Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (2): 794-802.DOI: 10.16085/j.issn.1000-6613.2022-0736
• Industrial catalysis • Previous Articles Next Articles
CHEN Hao(), ZHANG Chuanhao, YU Feng, FAN Binbin(), LI Ruifeng
Received:
2022-04-24
Revised:
2022-06-08
Online:
2023-03-13
Published:
2023-02-25
Contact:
FAN Binbin
通讯作者:
范彬彬
作者简介:
陈昊(1997—),男,硕士研究生,从事沸石合成及催化性能研究。E-mail:ksernisu@qq.com。
基金资助:
CLC Number:
CHEN Hao, ZHANG Chuanhao, YU Feng, FAN Binbin, LI Ruifeng. Catalytic performance of zeolite Y in oligomerization of isobutyl alcohol[J]. Chemical Industry and Engineering Progress, 2023, 42(2): 794-802.
陈昊, 张传浩, 于峰, 范彬彬, 李瑞丰. Y型沸石在异丁醇齐聚反应中的催化性能[J]. 化工进展, 2023, 42(2): 794-802.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-0736
样品 | BET比表面积/m2·g-1 | 微孔面积/m2·g-1 | 外表面积/m2·g-1 | 总孔体积/cm3·g-1 | 微孔体积/cm3·g-1 | 介孔体积/cm3·g-1 |
---|---|---|---|---|---|---|
HY-8.0 | 746 | 704 | 42 | 0.32 | 0.27 | 0.05 |
HY-13.0 | 750 | 630 | 120 | 0.44 | 0.24 | 0.20 |
HY-20.9 | 859 | 736 | 123 | 0.48 | 0.28 | 0.20 |
HY-28.0 | 906 | 768 | 138 | 0.52 | 0.30 | 0.22 |
HY-30.7 | 905 | 775 | 130 | 0.53 | 0.30 | 0.23 |
样品 | BET比表面积/m2·g-1 | 微孔面积/m2·g-1 | 外表面积/m2·g-1 | 总孔体积/cm3·g-1 | 微孔体积/cm3·g-1 | 介孔体积/cm3·g-1 |
---|---|---|---|---|---|---|
HY-8.0 | 746 | 704 | 42 | 0.32 | 0.27 | 0.05 |
HY-13.0 | 750 | 630 | 120 | 0.44 | 0.24 | 0.20 |
HY-20.9 | 859 | 736 | 123 | 0.48 | 0.28 | 0.20 |
HY-28.0 | 906 | 768 | 138 | 0.52 | 0.30 | 0.22 |
HY-30.7 | 905 | 775 | 130 | 0.53 | 0.30 | 0.23 |
样品 | 脱附峰温度/℃ | 峰面积 | 总酸量 |
---|---|---|---|
HY-8.0 | 239 | 914 | 3265 |
352 | 1403 | ||
462 | 948 | ||
HY-13.0 | 139 | 414 | 2101 |
195 | 1020 | ||
423 | 667 | ||
HY-20.9 | 129 | 265 | 1178 |
189 | 658 | ||
392 | 255 | ||
HY-28.0 | 125 | 169 | 1124 |
177 | 686 | ||
388 | 269 | ||
HY-30.7 | 133 | 144 | 609 |
187 | 297 | ||
403 | 168 |
样品 | 脱附峰温度/℃ | 峰面积 | 总酸量 |
---|---|---|---|
HY-8.0 | 239 | 914 | 3265 |
352 | 1403 | ||
462 | 948 | ||
HY-13.0 | 139 | 414 | 2101 |
195 | 1020 | ||
423 | 667 | ||
HY-20.9 | 129 | 265 | 1178 |
189 | 658 | ||
392 | 255 | ||
HY-28.0 | 125 | 169 | 1124 |
177 | 686 | ||
388 | 269 | ||
HY-30.7 | 133 | 144 | 609 |
187 | 297 | ||
403 | 168 |
样品 | 温度/K | L酸量/µmol·g-1 | B酸量/µmol·g-1 | 总酸量/µmol·g-1 | L酸/B酸 |
---|---|---|---|---|---|
HY-8.0 | 423 | 710 | 360 | 1070 | 1.97 |
623 | 640 | 330 | 970 | 1.94 | |
HY-13.0 | 423 | 123 | 389 | 512 | 0.32 |
623 | 65 | 316 | 381 | 0.21 | |
HY-20.9 | 423 | 97 | 262 | 359 | 0.37 |
623 | 47 | 217 | 264 | 0.21 | |
HY-28.0 | 423 | 54 | 236 | 290 | 0.23 |
623 | 36 | 186 | 222 | 0.19 | |
HY-30.7 | 423 | 35 | 182 | 217 | 0.19 |
623 | 24 | 144 | 168 | 0.16 |
样品 | 温度/K | L酸量/µmol·g-1 | B酸量/µmol·g-1 | 总酸量/µmol·g-1 | L酸/B酸 |
---|---|---|---|---|---|
HY-8.0 | 423 | 710 | 360 | 1070 | 1.97 |
623 | 640 | 330 | 970 | 1.94 | |
HY-13.0 | 423 | 123 | 389 | 512 | 0.32 |
623 | 65 | 316 | 381 | 0.21 | |
HY-20.9 | 423 | 97 | 262 | 359 | 0.37 |
623 | 47 | 217 | 264 | 0.21 | |
HY-28.0 | 423 | 54 | 236 | 290 | 0.23 |
623 | 36 | 186 | 222 | 0.19 | |
HY-30.7 | 423 | 35 | 182 | 217 | 0.19 |
623 | 24 | 144 | 168 | 0.16 |
样品 | BET比表面积/m2·g-1 | 微孔面积/m2·g-1 | 外表面积/m2·g-1 | 总孔体积/cm3·g-1 | 介孔体积/cm3·g-1 | 微孔体积/cm3·g-1 |
---|---|---|---|---|---|---|
HY-20.9 | 864 | 737 | 127 | 0.49 | 0.21 | 0.28 |
Hβ-22.4 | 582 | 471 | 111 | 0.38 | 0.20 | 0.18 |
样品 | BET比表面积/m2·g-1 | 微孔面积/m2·g-1 | 外表面积/m2·g-1 | 总孔体积/cm3·g-1 | 介孔体积/cm3·g-1 | 微孔体积/cm3·g-1 |
---|---|---|---|---|---|---|
HY-20.9 | 864 | 737 | 127 | 0.49 | 0.21 | 0.28 |
Hβ-22.4 | 582 | 471 | 111 | 0.38 | 0.20 | 0.18 |
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