破坏的抗冲击性分别提高了2.90倍和5.09倍 | [ | |
0~35% | 0,0.35%,1% | — | — | — | 抗剪强度提高,缩小裂纹 | [ | |
10%,20% | 0.5%,1% | — | — | 随纤维掺量增加提高 | 密度和吸收率略有增加,韧性和耐磨性也显著提高,不影响抗滑性 | [ | |
5% | 0,0.5%,1%,1.5% | — | — | — | 提高韧性,初始黏结强度、极限黏结强度等随纤维体积率增加先增大后降低 | [ | |
10% | 0,1%,1.5%,2% | 2%纤维 提高26.6% | — | 随纤维掺量增加提高 | 钢纤维对质量损失率的影响为正,对相对动态弹性模量的影响为负 | [ | |
5%,10% | 1%,1.5% | 提高 | — | — | 纤维与橡胶取代率的增加导致强度对应的轴向应变和侧向应变的增加 | [ | |
10%,15%,25% | 0.2% | — | — | 提高 | 纤维与橡胶结合对提高混凝土的裂纹扩展和耗能具有积极的耦合作用 | [ | |
聚乙烯醇纤维 | 15%,20%,25% | 0.5% | 略有降低 | — | 提高 | 改善力学性能,提高断裂能 良好的冻融性能和长期耐久性 | [ |
4%,8%,12%,16% | 0.1%,0.3%,0.5%,0.7% | — | — | — | 12%橡胶、0.1%纤维、温度20℃时抗渗性最好 | [ | |
5%,10%,15%,20% | 2.4kg/m³ | 28天 强度提高 | — | 降低 | 提高阻尼率,但加剧其界面缺陷 | [ | |
5%,10%,15% | 0.1%,0.2%,0.3% | 提高 | 提高 | 提高 | 玄武岩纤维和PVA纤维复合提高了强度 | [ | |
10%,20%,30% | 0.1%,0.2%,0.3% | 略有提高 | 提高 | 提高 | 混杂纤维复合对混凝土的劈裂抗拉强度和弯曲强度有积极的影响 | [ | |
玄武岩纤维 | 10% | 0.05%,0.1%,0.15%,0.2% | 随纤维掺量增加提高 | — | 随纤维掺量增加提高 | 纤维掺量为0.2%时混凝土强度最大 | [ |
5%~30% | 1~5kg/m³ | 1~3kg/m³ 强度提高 | — | — | 提高试件整体性和抗压强度,提高抗冻性能 | [ | |
15% | 0.08%,0.10%,0.12% | 0.1%纤维 强度提升最佳 | — | — | 纤维进一步提高抗冲击性能 | [ | |
10% | 2kg/m³,4kg/m³ | — | 提高 | 提高 | 较好的强度和变形性能,增韧效果明显 | [ | |
0~1% | 0.1% | 提高 | 提高 | — | 提高干缩性和抗冻性 | [ | |
10% | 4.56kg/m³ | — | — | 提高 | 提高工作性能 | [ | |
聚丙烯纤维 | 2%,6%,10% | 0.1%,0.5%,0.9% | 降低 | 先提高 后降低 | 降低 | 改善韧性,纤维掺量0.5%内最佳 | [ |
20% | 0.6kg/m³,1.2kg/m³ | 1.2kg/m³ 提升11.7% | 1.2kg/m³ 提升13.4% | 1.2kg/m³ 提升19.4% | 1.2kg/m³弹性模量提升15.5% | [ | |
5%,10% | 1%,2% | 提高 | 提高 | 提高 | 韧性和延性随纤维增加而提升 | [ | |
3%,6%, 9%,12% | 0.1%,0.2%,0.3% | 纤维增加 强度提高 | 略有提高 | 略有提高 | 密度略有提高 | [ |
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