Chemical Industry and Engineering Progress ›› 2022, Vol. 41 ›› Issue (4): 2161-2170.DOI: 10.16085/j.issn.1000-6613.2021-0823
• Resources and environmental engineering • Previous Articles Next Articles
DENG Yaling1(), SHU Jiancheng1(), CHEN Mengjun1, LEI Tianya1, ZENG Xiangfei1, YANG Yong2, LIU Zuohua2
Received:
2021-04-19
Revised:
2021-06-21
Online:
2022-04-25
Published:
2022-04-23
Contact:
SHU Jiancheng
邓亚玲1(), 舒建成1(), 陈梦君1, 雷天涯1, 曾祥菲1, 杨勇2, 刘作华2
通讯作者:
舒建成
作者简介:
邓亚玲(1997—),女,硕士研究生,研究方向为电解锰渣污染治理。E-mail:基金资助:
CLC Number:
DENG Yaling, SHU Jiancheng, CHEN Mengjun, LEI Tianya, ZENG Xiangfei, YANG Yong, LIU Zuohua. Physical and chemical properties analysis of electrolytic manganese residue in different storage times[J]. Chemical Industry and Engineering Progress, 2022, 41(4): 2161-2170.
邓亚玲, 舒建成, 陈梦君, 雷天涯, 曾祥菲, 杨勇, 刘作华. 不同堆存时间电解锰渣的理化特性分析[J]. 化工进展, 2022, 41(4): 2161-2170.
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堆存时间 编号 | Mn | Ca | Mg | Se | Cu | Cr | Cd | Pb | Zn | Fe | Al |
---|---|---|---|---|---|---|---|---|---|---|---|
a | 71700 | 102500 | 18105 | 480 | 550 | 274 | 250 | 350 | 895 | 56400 | 13010 |
b | 58150 | 90600 | 14955 | 340 | 535 | 295 | 150 | 345 | 1020 | 56600 | 14905 |
c | 51200 | 74100 | 9960 | 305 | 521 | 240 | 120 | 380 | 695 | 59100 | 19790 |
d | 37505 | 83250 | 8615 | 290 | 512 | 225 | 135 | 362 | 562 | 56650 | 16275 |
e | 34960 | 96600 | 8165 | 260 | 523 | 230 | 110 | 350 | 600 | 68550 | 18145 |
f | 29865 | 81350 | 8205 | 190 | 518 | 200 | 115 | 341 | 553 | 73850 | 22255 |
堆存时间 编号 | Mn | Ca | Mg | Se | Cu | Cr | Cd | Pb | Zn | Fe | Al |
---|---|---|---|---|---|---|---|---|---|---|---|
a | 71700 | 102500 | 18105 | 480 | 550 | 274 | 250 | 350 | 895 | 56400 | 13010 |
b | 58150 | 90600 | 14955 | 340 | 535 | 295 | 150 | 345 | 1020 | 56600 | 14905 |
c | 51200 | 74100 | 9960 | 305 | 521 | 240 | 120 | 380 | 695 | 59100 | 19790 |
d | 37505 | 83250 | 8615 | 290 | 512 | 225 | 135 | 362 | 562 | 56650 | 16275 |
e | 34960 | 96600 | 8165 | 260 | 523 | 230 | 110 | 350 | 600 | 68550 | 18145 |
f | 29865 | 81350 | 8205 | 190 | 518 | 200 | 115 | 341 | 553 | 73850 | 22255 |
评价标准 | Cu | Cr | Cd | Pb | Zn | Mn | ||
---|---|---|---|---|---|---|---|---|
土壤质量标准 | Ⅰ | 自然背景 | 35 | 90 | 0.2 | 35 | 100 | — |
<6.5 | 50 | 150 | 0.3 | 250 | 200 | — | ||
Ⅱ | 6.5~7.5 | 100 | 200 | 0.3 | 300 | 250 | — | |
>7.5 | 100 | 250 | 0.6 | 350 | 300 | — | ||
Ⅲ | >6.5 | 400 | 300 | 1 | 500 | 500 | — | |
广西土壤背景值 | 23.1 | 65.3 | 0.073 | 19.5 | 51.8 | 176 |
评价标准 | Cu | Cr | Cd | Pb | Zn | Mn | ||
---|---|---|---|---|---|---|---|---|
土壤质量标准 | Ⅰ | 自然背景 | 35 | 90 | 0.2 | 35 | 100 | — |
<6.5 | 50 | 150 | 0.3 | 250 | 200 | — | ||
Ⅱ | 6.5~7.5 | 100 | 200 | 0.3 | 300 | 250 | — | |
>7.5 | 100 | 250 | 0.6 | 350 | 300 | — | ||
Ⅲ | >6.5 | 400 | 300 | 1 | 500 | 500 | — | |
广西土壤背景值 | 23.1 | 65.3 | 0.073 | 19.5 | 51.8 | 176 |
堆存时间编号 | Mn2+ | NH | Se4+ | Pb2+ | Cd2+ | 总Cr | Cu2+ | Zn2+ | Ni2+ |
---|---|---|---|---|---|---|---|---|---|
a | 1533 | 6675 | 8.7 | 0.73 | 0.12 | 0.32 | 45.3 | 38.1 | 3.5 |
b | 859.3 | 6425 | 6.4 | 0.62 | 0.15 | 0.45 | 36.5 | 30.3 | 3.8 |
c | 777.4 | 5675 | 15.2 | 0.63 | 0.26 | 0.41 | 37.2 | 27.2 | 4.2 |
d | 772.5 | 2175 | 11.9 | 0.74 | 0.21 | 0.32 | 38.6 | 26.9 | 4.3 |
e | 509.6 | 925 | 10.9 | 0.82 | 0.39 | 0.30 | 39.3 | 30.8 | 3.8 |
f | 204.4 | 675 | 11.4 | 0.76 | 0.35 | 0.25 | 37.5 | 29.8 | 3.1 |
GB 8978—1996 一级 | 2.0 | 15.0 | — | 1.0 | 0.1 | 1.5 | 0.5 | 2.0 | 1.0 |
堆存时间编号 | Mn2+ | NH | Se4+ | Pb2+ | Cd2+ | 总Cr | Cu2+ | Zn2+ | Ni2+ |
---|---|---|---|---|---|---|---|---|---|
a | 1533 | 6675 | 8.7 | 0.73 | 0.12 | 0.32 | 45.3 | 38.1 | 3.5 |
b | 859.3 | 6425 | 6.4 | 0.62 | 0.15 | 0.45 | 36.5 | 30.3 | 3.8 |
c | 777.4 | 5675 | 15.2 | 0.63 | 0.26 | 0.41 | 37.2 | 27.2 | 4.2 |
d | 772.5 | 2175 | 11.9 | 0.74 | 0.21 | 0.32 | 38.6 | 26.9 | 4.3 |
e | 509.6 | 925 | 10.9 | 0.82 | 0.39 | 0.30 | 39.3 | 30.8 | 3.8 |
f | 204.4 | 675 | 11.4 | 0.76 | 0.35 | 0.25 | 37.5 | 29.8 | 3.1 |
GB 8978—1996 一级 | 2.0 | 15.0 | — | 1.0 | 0.1 | 1.5 | 0.5 | 2.0 | 1.0 |
堆存时间编号 | 总量锰/mg·kg-1 | 可溶性锰/mg·L-1 | 锰溶出率/% |
---|---|---|---|
a | 71700 | 1533 | 19.2 |
b | 58150 | 859.3 | 13.3 |
c | 51200 | 777.4 | 13.7 |
d | 37505 | 772.5 | 18.5 |
e | 34960 | 509.6 | 13.1 |
f | 29865 | 204.4 | 6.2 |
堆存时间编号 | 总量锰/mg·kg-1 | 可溶性锰/mg·L-1 | 锰溶出率/% |
---|---|---|---|
a | 71700 | 1533 | 19.2 |
b | 58150 | 859.3 | 13.3 |
c | 51200 | 777.4 | 13.7 |
d | 37505 | 772.5 | 18.5 |
e | 34960 | 509.6 | 13.1 |
f | 29865 | 204.4 | 6.2 |
项目 | 总量锰 | 可溶性锰 |
---|---|---|
总量锰 | 1 | |
可溶性锰 | 0.009** | 1 |
项目 | 总量锰 | 可溶性锰 |
---|---|---|
总量锰 | 1 | |
可溶性锰 | 0.009** | 1 |
堆存时间 编号 | SO3 | SiO2 | CaO | Fe2O3 | MnO | Al2O3 | MgO | K2O | P2O5 | TiO2 | BaO | 其他 |
---|---|---|---|---|---|---|---|---|---|---|---|---|
a | 32.43 | 26.6 | 16.23 | 9.78 | 7.97 | 2.82 | 2.48 | 0.74 | 0.33 | 0.17 | 0.18 | 0.27 |
b | 31.72 | 25.24 | 17.31 | 10.40 | 8.76 | 2.69 | 2.03 | 0.78 | 0.35 | 0.19 | 0.21 | 0.32 |
c | 30.18 | 25.76 | 16.38 | 13.29 | 7.79 | 3.31 | 1.43 | 0.85 | 0.39 | 0.22 | 0.21 | 0.19 |
d | 31.29 | 28.07 | 17.52 | 10.37 | 5.95 | 3.32 | 1.65 | 0.89 | 0.35 | 0.17 | 0.22 | 0.20 |
e | 31.43 | 27.27 | 19.32 | 10.20 | 5.19 | 3.60 | 1.35 | 0.73 | 0.34 | 0.21 | 0.17 | 0.19 |
f | 28.29 | 33.12 | 16.98 | 9.80 | 4.02 | 4.50 | 1.32 | 1.03 | 0.30 | 0.26 | 0.21 | 0.17 |
堆存时间 编号 | SO3 | SiO2 | CaO | Fe2O3 | MnO | Al2O3 | MgO | K2O | P2O5 | TiO2 | BaO | 其他 |
---|---|---|---|---|---|---|---|---|---|---|---|---|
a | 32.43 | 26.6 | 16.23 | 9.78 | 7.97 | 2.82 | 2.48 | 0.74 | 0.33 | 0.17 | 0.18 | 0.27 |
b | 31.72 | 25.24 | 17.31 | 10.40 | 8.76 | 2.69 | 2.03 | 0.78 | 0.35 | 0.19 | 0.21 | 0.32 |
c | 30.18 | 25.76 | 16.38 | 13.29 | 7.79 | 3.31 | 1.43 | 0.85 | 0.39 | 0.22 | 0.21 | 0.19 |
d | 31.29 | 28.07 | 17.52 | 10.37 | 5.95 | 3.32 | 1.65 | 0.89 | 0.35 | 0.17 | 0.22 | 0.20 |
e | 31.43 | 27.27 | 19.32 | 10.20 | 5.19 | 3.60 | 1.35 | 0.73 | 0.34 | 0.21 | 0.17 | 0.19 |
f | 28.29 | 33.12 | 16.98 | 9.80 | 4.02 | 4.50 | 1.32 | 1.03 | 0.30 | 0.26 | 0.21 | 0.17 |
XPS扫描区域 | 堆存时间 编号 | 参数 | FeOOH | Fe3O4 | γ-Fe2O3 | 卫星峰 |
---|---|---|---|---|---|---|
Fe 2p3/2 | a | 结合能/eV | 711.56 | 714.61 | 717.68 | 720.27 |
含量/% | 57.51 | 14.31 | 14.31 | |||
b | 结合能/eV | 711.47 | 714.35 | 717.21 | 721.14 | |
含量/% | 56.68 | 14.54 | 15.82 | |||
c | 结合能/eV | 711.23 | 713.87 | 716.56 | 720.22 | |
含量/% | 56.41 | 15.52 | 16.26 | |||
d | 结合能/eV | 711.48 | 714.1 | 716.81 | 720.92 | |
含量/% | 55.56 | 14.33 | 16.24 | |||
e | 结合能/eV | 711.39 | 714.21 | 717.21 | 721.96 | |
含量/% | 55.04 | 16.23 | 15.72 | |||
f | 结合能/eV | 711.64 | 714.33 | 718.26 | 721.23 | |
含量/% | 49.18 | 24.96 | 14.10 |
XPS扫描区域 | 堆存时间 编号 | 参数 | FeOOH | Fe3O4 | γ-Fe2O3 | 卫星峰 |
---|---|---|---|---|---|---|
Fe 2p3/2 | a | 结合能/eV | 711.56 | 714.61 | 717.68 | 720.27 |
含量/% | 57.51 | 14.31 | 14.31 | |||
b | 结合能/eV | 711.47 | 714.35 | 717.21 | 721.14 | |
含量/% | 56.68 | 14.54 | 15.82 | |||
c | 结合能/eV | 711.23 | 713.87 | 716.56 | 720.22 | |
含量/% | 56.41 | 15.52 | 16.26 | |||
d | 结合能/eV | 711.48 | 714.1 | 716.81 | 720.92 | |
含量/% | 55.56 | 14.33 | 16.24 | |||
e | 结合能/eV | 711.39 | 714.21 | 717.21 | 721.96 | |
含量/% | 55.04 | 16.23 | 15.72 | |||
f | 结合能/eV | 711.64 | 714.33 | 718.26 | 721.23 | |
含量/% | 49.18 | 24.96 | 14.10 |
XPS扫描区域 | 堆存时间编号 | 参数 | Mn2O3 | MnO2 | KMnO4 |
---|---|---|---|---|---|
Mn 2p3/2 | a | 结合能/eV | 641.44 | 642.67 | 646.7 |
含量/% | 19.53 | 64.16 | 16.31 | ||
b | 结合能/eV | 641.57 | 643.23 | 646.85 | |
含量/% | 42.6 | 42.61 | 14.79 | ||
c | 结合能/eV | 641.73 | 643.43 | 646.77 | |
含量/% | 50.29 | 34.92 | 14.79 | ||
d | 结合能/eV | 641.5 | 643.28 | 646.82 | |
含量/% | 50.42 | 36.39 | 13.19 | ||
e | 结合能/eV | 641.85 | 644.08 | 647.49 | |
含量/% | 54.09 | 29.28 | 16.63 | ||
f | 结合能/eV | 641.88 | 643.87 | 647.2 | |
含量/% | 59.84 | 25.88 | 14.28 |
XPS扫描区域 | 堆存时间编号 | 参数 | Mn2O3 | MnO2 | KMnO4 |
---|---|---|---|---|---|
Mn 2p3/2 | a | 结合能/eV | 641.44 | 642.67 | 646.7 |
含量/% | 19.53 | 64.16 | 16.31 | ||
b | 结合能/eV | 641.57 | 643.23 | 646.85 | |
含量/% | 42.6 | 42.61 | 14.79 | ||
c | 结合能/eV | 641.73 | 643.43 | 646.77 | |
含量/% | 50.29 | 34.92 | 14.79 | ||
d | 结合能/eV | 641.5 | 643.28 | 646.82 | |
含量/% | 50.42 | 36.39 | 13.19 | ||
e | 结合能/eV | 641.85 | 644.08 | 647.49 | |
含量/% | 54.09 | 29.28 | 16.63 | ||
f | 结合能/eV | 641.88 | 643.87 | 647.2 | |
含量/% | 59.84 | 25.88 | 14.28 |
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