Chemical Industry and Engineering Progress ›› 2019, Vol. 38 ›› Issue (02): 842-850.DOI: 10.16085/j.issn.1000-6613.2018-1321
• Energy processes and technology • Previous Articles Next Articles
Baomin SUN(),Manda GAO(),Shixing DING,Yifeng SU
Received:
2018-06-26
Revised:
2018-09-07
Online:
2019-02-05
Published:
2019-02-05
Contact:
Manda GAO
通讯作者:
高满达
作者简介:
<named-content content-type="corresp-name">孙保民</named-content>(1959—),男,博士生导师,研究方向为电站热力过程。E-mail:<email>965822001@qq.com</email>。|高满达,博士,研究方向为燃煤数值模拟及煤灰熔融性。E-mail:<email>gmdreneng@163.com</email>。
基金资助:
CLC Number:
Baomin SUN, Manda GAO, Shixing DING, Yifeng SU. Effect of sodium in synthetic coal on coal combustion performance and ash characteristics[J]. Chemical Industry and Engineering Progress, 2019, 38(02): 842-850.
孙保民, 高满达, 丁世兴, 苏逸峰. 合成煤中钠对煤燃烧及灰特性影响[J]. 化工进展, 2019, 38(02): 842-850.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2018-1321
工业分析w/% | 元素分析w/% | |||||||
---|---|---|---|---|---|---|---|---|
Mad | Aad | FCad | Vad | Cdaf | Hdaf | Ndaf | Odaf | Sdaf |
9.57 | 8.74 | 54.43 | 27.26 | 61.18 | 3.94 | 0.59 | 15.37 | 0.61 |
工业分析w/% | 元素分析w/% | |||||||
---|---|---|---|---|---|---|---|---|
Mad | Aad | FCad | Vad | Cdaf | Hdaf | Ndaf | Odaf | Sdaf |
9.57 | 8.74 | 54.43 | 27.26 | 61.18 | 3.94 | 0.59 | 15.37 | 0.61 |
SiO2 | Al2O3 | Fe2O3 | CaO | MgO | TiO2 | SO3 | P2O5 | K2O | Na2O | 总计 |
---|---|---|---|---|---|---|---|---|---|---|
33.51 | 13.66 | 4.64 | 20.21 | 5.48 | 0.62 | 12.82 | 0.17 | 0.67 | 4.04 | 95.82 |
SiO2 | Al2O3 | Fe2O3 | CaO | MgO | TiO2 | SO3 | P2O5 | K2O | Na2O | 总计 |
---|---|---|---|---|---|---|---|---|---|---|
33.51 | 13.66 | 4.64 | 20.21 | 5.48 | 0.62 | 12.82 | 0.17 | 0.67 | 4.04 | 95.82 |
合成煤 | 质量分数/% | ||||||
---|---|---|---|---|---|---|---|
超纯煤 | SiO2 | Al2O3 | Fe2O3 | CaO | MgO | Na2O | |
1 | 70 | 12.63 | 5.37 | 1.89 | 7.89 | 2.21 | 0(0%) |
2 | 70 | 12.57 | 5.34 | 1.88 | 7.85 | 2.20 | 0.15(0.5%) |
3 | 70 | 12.50 | 5.31 | 1.87 | 7.81 | 2.19 | 0.30(1%) |
4 | 70 | 12.37 | 5.26 | 1.86 | 7.73 | 2.16 | 0.60(2%) |
5 | 70 | 12.00 | 5.10 | 1.80 | 7.50 | 2.10 | 1.50(5%) |
6 | 70 | 11.65 | 4.95 | 1.75 | 7.28 | 2.04 | 2.40(8%) |
合成煤 | 质量分数/% | ||||||
---|---|---|---|---|---|---|---|
超纯煤 | SiO2 | Al2O3 | Fe2O3 | CaO | MgO | Na2O | |
1 | 70 | 12.63 | 5.37 | 1.89 | 7.89 | 2.21 | 0(0%) |
2 | 70 | 12.57 | 5.34 | 1.88 | 7.85 | 2.20 | 0.15(0.5%) |
3 | 70 | 12.50 | 5.31 | 1.87 | 7.81 | 2.19 | 0.30(1%) |
4 | 70 | 12.37 | 5.26 | 1.86 | 7.73 | 2.16 | 0.60(2%) |
5 | 70 | 12.00 | 5.10 | 1.80 | 7.50 | 2.10 | 1.50(5%) |
6 | 70 | 11.65 | 4.95 | 1.75 | 7.28 | 2.04 | 2.40(8%) |
合成煤 | 最大燃烧速率 /%·min-1 | 平均燃烧速率 /%·min-1 | 综合燃烧指数 ×10-7 /%2·min-2·K-3 | 点燃温度 燃尽率/% | 燃尽指数 /10-4·min-1 |
---|---|---|---|---|---|
1 | 14.25 | 5.62 | 2.77 | 14.88 | 36.49 |
2 | 13.48 | 5.67 | 2.59 | 14.88 | 36.16 |
3 | 11.98 | 6.98 | 2.45 | 25.85 | 54.62 |
4 | 13.88 | 6.16 | 2.56 | 19.25 | 45.62 |
5 | 15.20 | 6.20 | 2.66 | 24.01 | 54.45 |
6 | 13.31 | 9.59 | 3.12 | 25.47 | 55.13 |
合成煤 | 最大燃烧速率 /%·min-1 | 平均燃烧速率 /%·min-1 | 综合燃烧指数 ×10-7 /%2·min-2·K-3 | 点燃温度 燃尽率/% | 燃尽指数 /10-4·min-1 |
---|---|---|---|---|---|
1 | 14.25 | 5.62 | 2.77 | 14.88 | 36.49 |
2 | 13.48 | 5.67 | 2.59 | 14.88 | 36.16 |
3 | 11.98 | 6.98 | 2.45 | 25.85 | 54.62 |
4 | 13.88 | 6.16 | 2.56 | 19.25 | 45.62 |
5 | 15.20 | 6.20 | 2.66 | 24.01 | 54.45 |
6 | 13.31 | 9.59 | 3.12 | 25.47 | 55.13 |
1 | LIUX Q, WANGC A, DUY B, et al. Effect of operation conditions on activity of de-NOx SCR catalysts before and after poisoned by alkali metal[J]. Advanced Materials Research, 2014, 955/956/957/958/959:702-705. |
2 | 陈川, 张守玉, 刘大海, 等. 新疆高钠煤中钠的赋存形态及其对燃烧过程的影响[J]. 燃料化学学报, 2013, 41(7): 832-838. |
CHENC, ZHANGS Y, LIUD H, et al. Existence form of sodium in high sodium coals from Xinjiang and its effect on combustion process[J]. Journal of Fuel Chemistry and Technology, 2013, 41(7): 832-838. | |
3 | 陈新蔚, 庄新国, 周继兵, 等. 准东煤田煤质特征及分布规律[J]. 新疆地质, 2013(1): 89-93. |
CHENX W, ZHUANGX G, ZHOUJ B, et al. Coal quality features and distribution of Zhundong coalfield[J]. Xinjiang Geology, 2013(1): 89-93. | |
4 | 陶玉洁. 高碱金属准东煤燃烧特性及灰渣行为的基础研究[D]. 杭州:浙江大学, 2015. |
TAOY J. Basic research on combustion characteristics and ash behaviors of high-alkali Zhundong coal[D]. Hangzhou:Zhejiang University, 2015. | |
5 | SONGG L, QIX B, SONGW J, et al. Slagging behaviors of high alkali Zhundong coal during circulating fluidized bed gasification[J]. Fuel, 2016, 186:140-149. |
6 | 白向飞, 王越, 丁华, 等. 准东煤中钠的赋存状态[J]. 煤炭学报, 2015, 40(12): 2909-2915. |
BAIX F, WANGY, DINGH, et al. Modes of occurrence of sodium in Zhundong coal[J]. Journal of China Coal Society, 2015, 40(12): 2909-2915. | |
7 | QIX B, SONGG L, SONGW J, et al. Combustion performance and slagging characteristics during co-combustion of Zhundong coal and sludge[J]. Journal of the Energy Institute, 2018, 91(3): 397-410. |
8 | 高姗姗, 金晶, 刘敦禹, 等. 蛭石复合添加剂对准东煤灰特性影响[J]. 化工进展, 2017, 36(9): 3280-3286. |
GAOS S, JINJ, LIUD Y, et al. Effect of vermiculite composite additives on the anti-slagging behavior during combustion of Zhundong coal[J]. Chemical Industry and Engineering Progress, 2017, 36(9): 3280-3286. | |
9 | CHENX D, KONGL X, JINB, et al. Effect of Na2O on mineral transformation of coal ash under high temperature gasification condition[J]. Journal of Fuel Chemistry & Technology, 2016, 44(3): 263-272. |
10 | NIUY Q, WANGZ Z, ZHUY M, et al. Experimental evaluation of additives and K2O–SiO2–Al2O3 diagrams on high-temperature silicate melt-induced slagging during biomass combustion[J]. Fuel, 2016, 179:52-59. |
11 | SONGW J, SONGG L, QIX B, et al. Speciation and distribution of sodium during Zhundong coal gasification in a circulating fluidized bed[J]. Energy & Fuels, 2017, 31(2): 1889-1895. |
12 | NANOUP, MURILLOH E G, SWAAIJW P M V, et al. Intrinsic reactivity of biomass-derived char under steam gasification conditions-potential of wood ash as catalyst[J]. Chemical Engineering Journal, 2013, 217(2): 289-299. |
13 | 翁青松, 王长安, 车得福, 等. 准东煤碱金属赋存形态及对燃烧特性的影响[J]. 燃烧科学与技术, 2014, 20(3): 216-221. |
WENGQ S, WANGC A, CHED F, et al. Alkali metal occurrence mode and its influence on combustion characteristics in Zhundong coals[J]. Journal of Combustion Science and Technology, 2014, 20(3): 216-221. | |
14 | 刘辉, 许连飞, 朱书骏, 等. 水溶钠对准东煤快速热解煤焦燃烧特性的影响[J]. 煤炭学报, 2016, 41(5): 1259-1265. |
LIUH, XUL F, ZHUS J, et al. Effect of water-soluble sodium on combustion characteristics of Zhundong rapidly pyrolyzed coal char[J]. Journal of China Coal Society, 2016, 41(5): 1259-1265. | |
15 | ZHANGH X, GUOX W, ZHUZ P. Effect of temperature on gasification performance and sodium transformation of Zhundong coal[J]. Fuel, 2017, 189:301-311. |
16 | 肖劲, 王炳杰, 李发闯, 等. 酸碱法制备超纯煤[J]. 煤炭技术, 2016, 35(1): 290-292. |
XIAOJ, WANGB J, LIF C, et al. Preparation of ultra-clean coal by acid-alkali method[J]. Coal Technology, 2016, 35(1): 290-292. | |
17 | 曾凡. 常规酸碱化学脱灰法: 超纯煤的选制工艺专题之三[J]. 煤炭加工与综合利用, 1995(1): 32-36. |
ZENGF. Conventional acid-alkali chemical deliming method: the third of the selection process of ultra-pure coal[J]. Coal Processing and Comprehensive Utilization, 1995(1): 32-36. | |
18 | WANGC P, WANGF Y, YANGQ R, et al. Thermogravimetric studies of the behavior of wheat straw with added coal during combustion[J]. Biomass and Bioenergy, 2009, 33(1): 50-56. |
19 | 聂其红, 孙绍增, 李争起, 等. 褐煤混煤燃烧特性的热重分析法研究[J]. 燃烧科学与技术, 2001, 7(1): 72-76. |
NIEQ H, SUNS Z, LIZ Q, et al. Thermogravimetric analysis on the combustion characteristics of brown coal blends[J]. Journal of Combustion Science and Technology, 2001, 7(1): 72-76. | |
20 | 鄢晓忠, 邱靖, 尹艳山, 等. 褐煤中官能团对其燃烧特性的影响[J]. 煤炭科学技术, 2016, 44(4): 169-174. |
YANX Z, QIUJ, YINY S, et al. Effects of functional groups in lignite on its combustion characteristics[J]. Coal Science and Technology, 2016, 44(4): 169-174. | |
21 | 刘建忠, 刘明强, 赵卫东, 等. 褐煤半焦燃烧特性的热重试验研究[J]. 热力发电, 2013, 42(11): 86-92. |
LIUJ Z, LIUM Q, ZHAOW D, et al. Thermogravimetric study on combustion characteristics of lignite semicoke[J]. Thermal Power Generation, 2013, 42(11): 86-92. | |
22 | 侯康, 武建军, 尚晓玲, 等. 热重法研究逐级脱矿对褐煤燃烧特性的影响[J]. 化工进展, 2017, 36(3): 900-908. |
HOUK, WUJ J, SHANGX L, et al. Experimental study on effects of stepwise removal of minerals on the combustion characteristics of lignites by TG/DTG[J]. Chemical Industry and Engineering Progress, 2017, 36(3): 900-908. | |
23 | 张洪, 蒲文秀, 哈斯, 等. 化学脱灰对低灰煤粉性质的影响[J]. 工程热物理学报, 2009, 30(4): 699-702. |
ZHANGH, PUW X, HA S, et al. Influence of acid treatment on the properties of pulverized coals with low ash content[J]. Journal of Engineering Thermophysics, 2009, 30(4): 699-702. | |
24 | 肖劲, 李发闯, 邓松云, 等. 酸碱脱灰对煤结构及其热解特性的影响[J]. 中南大学学报(自然科学版), 2016, 47(1): 14-19. |
XIAOJ, LIF C, DENGS Y, et al. Influence of demineralization on structure and pyrolysis characteristics of coal with acid-alkali method[J]. Journal of Central South University(Science and Technology), 2016, 47(1): 14-19. | |
25 | CHENGJ, ZHOUF, XUANX X, et al. Comparison of the catalytic effects of eight industrial wastes rich in Na, Fe, Ca and Al on anthracite coal combustion[J]. Fuel, 2017, 187:398-402. |
26 | 刘永新, 张波波, 王福先, 等. 碱金属对焦炭热性能的影响[J]. 煤炭转化, 2008, 31(3): 43-47. |
LIUY X, ZHANGB B, WANGF X, et al. Effect of alkali metal on the thermal properties of coke[J]. Coal Conversion, 2008, 31(3): 43-47. | |
27 | 蔡雪贞, 孙章, 王杰平, 等. 焦炭气化反应性对抚顺气煤容惰能力的评价[J]. 化工进展, 2018, 37(3): 976-983. |
CAIX Z, SHUNZ, WANGJ P, et al. Study on the inert-tolerant capacity of Fushun gas coal by the characteristics of coke-CO2 gasification[J]. Chemical Industry and Engineering Progress, 2018, 37(3): 976-983. | |
28 | 孙学信. 燃煤锅炉燃烧试验技术与方法[M]. 北京:中国电力出版社, 2002:51-88. |
SUNX X. Coal-fired boiler combustion test technology and method[M]. Beijing:China Electric Power Press, 2002:51-88. | |
29 | LIF H, MA X W, XUM L, et al. Regulation of ash-fusion behaviors for high ash-fusion-temperature coal by coal blending[J]. Fuel Processing Technology, 2017, 166:131-139. |
30 | 管嵘清, 杜梅芳, 李洁, 等. 煤灰中霞石与钠长石的光学性质对熔融特性影响[J]. 上海理工大学学报, 2010, 32(6): 597-601. |
GUANR Q, DUM F, LIJ, et al. Impact of optical properties of nepheline and albite on fusion characteristics in coal ash[J]. Journal of University of Shanghai for Science and Technology, 2010, 32(6): 597-601. | |
31 | 朱秀英, 孙钦英. 探寻开发新型耐火材料的途径[J]. 耐火材料, 2000, 34(4): 230-235. |
ZHUX Y, SUNQ Y. Explore ways to develop new refractories[J]. Refractories, 2000, 34(4): 230-235. | |
32 | WUX J, ZHANGZ Z, CHENY S, et al. Main mineral melting behavior and mineral reaction mechanism at molecular level of blended coal ash under gasification condition[J]. Fuel Processing Technology, 2010, 91(11): 1591-1600. |
33 | SONGW J, TANGL H, ZHUX D, et al. Prediction of Chinese coal ash fusion temperatures in Ar and H2 atmospheres[J]. Energy & Fuels, 2009, 23(4): 1990-1997. |
34 | BAIJ, LIW, LIB Q. Characterization of low-temperature coal ash behaviors at high temperatures under reducing atmosphere[J]. Fuel, 2008, 87(4/5): 583-591. |
35 | 王平泽, 郝临山. 粒化碱性高炉矿渣中原始矿物相的形成研究[J]. 山西大同大学学报 (自然科学版), 2008, 24(5): 44-47. |
WANGP Z, HAOL S. Study on formation of original mineral phase in granulated alkali blast ash[J]. Journal of Shanxi Datong University (Natural Science), 2008, 24(5): 44-47. | |
36 | 王桂英, 俞海淼, 陈德珍. 炉排式垃圾焚烧炉灰渣成分及熔融特性分析[J]. 热力发电, 2009, 38(1): 35-38. |
WANGG Y, YUH M, CHEND Z. Analysis of ash composition and fusing behavior for ash resulted from grate-type msw incinerator[J]. Thermal Power Generation, 2009, 38(1): 35-38. | |
37 | 代廷魁. 改善高铝煤灰熔融特性及助熔机理研究[D]. 淮南:安徽理工大学, 2016. |
DAIT K. Study on improving ash fusibility and fluxing mechanism of high alumina coal[D]. Huainan:Anhui University of Science and Technology, 2016. | |
38 | 杨建国, 邓芙蓉, 赵虹, 等. 煤灰熔融过程中的矿物演变及其对灰熔点的影响[J]. 中国电机工程学报, 2006, 26(17): 122-126. |
YANGJ G, DENGF R, ZHAOH, et al. Mineral conversion of coal-ash in fusing process and the influence to ash fusion point[J]. Proceeding of the CSEE, 2006, 26(17): 122-126. | |
39 | HASEGAWAM, KASHIWAYAY, IWASEM. Thermodynamic properties of solid solutions between di-calcium silicate and tri-calcium phosphate[J]. High Temperature Materials & Processes, 2012, 31(4/5): 421-430. |
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