Research progress of main catalyst in biomass pyrolysis and utilization

doi:10.16085/j.issn.1000-6613.2021-0245

Abstract

Abstract:

At present, catalytic pyrolysis has gradually become the main research direction of biomass conversion and utilization technology. Compared with conventional pyrolysis, catalytic pyrolysis could effectively improve the quality of bio-oil and produce high-value products. This paper reviews the new catalyst in recent years, including molecular sieve catalyst (ZSM-5, HZSM-5, USY, etc.), carbon-based catalysts, metal oxides, dolomite, monolithic catalysts, etc., and understands the latest research progress in the field of catalystfor biomass pyrolysis. The good catalyst is the key to ensure the smooth progress of the reaction, and the high-value products produced by different catalyst are also different, so the correct selection of catalyst plays an important role in the quality improvement of bio-oil. According to the current research content in the field, this paper also makes a detailed comparison of the advantages and disadvantages and product characteristics of all kinds of catalyst, and puts forward some suggestions and prospects for the existing problems of this technology. It provides an important theoretical basis for the future research of catalyst in the field of biomass pyrolysis.

Key words: biomass, catalytic pyrolysis, catalyst, bio-oil

摘要：

催化热解目前逐渐成为生物质转化利用技术的主要研究方向，相比常规热解，催化热解可以对生物油进行有效提质并且定向产生高值化产品。本文通过对近年来新兴的催化剂进行综述，包括分子筛类催化剂（ZSM-5、HZSM-5、USY等）、炭基催化剂、金属氧化物、白云石、整体式催化剂等，了解了目前生物质热解利用中催化剂领域内的最新研究进展。文中指出，良好的催化剂是保证反应顺利进行的关键，不同催化剂定向产生的高值化产品也有所不同，因此催化剂的正确选择对于生物油的提质起着重大作用。根据目前领域内所研究内容，本文还对各类催化剂的优缺点、产物特性进行了详细比较，并针对该技术现有问题提出了部分建议并进行展望，为以后生物质热解领域催化剂的研究提供了重要的理论依据。

关键词: 生物质, 催化热解, 催化剂, 生物油

CLC Number:

FANG Shuqi, WANG Yuqian, LI Pan, SONG Jiande, BAI Jing, CHANG Chun. Research progress of main catalyst in biomass pyrolysis and utilization[J]. Chemical Industry and Engineering Progress, 2021, 40(9): 5195-5203.

方书起, 王毓谦, 李攀, 宋建德, 白净, 常春. 生物质热解利用中主要催化剂的研究进展[J]. 化工进展, 2021, 40(9): 5195-5203.

Figures/Tables 1

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