Chemical Industry and Engineering Progress ›› 2022, Vol. 41 ›› Issue (11): 5783-5799.DOI: 10.16085/j.issn.1000-6613.2022-0117
• Industrial catalysis • Previous Articles Next Articles
HAN He1(), ZHANG Xinhao1(), ZHANG Anfeng1, ZHAO Chenghao2, SHI Chuan1, YU Zhengxi3, SONG Chunshan1,4, GUO Xinwen1()
Received:
2022-01-08
Revised:
2022-04-08
Online:
2022-11-28
Published:
2022-11-25
Contact:
GUO Xinwen
韩贺1(), 张锌豪1(), 张安峰1, 赵成浩2, 石川1, 于政锡3, 宋春山1,4, 郭新闻1()
通讯作者:
郭新闻
作者简介:
韩贺(1988—),男,博士后,助理研究员,研究方向为分子筛合成与多相催化。E-mail:hehan@dlut.edu.cn基金资助:
CLC Number:
HAN He, ZHANG Xinhao, ZHANG Anfeng, ZHAO Chenghao, SHI Chuan, YU Zhengxi, SONG Chunshan, GUO Xinwen. Development of shape-selective alkylation of toluene with methanol to para-xylene[J]. Chemical Industry and Engineering Progress, 2022, 41(11): 5783-5799.
韩贺, 张锌豪, 张安峰, 赵成浩, 石川, 于政锡, 宋春山, 郭新闻. 甲苯与甲醇择形催化制对二甲苯技术进展[J]. 化工进展, 2022, 41(11): 5783-5799.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-0117
名称 | 拓扑结构 | 分子筛结构 | 孔道尺寸 | 反应条件 | 改性条件 | 对二甲苯 选择性/% | 甲苯 转化率/% | 参考文献 |
---|---|---|---|---|---|---|---|---|
SAPO-5 | AFI | 一维十二元环孔道 | 直孔道0.73nm×0.73nm | 400℃;常压; F/W=0.24mol·g-1·h-1; n(T)/n(M)=2 | 未改性 | 25.0 | 16.0 | [ |
β | BEA | 三维十二元环孔道 | 直孔道0.73nm×0.60nm 弯曲孔道0.56nm×0.56nm | 300℃;常压; WHSV=17.3min-1; n(T)/n(M)=4 | 未改性 | 29.4 | 6.7 | [ |
Y | FAU | 由SOD笼和六方柱笼连接围成八面沸石笼,笼间通过十二元环相连 | 孔口直径0.74~0.74nm | 225℃;常压; F/W=0.008mol·g-1·h-1; n(T)/n(M)=2 | 阳离子交换 | 51.0 | 28.9 | [ |
Mordenite | MOR | c轴方向十二元环主孔道和平行的八元环侧通道 | 主孔道0.65nm×0.70nm 侧通道0.28nm×0.57nm | 400℃;常压; 催化剂/进料比例为5 n(T)/n(M)=1 | 未改性 | 24.2 | 49.6 | [ |
ZSM-12 | MTW | 十二元环构成的一维线性非交叉孔道 | 0.57nm×0.61nm | 300℃;常压;LHSV=2.5h-1 n(T)/n(M)=0.5 | 未改性 | 50.9 | 61.7 | [ |
SAPO-11 | AEL | 一维十元环孔道 | 0.39nm×0.64nm | 450℃;常压; WHSV=2h-1 n(T)/n(M)=2 | 金属/非金属 改性;硅氧 烷试剂修饰 | 89.5 | 6.7 | [ |
SAPO-41 | AFO | 一维椭圆十元环孔道 | 0.43nm×0.7nm | 400℃;常压; WHSV=4.5h-1 n(T)/n(M)=2 | 未改性 | 37.9 | 57.6 | [ |
MCM-22 | MWW | 具有十元环交叉孔道、十元环开口的十二元环超笼及表面的十二元环孔穴 | 正弦孔道0.51nm×0.41nm 短孔道0.55nm×0.40nm | 250℃;常压; F/W=0.47mol·g-1·h-1; n(T)/n(M)=1 | 三甲基吡啶 处理 | 74.1 | 3.8 | [ |
ZSM-5 | MFI | 由截面椭圆形的十元环直孔道和截面近乎圆形的正弦孔道相互交叉构成 | 直孔道0.53nm×0.56nm 正弦孔道0.51nm×0.55nm | 460℃;常压; WHSV=2h-1; n(T)/n(M)=2; n(H2)/n(H2O)/n(T+M)=8/8/1 | Si-P-Mg 改性后负载Pt | 98.0 | 23.0 | [ |
460℃;0.2MPa; WHSV=2.5h-1; n(T)/n(M)=4; n(H2)/n(H2O)/n(T+M)=2/2/1 | Si-P-Mg 改性后负载Pt | 94.0 | 12.0 | [ |
名称 | 拓扑结构 | 分子筛结构 | 孔道尺寸 | 反应条件 | 改性条件 | 对二甲苯 选择性/% | 甲苯 转化率/% | 参考文献 |
---|---|---|---|---|---|---|---|---|
SAPO-5 | AFI | 一维十二元环孔道 | 直孔道0.73nm×0.73nm | 400℃;常压; F/W=0.24mol·g-1·h-1; n(T)/n(M)=2 | 未改性 | 25.0 | 16.0 | [ |
β | BEA | 三维十二元环孔道 | 直孔道0.73nm×0.60nm 弯曲孔道0.56nm×0.56nm | 300℃;常压; WHSV=17.3min-1; n(T)/n(M)=4 | 未改性 | 29.4 | 6.7 | [ |
Y | FAU | 由SOD笼和六方柱笼连接围成八面沸石笼,笼间通过十二元环相连 | 孔口直径0.74~0.74nm | 225℃;常压; F/W=0.008mol·g-1·h-1; n(T)/n(M)=2 | 阳离子交换 | 51.0 | 28.9 | [ |
Mordenite | MOR | c轴方向十二元环主孔道和平行的八元环侧通道 | 主孔道0.65nm×0.70nm 侧通道0.28nm×0.57nm | 400℃;常压; 催化剂/进料比例为5 n(T)/n(M)=1 | 未改性 | 24.2 | 49.6 | [ |
ZSM-12 | MTW | 十二元环构成的一维线性非交叉孔道 | 0.57nm×0.61nm | 300℃;常压;LHSV=2.5h-1 n(T)/n(M)=0.5 | 未改性 | 50.9 | 61.7 | [ |
SAPO-11 | AEL | 一维十元环孔道 | 0.39nm×0.64nm | 450℃;常压; WHSV=2h-1 n(T)/n(M)=2 | 金属/非金属 改性;硅氧 烷试剂修饰 | 89.5 | 6.7 | [ |
SAPO-41 | AFO | 一维椭圆十元环孔道 | 0.43nm×0.7nm | 400℃;常压; WHSV=4.5h-1 n(T)/n(M)=2 | 未改性 | 37.9 | 57.6 | [ |
MCM-22 | MWW | 具有十元环交叉孔道、十元环开口的十二元环超笼及表面的十二元环孔穴 | 正弦孔道0.51nm×0.41nm 短孔道0.55nm×0.40nm | 250℃;常压; F/W=0.47mol·g-1·h-1; n(T)/n(M)=1 | 三甲基吡啶 处理 | 74.1 | 3.8 | [ |
ZSM-5 | MFI | 由截面椭圆形的十元环直孔道和截面近乎圆形的正弦孔道相互交叉构成 | 直孔道0.53nm×0.56nm 正弦孔道0.51nm×0.55nm | 460℃;常压; WHSV=2h-1; n(T)/n(M)=2; n(H2)/n(H2O)/n(T+M)=8/8/1 | Si-P-Mg 改性后负载Pt | 98.0 | 23.0 | [ |
460℃;0.2MPa; WHSV=2.5h-1; n(T)/n(M)=4; n(H2)/n(H2O)/n(T+M)=2/2/1 | Si-P-Mg 改性后负载Pt | 94.0 | 12.0 | [ |
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