Chemical Industry and Engineering Progress ›› 2024, Vol. 43 ›› Issue (3): 1178-1198.DOI: 10.16085/j.issn.1000-6613.2023-0401
• Energy processes and technology • Previous Articles
WU Fengming1,2(), LI Shuaiqi1,2, HE Shihui2, SONG Wenji1,2(), FENG Ziping1,2
Received:
2023-03-16
Revised:
2023-05-08
Online:
2024-04-11
Published:
2024-03-10
Contact:
SONG Wenji
吴锋明1,2(), 李帅旗1,2, 何世辉2, 宋文吉1,2(), 冯自平1,2
通讯作者:
宋文吉
作者简介:
吴锋明(1999—),男,硕士研究生,研究方向为高温热泵技术及应用。E-mail:wufm@ms.giec.ac.cn。
基金资助:
CLC Number:
WU Fengming, LI Shuaiqi, HE Shihui, SONG Wenji, FENG Ziping. Research progress on optimization of large temperature-lift vapor compression heat pump system[J]. Chemical Industry and Engineering Progress, 2024, 43(3): 1178-1198.
吴锋明, 李帅旗, 何世辉, 宋文吉, 冯自平. 大温升蒸汽压缩式热泵系统优化研究进展[J]. 化工进展, 2024, 43(3): 1178-1198.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2023-0401
100年GWP | 描述分类 |
---|---|
<30 | 极低或者可忽略不计 |
<100 | 低 |
<300 | 较低 |
300~1000 | 中等 |
>1000 | 高 |
>3000 | 较高 |
>10000 | 极高 |
100年GWP | 描述分类 |
---|---|
<30 | 极低或者可忽略不计 |
<100 | 低 |
<300 | 较低 |
300~1000 | 中等 |
>1000 | 高 |
>3000 | 较高 |
>10000 | 极高 |
制冷剂分类 | 制冷剂名称 | ODP | GWP | 临界压力 /MPa | 临界温度 /℃ | 冷凝潜热(30℃饱和状态下) /kJ·kg-1 | 大温升理论压缩比 (蒸发/冷凝温度) | 参考 文献 |
---|---|---|---|---|---|---|---|---|
自然制冷剂 | R718 | 0 | <1 | 22.12 | 374.2 | 2429.0 | 5.53(110/170℃) | [ |
R744 | 0 | 1 | 7.38 | 31.1 | Non① | 2.34(-20/40℃) 2.21(5/65℃) | [ | |
R717 | 0 | <1 | 11.33 | 132.3 | 1144.6 | 5.718(5/65℃) | [ | |
有机纯制冷剂 | ||||||||
HCs族制冷剂 | R290 | 0 | <3 | 4.25 | 96.7 | 326.7 | 5.60(-20/40℃) 4.26(5/65℃) | [ |
R600 | 0 | 约20 | 3.80 | 152.0 | 356.3 | 4.26(5/65℃) 3.97(60/120℃) | [ | |
R600a | 0 | 约3 | 3.63 | 134.7 | 323.3 | 5.23(5/65℃) 3.38(60/120℃) | [ | |
氢氟烯烃(HFOs)族制冷剂 | R1234ze(Z) | 0 | <1 | 3.53 | 150.1 | 203.1 | 4.74(60/120℃) | [ |
R1234ze(E) | 0 | <1 | 3.63 | 109.4 | 163.1 | 5.53(5/65℃) | [ | |
R1336mzz(Z) | 0 | <10 | 2.90 | 171.35 | 166.2 | 4.50(60/120℃) | [ | |
R1234yf | 0 | <1 | 3.38 | 94.7 | 141.2 | 4.92(5/65℃) | [ | |
HCFOs族制冷剂 | R1233zd(E) | 0② | 1 | 3.62 | 166.5 | 188.5 | 4.03(60/120℃) | [ |
R1224yd(Z) | 0② | <1 | 3.33 | 155.5 | 161.5 | 3.97(60/120℃) | [ | |
混合制冷剂 | ||||||||
R32基混合制冷剂 | R454a | 0 | 239 | 4.63 | 81.7 | 173.3 | 4.12(5/65℃) | [ |
R457a | 0 | 139 | 4.30 | 90.0 | 172.2 | 5.98(-20/40℃) 4.46(5/65℃) | [ | |
HFOs基混合制冷剂 | R445a | 0 | 130 | 4.54 | 106.1 | 167.9 | 3.80(5/65℃) | [ |
R454c | 0 | 146 | 4.31 | 82.4 | 193.0 | 5.84(-20/40℃) 4.36(5/65℃) | [ | |
CO2基混合制冷剂 | R744/R600a(7%/93%) | 0 | 20 | 4.41 | 146.2 | 341.82 | 4.11(60/120℃) | [ |
R455a | 0 | 145 | 4.65 | 85.6 | 252.1 | 4.04(5/65℃) | [ |
制冷剂分类 | 制冷剂名称 | ODP | GWP | 临界压力 /MPa | 临界温度 /℃ | 冷凝潜热(30℃饱和状态下) /kJ·kg-1 | 大温升理论压缩比 (蒸发/冷凝温度) | 参考 文献 |
---|---|---|---|---|---|---|---|---|
自然制冷剂 | R718 | 0 | <1 | 22.12 | 374.2 | 2429.0 | 5.53(110/170℃) | [ |
R744 | 0 | 1 | 7.38 | 31.1 | Non① | 2.34(-20/40℃) 2.21(5/65℃) | [ | |
R717 | 0 | <1 | 11.33 | 132.3 | 1144.6 | 5.718(5/65℃) | [ | |
有机纯制冷剂 | ||||||||
HCs族制冷剂 | R290 | 0 | <3 | 4.25 | 96.7 | 326.7 | 5.60(-20/40℃) 4.26(5/65℃) | [ |
R600 | 0 | 约20 | 3.80 | 152.0 | 356.3 | 4.26(5/65℃) 3.97(60/120℃) | [ | |
R600a | 0 | 约3 | 3.63 | 134.7 | 323.3 | 5.23(5/65℃) 3.38(60/120℃) | [ | |
氢氟烯烃(HFOs)族制冷剂 | R1234ze(Z) | 0 | <1 | 3.53 | 150.1 | 203.1 | 4.74(60/120℃) | [ |
R1234ze(E) | 0 | <1 | 3.63 | 109.4 | 163.1 | 5.53(5/65℃) | [ | |
R1336mzz(Z) | 0 | <10 | 2.90 | 171.35 | 166.2 | 4.50(60/120℃) | [ | |
R1234yf | 0 | <1 | 3.38 | 94.7 | 141.2 | 4.92(5/65℃) | [ | |
HCFOs族制冷剂 | R1233zd(E) | 0② | 1 | 3.62 | 166.5 | 188.5 | 4.03(60/120℃) | [ |
R1224yd(Z) | 0② | <1 | 3.33 | 155.5 | 161.5 | 3.97(60/120℃) | [ | |
混合制冷剂 | ||||||||
R32基混合制冷剂 | R454a | 0 | 239 | 4.63 | 81.7 | 173.3 | 4.12(5/65℃) | [ |
R457a | 0 | 139 | 4.30 | 90.0 | 172.2 | 5.98(-20/40℃) 4.46(5/65℃) | [ | |
HFOs基混合制冷剂 | R445a | 0 | 130 | 4.54 | 106.1 | 167.9 | 3.80(5/65℃) | [ |
R454c | 0 | 146 | 4.31 | 82.4 | 193.0 | 5.84(-20/40℃) 4.36(5/65℃) | [ | |
CO2基混合制冷剂 | R744/R600a(7%/93%) | 0 | 20 | 4.41 | 146.2 | 341.82 | 4.11(60/120℃) | [ |
R455a | 0 | 145 | 4.65 | 85.6 | 252.1 | 4.04(5/65℃) | [ |
研究者 | 研究方法 | 采用工质 | 蒸发温度/℃ | 冷凝(气冷)温度/℃ | 温升范围/℃ | COP |
---|---|---|---|---|---|---|
Wu等 [ | 实验 | R718 | 75~85 | 110~150 | 35~65 | 1.9~6.1 |
沈九兵等[ | 模拟 | R718 | 75~90 | 120~130 | 30~55 | 4.0~11.1 |
于振国等[ | 模拟 | R744 | -25~-5 | 50~70 | 45~65℃ | 1.8~2.4 |
Wang等[ | 实验 | R744 | -25~-15 | 35~45 | 15~55 | 1.5~2.4 |
Ivanovski等[ | 模拟 | R717 | -20~25 | 65~80 | 40~100 | 2.9~6.5 |
Zhao等[ | 实验 | R717 | 25~35 | 75~105 | 50~70 | 3.0~5.5 |
研究者 | 研究方法 | 采用工质 | 蒸发温度/℃ | 冷凝(气冷)温度/℃ | 温升范围/℃ | COP |
---|---|---|---|---|---|---|
Wu等 [ | 实验 | R718 | 75~85 | 110~150 | 35~65 | 1.9~6.1 |
沈九兵等[ | 模拟 | R718 | 75~90 | 120~130 | 30~55 | 4.0~11.1 |
于振国等[ | 模拟 | R744 | -25~-5 | 50~70 | 45~65℃ | 1.8~2.4 |
Wang等[ | 实验 | R744 | -25~-15 | 35~45 | 15~55 | 1.5~2.4 |
Ivanovski等[ | 模拟 | R717 | -20~25 | 65~80 | 40~100 | 2.9~6.5 |
Zhao等[ | 实验 | R717 | 25~35 | 75~105 | 50~70 | 3.0~5.5 |
研究者 | 研究方法 | 采用工质 | 蒸发温度/℃ | 冷凝温度/℃ | 温升范围/℃ | COP |
---|---|---|---|---|---|---|
Liu等[ | 实验 | R290 | -30~-10 | 50 | 50~70 | 1.9~4.2 |
Nawaz等[ | 模拟 | R290 | 10 | 60 | 50 | 3.6 |
潘利生等[ | 实验 | R600 | 30~50 | 60~95 | 10~50 | 3.0~5.5 |
Bamigbetan等[ | 模拟 | R600 | 50~70 | 115~135 | 40~75 | 2.1~3.2 |
Nawaz等[ | 模拟 | R600a | 10 | 60 | 50 | 3.2 |
Bamigbetan等[ | 模拟 | R600a | 50~70 | 115~135 | 40~75 | 1.5~3.1 |
Zhang等[ | 实验 | R1234ze(Z) | 25~40 | 70~85 | 45~58 | 3.0~3.5 |
Fukuda等[ | 模拟 | R1234ze(Z) | 60,80 | 110,130 | 50 | 6.3,6.6 |
Colombo等[ | 实验 | R1234ze(E) | -5~15 | 25~65 | 10~70 | 1.4~5.0 |
Kondou等[ | 模拟 | R1234ze(E) | 35 | 75~95 | 40~60 | 2.9~4.8 |
Sulaiman等[ | 模拟 | R1336mzz(Z) | 60,70 | 90~140 | 30~70 | 2.7~9.1 |
Arpagaus等[ | 实验 | R1336mzz(Z) | 30~70 | 80~130 | 30~70 | 1.3~4.0 |
Yildiz等[ | 实验 | R1234yf | -10~0 | 35 | 45 | 4.0~4.5 |
Alkan等[ | 实验 | R1234yf | -10,0 | 55~70 | 55~70 | 2.4~4.6 |
Mateu-Royo等[ | 模拟 | R1233zd(E) | 70~100 | 145 | 45~75 | 1.6~2.7 |
Alhamid等[ | 模拟 | R1233zd(E) | 50~70 | 110 | 40~60 | 2.7~4.7 |
Mateu-Royo等[ | 模拟 | R1224yd(Z) | 70~100 | 145 | 45~75 | 1.5~2.6 |
Arpagaus等[ | 实验 | R1224yd(Z) | 30~70 | 70~140 | 30~70 | 1.4~4.5 |
研究者 | 研究方法 | 采用工质 | 蒸发温度/℃ | 冷凝温度/℃ | 温升范围/℃ | COP |
---|---|---|---|---|---|---|
Liu等[ | 实验 | R290 | -30~-10 | 50 | 50~70 | 1.9~4.2 |
Nawaz等[ | 模拟 | R290 | 10 | 60 | 50 | 3.6 |
潘利生等[ | 实验 | R600 | 30~50 | 60~95 | 10~50 | 3.0~5.5 |
Bamigbetan等[ | 模拟 | R600 | 50~70 | 115~135 | 40~75 | 2.1~3.2 |
Nawaz等[ | 模拟 | R600a | 10 | 60 | 50 | 3.2 |
Bamigbetan等[ | 模拟 | R600a | 50~70 | 115~135 | 40~75 | 1.5~3.1 |
Zhang等[ | 实验 | R1234ze(Z) | 25~40 | 70~85 | 45~58 | 3.0~3.5 |
Fukuda等[ | 模拟 | R1234ze(Z) | 60,80 | 110,130 | 50 | 6.3,6.6 |
Colombo等[ | 实验 | R1234ze(E) | -5~15 | 25~65 | 10~70 | 1.4~5.0 |
Kondou等[ | 模拟 | R1234ze(E) | 35 | 75~95 | 40~60 | 2.9~4.8 |
Sulaiman等[ | 模拟 | R1336mzz(Z) | 60,70 | 90~140 | 30~70 | 2.7~9.1 |
Arpagaus等[ | 实验 | R1336mzz(Z) | 30~70 | 80~130 | 30~70 | 1.3~4.0 |
Yildiz等[ | 实验 | R1234yf | -10~0 | 35 | 45 | 4.0~4.5 |
Alkan等[ | 实验 | R1234yf | -10,0 | 55~70 | 55~70 | 2.4~4.6 |
Mateu-Royo等[ | 模拟 | R1233zd(E) | 70~100 | 145 | 45~75 | 1.6~2.7 |
Alhamid等[ | 模拟 | R1233zd(E) | 50~70 | 110 | 40~60 | 2.7~4.7 |
Mateu-Royo等[ | 模拟 | R1224yd(Z) | 70~100 | 145 | 45~75 | 1.5~2.6 |
Arpagaus等[ | 实验 | R1224yd(Z) | 30~70 | 70~140 | 30~70 | 1.4~4.5 |
研究者 | 研究方法 | 采用工质 | 蒸发温度/℃ | 冷凝温度/℃ | 温升范围/℃ | COP |
---|---|---|---|---|---|---|
Oruç等[ | 实验 | R454a | -5~5 | 30~50 | 25~55 | 1.2~3.2 |
Devecioğlu等[ | 模拟 | R457a | -25~0 | 30~40 | 30~65 | 3.2~6.2 |
Devecioğlu等[ | 模拟 | R445a | -5~5 | 30~60 | 25~65℃ | 1.7~5 |
闫伟国等[ | 实验 | R454c | -7 | 55 | 62 | 2.1 |
范晓伟等[ | 实验 | R744/R600a(7%/93%) | 10 | 70 | 60 | 3.7 |
Devecioğlu等[ | 模拟 | R455a | -5~5 | 35~55 | 30~60 | 1.1~3.0 |
研究者 | 研究方法 | 采用工质 | 蒸发温度/℃ | 冷凝温度/℃ | 温升范围/℃ | COP |
---|---|---|---|---|---|---|
Oruç等[ | 实验 | R454a | -5~5 | 30~50 | 25~55 | 1.2~3.2 |
Devecioğlu等[ | 模拟 | R457a | -25~0 | 30~40 | 30~65 | 3.2~6.2 |
Devecioğlu等[ | 模拟 | R445a | -5~5 | 30~60 | 25~65℃ | 1.7~5 |
闫伟国等[ | 实验 | R454c | -7 | 55 | 62 | 2.1 |
范晓伟等[ | 实验 | R744/R600a(7%/93%) | 10 | 70 | 60 | 3.7 |
Devecioğlu等[ | 模拟 | R455a | -5~5 | 35~55 | 30~60 | 1.1~3.0 |
优化技术 | 研究者 | 系统运行场景 | 工质 | 蒸发温度 /℃ | 冷凝(气冷) 温度①/℃ | 温升程度 /℃ | COP | 系统性能提升情况 |
---|---|---|---|---|---|---|---|---|
回热技术 | 王辉等[ | 利用油田低温余热制备55℃热水 | R744 | 0℃ | 60~95 | 60~95 | 3.3~4.1 | 最优冷凝压力条件下系统运行压力可降低4.2%,COP提高1.7% |
Sun等[ | 制备物料干燥、印刷等场景需要的65~100℃热水 | R1270/正己烷 | 0~10 | 75~100 | 65~100 | 2.2~6.1 | 达到与同等情况CO2跨临界循环相近COP值,同时显著降低排气压力 | |
补液/补气增焓技术 | 杨文军等[ | 低环境温度(-15℃以下)供暖 | R410a | -25 | 60~80 | 85~105 | — | 补液降低排气温度20% 左右 |
d’Angelo等[ | 低环境温度供暖 | R600a/R290 | -23 | 55 | 78 | 1.69 | COP较无补气装置提升了24%左右,排气温度降低了15%左右 | |
喷射技术 | Sarkar[ | 低环境温度供暖 | R744 | -45~0 | 30~60 | 30~105 | 2.2~11.2 | 㶲效率最多可提高9%,最优排气压力最多可降低10% |
Qin等[ | 制备60℃生活 热水 | R744 | 5 | 85 | 80 | 4.27 | 与无喷射装置循环相比,㶲效率提高22% | |
多级蒸发冷凝技术 | Chua等[ | 热泵干燥机 | R22 | 2~10 | 60 | 50~58 | 2.2~3.0 | 与单级蒸发器系统相比,回收的热量最多可增加35% |
李小燕等[ | 制备60℃以上生活热水 | R744 | 0~15 | 70~110 | 55~110 | 3.5~4.8 | 较常规CO2热泵系统COP提高了9.88%,不可逆损失降低了24.50% | |
串联多级压缩技术 | Redón等[ | 热源与散热器温差超过70℃ | R290 | -20~0 | 65 | 65~85 | 2.47~3.62 | 二级系统COP可以提高30%,且不良的二级系统会损失6%~10%的COP |
Kosmadakis等[ | 产热温度在120℃以上的高温热泵 | R1234ze(Z) | 30~90 | 100~150 | 10~120 | 1.5~6 | 在变化范围内COP提升程度为20%~95%;同时温升程度在50~60℃范围内二级循环投资回报周期最短 | |
复叠式压缩技术 | 神户制钢[ | 产生165℃工业用高温蒸汽 | R245fa/R718 | 30~60 | 150~180 | 90~160 | 1.6~2.5 | 达到与工业燃气锅炉相同水平的蒸汽产生能力;较单级循环COP提升24%以上 |
Wang等[ | 严寒条件供应85℃热水的控制策略优化 | R134a/R744 | -30~-5 | 95 | 100~125 | 1.7~2.0 | 成功收敛到校准的最佳值中间温度,稳定误差为0.8%,相比于使用参考控制策略的热泵循环,COP平均提高了10.6% | |
涡流管技术 | Liu等[ | CO2热泵供暖 | R744 | -10~10 | 100 | 90~110 | 1.5~2.6 | 一定条件下较无涡流管循环,COP提高了33.7% |
Zhao等[ | CO2热泵供应生活热水 | R744 | -15~3 | 90 | 87~105 | 2.9~3.9 | 该循环的COP可提高至3.9,与传统CO2热泵循环相比可提高16.8% |
优化技术 | 研究者 | 系统运行场景 | 工质 | 蒸发温度 /℃ | 冷凝(气冷) 温度①/℃ | 温升程度 /℃ | COP | 系统性能提升情况 |
---|---|---|---|---|---|---|---|---|
回热技术 | 王辉等[ | 利用油田低温余热制备55℃热水 | R744 | 0℃ | 60~95 | 60~95 | 3.3~4.1 | 最优冷凝压力条件下系统运行压力可降低4.2%,COP提高1.7% |
Sun等[ | 制备物料干燥、印刷等场景需要的65~100℃热水 | R1270/正己烷 | 0~10 | 75~100 | 65~100 | 2.2~6.1 | 达到与同等情况CO2跨临界循环相近COP值,同时显著降低排气压力 | |
补液/补气增焓技术 | 杨文军等[ | 低环境温度(-15℃以下)供暖 | R410a | -25 | 60~80 | 85~105 | — | 补液降低排气温度20% 左右 |
d’Angelo等[ | 低环境温度供暖 | R600a/R290 | -23 | 55 | 78 | 1.69 | COP较无补气装置提升了24%左右,排气温度降低了15%左右 | |
喷射技术 | Sarkar[ | 低环境温度供暖 | R744 | -45~0 | 30~60 | 30~105 | 2.2~11.2 | 㶲效率最多可提高9%,最优排气压力最多可降低10% |
Qin等[ | 制备60℃生活 热水 | R744 | 5 | 85 | 80 | 4.27 | 与无喷射装置循环相比,㶲效率提高22% | |
多级蒸发冷凝技术 | Chua等[ | 热泵干燥机 | R22 | 2~10 | 60 | 50~58 | 2.2~3.0 | 与单级蒸发器系统相比,回收的热量最多可增加35% |
李小燕等[ | 制备60℃以上生活热水 | R744 | 0~15 | 70~110 | 55~110 | 3.5~4.8 | 较常规CO2热泵系统COP提高了9.88%,不可逆损失降低了24.50% | |
串联多级压缩技术 | Redón等[ | 热源与散热器温差超过70℃ | R290 | -20~0 | 65 | 65~85 | 2.47~3.62 | 二级系统COP可以提高30%,且不良的二级系统会损失6%~10%的COP |
Kosmadakis等[ | 产热温度在120℃以上的高温热泵 | R1234ze(Z) | 30~90 | 100~150 | 10~120 | 1.5~6 | 在变化范围内COP提升程度为20%~95%;同时温升程度在50~60℃范围内二级循环投资回报周期最短 | |
复叠式压缩技术 | 神户制钢[ | 产生165℃工业用高温蒸汽 | R245fa/R718 | 30~60 | 150~180 | 90~160 | 1.6~2.5 | 达到与工业燃气锅炉相同水平的蒸汽产生能力;较单级循环COP提升24%以上 |
Wang等[ | 严寒条件供应85℃热水的控制策略优化 | R134a/R744 | -30~-5 | 95 | 100~125 | 1.7~2.0 | 成功收敛到校准的最佳值中间温度,稳定误差为0.8%,相比于使用参考控制策略的热泵循环,COP平均提高了10.6% | |
涡流管技术 | Liu等[ | CO2热泵供暖 | R744 | -10~10 | 100 | 90~110 | 1.5~2.6 | 一定条件下较无涡流管循环,COP提高了33.7% |
Zhao等[ | CO2热泵供应生活热水 | R744 | -15~3 | 90 | 87~105 | 2.9~3.9 | 该循环的COP可提高至3.9,与传统CO2热泵循环相比可提高16.8% |
项目 | 神户制钢SGH165[ | 中科院广州能源研究所高温热泵机组[ | 欧适能 IWWDS-ER3c4[ | 上海交通大学空气源 热泵锅炉系统[ | 大金二级压缩VRV热泵空调[ |
---|---|---|---|---|---|
工质 | R245fa/R718 | R245fa | R245fa | R410A/R245fa/R718 | R410A |
优化技术 | 复叠式压缩技术 | 补气增焓技术 | 补气增焓技术 | 复叠式压缩技术 | 串联二级压缩技术 |
温升范围 | 50℃→165℃ | 40℃→120℃ | 50℃→120℃ | 15℃→120℃ | -10℃→40℃ |
性能系数 | 2.0 | 2.8 | 3.0 | 1.4 | 3.15 |
最大制热功率/kW | 660 | 360 | 750 | 1351 | 63 |
样机图片 |
项目 | 神户制钢SGH165[ | 中科院广州能源研究所高温热泵机组[ | 欧适能 IWWDS-ER3c4[ | 上海交通大学空气源 热泵锅炉系统[ | 大金二级压缩VRV热泵空调[ |
---|---|---|---|---|---|
工质 | R245fa/R718 | R245fa | R245fa | R410A/R245fa/R718 | R410A |
优化技术 | 复叠式压缩技术 | 补气增焓技术 | 补气增焓技术 | 复叠式压缩技术 | 串联二级压缩技术 |
温升范围 | 50℃→165℃ | 40℃→120℃ | 50℃→120℃ | 15℃→120℃ | -10℃→40℃ |
性能系数 | 2.0 | 2.8 | 3.0 | 1.4 | 3.15 |
最大制热功率/kW | 660 | 360 | 750 | 1351 | 63 |
样机图片 |
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