Chemical Industry and Engineering Progress ›› 2023, Vol. 42 ›› Issue (11): 5981-5992.DOI: 10.16085/j.issn.1000-6613.2022-2259
• Resources and environmental engineering • Previous Articles
KE Yuxin1,2(), ZHU Xiaoli1,2(), SI Shaocheng1,2, ZHANG Ting1,2, WANG Junqiang1,3, ZHANG Ziye3
Received:
2022-12-04
Revised:
2023-04-23
Online:
2023-12-15
Published:
2023-11-20
Contact:
ZHU Xiaoli
柯玉鑫1,2(), 朱晓丽1,2(), 司绍诚1,2, 张婷1,2, 王军强1,3, 张子夜3
通讯作者:
朱晓丽
作者简介:
柯玉鑫(1997—),男,博士研究生,研究方向为多介质污染物修复技术。E-mail:keyuxin_ak@163.com。
基金资助:
CLC Number:
KE Yuxin, ZHU Xiaoli, SI Shaocheng, ZHANG Ting, WANG Junqiang, ZHANG Ziye. Adsorbent derived from spent bleaching earth for the synergistic removal of tetracycline and copper in wastewater[J]. Chemical Industry and Engineering Progress, 2023, 42(11): 5981-5992.
柯玉鑫, 朱晓丽, 司绍诚, 张婷, 王军强, 张子夜. 废白土衍生吸附剂协同去除水中的四环素和铜[J]. 化工进展, 2023, 42(11): 5981-5992.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2022-2259
扩散模型 | Cu2+ | TC | ||
---|---|---|---|---|
BE500 | BE700 | BE500 | BE700 | |
准一级动力学 | ||||
Qe/mg·g-1 | 13.4 | 17.0 | 30.7 | 26.9 |
k1/h-1 | 3.270 | 1.770 | 3.327 | 3.538 |
R2 | 0.423 | 0.719 | 0.698 | 0.640 |
准二级动力学 | ||||
Qe/mg·g-1 | 14.6 | 18.6 | 31.9 | 27.995 |
k2/g·mg-1·h-1 | 0.306 | 0.126 | 0.184 | 0.220 |
R2 | 0.700 | 0.873 | 0.930 | 0.917 |
液膜扩散模型 | ||||
Kfd/mg·g-1 | 0.102 | 0.104 | 0.317 | 0.292 |
R2 | 0.951 | 0.963 | 0.965 | 0.949 |
C/mg·L-1 | -0.729 | -0.519 | -1.312 | -1.249 |
颗粒内扩散模型 | ||||
Ki/mg·g-1·h0.5 | 2.158 | 3.506 | 2.398 | 2.147 |
R2 | 0.979 | 0.978 | 0.627 | 0.719 |
C/mg·L-1 | 8.396 | 7.866 | 23.245 | 20.407 |
扩散模型 | Cu2+ | TC | ||
---|---|---|---|---|
BE500 | BE700 | BE500 | BE700 | |
准一级动力学 | ||||
Qe/mg·g-1 | 13.4 | 17.0 | 30.7 | 26.9 |
k1/h-1 | 3.270 | 1.770 | 3.327 | 3.538 |
R2 | 0.423 | 0.719 | 0.698 | 0.640 |
准二级动力学 | ||||
Qe/mg·g-1 | 14.6 | 18.6 | 31.9 | 27.995 |
k2/g·mg-1·h-1 | 0.306 | 0.126 | 0.184 | 0.220 |
R2 | 0.700 | 0.873 | 0.930 | 0.917 |
液膜扩散模型 | ||||
Kfd/mg·g-1 | 0.102 | 0.104 | 0.317 | 0.292 |
R2 | 0.951 | 0.963 | 0.965 | 0.949 |
C/mg·L-1 | -0.729 | -0.519 | -1.312 | -1.249 |
颗粒内扩散模型 | ||||
Ki/mg·g-1·h0.5 | 2.158 | 3.506 | 2.398 | 2.147 |
R2 | 0.979 | 0.978 | 0.627 | 0.719 |
C/mg·L-1 | 8.396 | 7.866 | 23.245 | 20.407 |
参数 | Cu2+ | TC | ||||
---|---|---|---|---|---|---|
BE500 | BE700 | BE500 | BE700 | |||
Langmuir | ||||||
15℃ | Qm | 12.999 | 15.248 | 36.124 | 36.091 | |
KL | 0.996 | 30.313 | 0.154 | 0.098 | ||
R2 | 0.469 | 0.577 | 0.933 | 0.950 | ||
25℃ | Qm | 14.098 | 17.930 | 41.090 | 36.821 | |
KL | 2.790 | 206.743 | 0.176 | 0.202 | ||
R2 | 0.534 | 0.942 | 0.942 | 0.943 | ||
35℃ | Qm | 15.790 | 20.643 | 41.950 | 46.705 | |
KL | 9.516 | 9.039 | 0.310 | 0.121 | ||
R2 | 0.832 | 0.897 | 0.908 | 0.899 | ||
Freundlich | ||||||
15℃ | KF | 7.050 | 11.959 | 8.831 | 6.348 | |
n | 21.358 | 11.485 | 2.938 | 2.529 | ||
R2 | 0.818 | 0.856 | 0.997 | 0.981 | ||
25℃ | KF | 9.314 | 14.849 | 10.442 | 9.559 | |
n | 7.463 | 13.947 | 3.037 | 3.070 | ||
R2 | 0.848 | 0.970 | 0.993 | 0.972 | ||
35℃ | KF | 11.786 | 14.645 | 12.212 | 8.519 | |
n | 9.901 | 7.680 | 3.173 | 2.456 | ||
R2 | 0.972 | 0.958 | 0.979 | 0.959 |
参数 | Cu2+ | TC | ||||
---|---|---|---|---|---|---|
BE500 | BE700 | BE500 | BE700 | |||
Langmuir | ||||||
15℃ | Qm | 12.999 | 15.248 | 36.124 | 36.091 | |
KL | 0.996 | 30.313 | 0.154 | 0.098 | ||
R2 | 0.469 | 0.577 | 0.933 | 0.950 | ||
25℃ | Qm | 14.098 | 17.930 | 41.090 | 36.821 | |
KL | 2.790 | 206.743 | 0.176 | 0.202 | ||
R2 | 0.534 | 0.942 | 0.942 | 0.943 | ||
35℃ | Qm | 15.790 | 20.643 | 41.950 | 46.705 | |
KL | 9.516 | 9.039 | 0.310 | 0.121 | ||
R2 | 0.832 | 0.897 | 0.908 | 0.899 | ||
Freundlich | ||||||
15℃ | KF | 7.050 | 11.959 | 8.831 | 6.348 | |
n | 21.358 | 11.485 | 2.938 | 2.529 | ||
R2 | 0.818 | 0.856 | 0.997 | 0.981 | ||
25℃ | KF | 9.314 | 14.849 | 10.442 | 9.559 | |
n | 7.463 | 13.947 | 3.037 | 3.070 | ||
R2 | 0.848 | 0.970 | 0.993 | 0.972 | ||
35℃ | KF | 11.786 | 14.645 | 12.212 | 8.519 | |
n | 9.901 | 7.680 | 3.173 | 2.456 | ||
R2 | 0.972 | 0.958 | 0.979 | 0.959 |
吸附剂 | 理论最大吸附量(Qm) | 参考文献 | |
---|---|---|---|
TC | Cu2+ | ||
BE500 | 41.090mg/g | 本研究 | |
BE700 | 17.930mg/g | 本研究 | |
茶渣生物炭 | 8.081mg/g | [ | |
壳聚糖 | 4.24mg/g | [ | |
改性石英砂 | 25.60mg/g | [ | |
多基团秸秆纤维 | 4.71mg/g | [ | |
自养硝化颗粒污泥 | 15.02mg/g | [ | |
苹果树枝生物炭 | 15.85mg/g | [ |
吸附剂 | 理论最大吸附量(Qm) | 参考文献 | |
---|---|---|---|
TC | Cu2+ | ||
BE500 | 41.090mg/g | 本研究 | |
BE700 | 17.930mg/g | 本研究 | |
茶渣生物炭 | 8.081mg/g | [ | |
壳聚糖 | 4.24mg/g | [ | |
改性石英砂 | 25.60mg/g | [ | |
多基团秸秆纤维 | 4.71mg/g | [ | |
自养硝化颗粒污泥 | 15.02mg/g | [ | |
苹果树枝生物炭 | 15.85mg/g | [ |
吸附剂 | 温度/K | Cu2+ | TC | ||||||
---|---|---|---|---|---|---|---|---|---|
lnKd | ΔG/kJ∙mol-1 | ΔH/kJ∙mol-1 | ΔS/J∙mol-1∙K-1 | lnKd | ΔG/kJ∙mol-1 | ΔH/kJ∙mol-1 | ΔS/J∙mol-1∙K-1 | ||
BE500 | 288 | 2.215 | -5.307 | 0.665 | 0.030 | 2.023 | -4.846 | 2.494 | 0.034 |
298 | 3.329 | -8.251 | 2.449 | -6.070 | |||||
308 | 4.903 | -12.561 | 2.712 | -6.949 | |||||
BE700 | 288 | 5.793 | -13.878 | 0.083 | 0.027 | 1.324 | -3.173 | 1.663 | 0.032 |
298 | 8.178 | -20.273 | 2.034 | -5.043 | |||||
308 | 5.208 | -13.342 | 1.903 | -4.874 |
吸附剂 | 温度/K | Cu2+ | TC | ||||||
---|---|---|---|---|---|---|---|---|---|
lnKd | ΔG/kJ∙mol-1 | ΔH/kJ∙mol-1 | ΔS/J∙mol-1∙K-1 | lnKd | ΔG/kJ∙mol-1 | ΔH/kJ∙mol-1 | ΔS/J∙mol-1∙K-1 | ||
BE500 | 288 | 2.215 | -5.307 | 0.665 | 0.030 | 2.023 | -4.846 | 2.494 | 0.034 |
298 | 3.329 | -8.251 | 2.449 | -6.070 | |||||
308 | 4.903 | -12.561 | 2.712 | -6.949 | |||||
BE700 | 288 | 5.793 | -13.878 | 0.083 | 0.027 | 1.324 | -3.173 | 1.663 | 0.032 |
298 | 8.178 | -20.273 | 2.034 | -5.043 | |||||
308 | 5.208 | -13.342 | 1.903 | -4.874 |
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