Review of research on the effect of salt storage deicing material on the preformance of asphalt mixture

doi:10.16085/j.issn.1000-6613.2017-1373

Abstract

Abstract: The research about the influence of deicing materials on the performance of asphalt mixture was introduced. The main deicing materials, mechanism of deicing or snow melting, evaluation method and application effect were also summarized and analyzed. The influences of the material on the anti-freezing function and the performance of asphalt mixture were discussed. The results showed that when compared with original asphalt mixture, the snow melting performance of salt storage asphalt mixture had been significantly improved, because the freezing points of water solution and interfacial adhesion between ice layer and pavement is reduced. This is quantitatively assessed by pull out test or interlaminar shear strength test. The pavement performance especially water stability of asphalt mixture decreased obviously after Mafilon was added. When Verglimit-260 was added into the asphalt mixture, the water stability and low temperature performance were both reduced. The particle size, displacement method, dosage of Icebane material and mineral aggregate gradation all have significant influence on the performance of asphalt mixture. Compared with salt storage asphalt mixture, the pavement performance of above mixture could be improved by using high viscosity modified asphalt or additives.

Key words: road engineering, asphalt mixture, deicing material, salt, pavement performance, composites

摘要： 为提高冰雪气候条件下沥青路面的运营安全水平，系统介绍了国内外储盐类融雪抑冰材料对沥青混合料性能研究的现状，总结分析了融雪抑冰的主要材料类型、作用机理、评价方法及应用效果等，并探讨了材料对沥青混合料融雪抑冰功能和路用性能的影响。分析表明：储盐类沥青混合料中融雪关键成分氯化物的析出降低了路表水溶液的冰点、路面与冰雪之间的黏附力，显著提高了自身融雪除冰功能；但导致混合料路用性能发生了一定的变化。MFL（Mafilon）材料的掺加，使混合料的各项路用性能均降低，尤其是水稳性能。V-260（Verglimit-260）材料以外掺的方式添加到混合料中，其水稳性能和低温性能均降低。而ICB（icebane）材料的粒径、置换方式、掺量及所用矿料级配等因素均对混合料路用性能有影响。采用高黏改性沥青或掺加添加剂，可有效改善融雪抑冰沥青混合料的路用性能。

关键词: 道路工程, 沥青混合料, 融雪抑冰材料, 盐化物, 路用性能, 复合材料

CLC Number:

U416
TB302

ZHANG Zhengqi, LUO Yaofei, ZHAO Fuqiang. Review of research on the effect of salt storage deicing material on the preformance of asphalt mixture[J]. Chemical Industry and Engineering Progress, 2018, 37(06): 2282-2294.

张争奇, 罗要飞, 赵富强. 储盐类融雪抑冰材料对沥青混合料性能影响研究进展[J]. 化工进展, 2018, 37(06): 2282-2294.

References

[1] 刘状壮. 沥青路面融雪抑冰材料的研发与应用[D]. 西安:长安大学, 2013. LIU Zhuangzhuang. Anti-freezing materials used in asphalt pavement and its application properties[D]. Xi'an:Chang'an University, 2012.
[2] AUGERI F. Placement of experimental bituminous concrete mixture utilizing an asphalt additive(verglimit)[R].Washington D C:Federal Highway Administration, 1987.
[3] LOHREY E C. Field evaluation of an experimental bituminous pavemene utilizing an ice-retardant additive-Verglimit[R]. Connecticut:Connecticut Department of Transportation Division of Research,1992.
[4] 荒木美民,竹田巌,鈴木秀輔. 粉粉体·塩化物系凍結抑制舗装の追跡調査:欧州および我が国における調査事例から[J]. 舗装, 1997, 32(9):8-14. ARAKI Y, TAKEDA I, SUZUKI S. Follow-up survey on powder/chloride freeze control pavement:survey cases of Europe and Japan[J]. Pavement, 1997, 32(9):8-14.
[5] WRIGHT Michael. A study of the effects of adding ice retardant additives to pavement surface course materials[D]. Nottingham:University of Nottingham, 2013.
[6] 白艳君. 盐化物融雪沥青混合料性能评价[D]. 西安:长安大学, 2012. BAI Yanjun. Evaluate on the performance of snow melt salt asphalt mixture[D]. Xi'an:Chang'an University, 2012.
[7] 康捷. 抗凝冰沥青混合料技术研究[D]. 重庆:重庆交通大学, 2011. KANG Jie. The research on anticoagulant mixture of ice[D]. Chongqing:Chognqing Jiaotong University, 2011.
[8] 李悦,李铁山,徐玉峰,等. 多功能自融雪沥青路面的研究与应用[J].中外公路, 2012, 32(6):85-89. LI Yue, LI Tieshan, XU Yufeng, et al. Research and application of multifunction asphalt pavement with with snow melt salt[J]. Journal of China & Foreign Highway, 2012, 32(6):85-89.
[9] 孙嵘蓉. 缓释蓄盐沥青混合料的研发及性能的评价[D]. 哈尔滨:哈尔滨工业大学, 2012. SUN Zhengrong. Develop and performance evaluate of sustained-release mixture include salt[D]. Harbin:Harbin Institute of Technology, 2012.
[10] 付靖宜,彭超,赵之杰,等. 雨水对蓄盐沥青路面自融冰性能影响研究[J]. 武汉理工大学学报, 2015, 37(2):50-54, 62. FU Jingyi, PENG Chao, ZHAO Zhijie, et al. Effect of rain on selt-deicing performance of asphalt pavement containing deicing additive[J]. Journal of Wuhan University of Technology, 2015, 37(2):50-54, 62.
[11] 邵明玉. 除冰雪蓄盐沥青混合料的制备与性能研究[D]. 西安:长安大学, 2015. SHAO Mingyu. Study on performance and preparation of deicing snowmelt by salt storage asphalt mixture[D]. Xi'an:Chang'an University, 2015.
[12] 黄玮,杨贺群,丛玉凤,等. 沥青路面用融雪抑冰材料性能的研究[J]. 应用化工, 2016, 45(7):1215-1219. HUANG Wei, YANG Hequn, CONG Yufeng, et al. Research on the performance of the de-ice materials used in asphalt pavement[J]. Applied Chemical Industry, 2016, 45(7):1215-1219.
[13] 高伏良,胡柏学,黄浩,等. 基于外掺防冻材料的桥面防冰性能试验研究[J]. 公路工程, 2015, 40(1):229-273. GAO Fuliang, HU Boxue, HUANG Hao, et al. Research of bridge deck anti-icing performance test base on mixed antifreeze materials[J]. Highway Engineering, 2015, 40(1):229-273.
[14] 张忠,刘红莹,李云霞,等. 盐化物融雪剂在高速公路建设中的应用研究[J].公路工程, 2012, 37(6):204-207. ZHANG Zhong, LIU Hongying, LI Yunxia, et al. Applied research of snow-melting agent of substance in expressway construction[J]. Highway Engineering, 2012, 37(6):204-207.
[15] 李福普, 王志军. 长效型主动融雪沥青混合料路用性能试验[J]. 公路交通科技, 2012, 29(3):7-11. LI Fupu, WANG Zhijun. Experiment of road performance of asphalt mixture with automatic long-term snowmelt agent[J]. Journal of Highway and Transportation Research and Development, 2012, 29(3):7-11.
[16] HIDEHIKO Ninomiya, KIYOSHI Takeichi, KAZUYUKI Kawamura. Performance evaluation of pavement with deicing materials[J]. Transportation Research Record, 1993, 1387:151-155.
[17] ANBURAJ Muthumani, LAURA Fay, MICHELLE Akin, et al. Correlating lab and field tests for evaluation of deicing and anti-icing chemicals:a review of potential approaches[J]. Cold Regions Science and Technology, 2014, 97:21-32.
[18] KIYOSHI Takeichi, IWAO Sato, FUMIHIRO Hara, et al. Performance of various antifreezing pavement by field test[J]. Transportation Research Record, 2001, 1741:114-123.
[19] PENG Chao, YU Jianying, ZHAO Zhijie, et al. Preparation and properties of a layered double hydroxide deicing additive for asphalt mixture[J]. Cold Regions Science and Technology, 2015, 110:70-76.
[20] LUO Sang, YANG Xu. Performance evaluation of high-elastic asphalt mixture containing deicing agent Mafilon[J]. Construction and Building Materials, 2015, 94:494-501.
[21] 谭忆秋,孙嵘蓉,郭猛,等. 蓄盐沥青混合料除冰雪性能研究[J]. 中国公路学报, 2013, 26(1):23-29. TAN Yiqiu, SUN Zhengrong, GUO Meng, et al. Research on deicing performance of asphalt mixture containing salt[J]. China Journal of Highway and Transport, 2013, 26(1):23-29.
[22] 薛忠军,王春明,张荣荣,等. 防冰沥青混合料路用性能试验研究[J]. 公路交通科技, 2014, 31(1):1-6, 12. XUE Zhongjun, WANG Chunming, ZHANG Rongrong, et al. Experimental study on pavement performances of anti-icing asphalt mixture[J]. Journal of Highway and Transportation Research and Development, 2014, 31(1):1-6, 12.
[23] 俞文生,张晓春,钟科. 高弹蓄盐融冰雪沥青混合料除冰特性[J]. 中国矿业大学学报, 2015, 44(5):912-916. YU Wensheng, ZHANG Xiaochun, ZHONG Ke. Deicing performance of asphalt mixture with snowmelt agent and high-elastic modified asphalt binder[J]. Journal of China University of Mining & Technology, 2015, 44(5):912-916.
[24] MA Tao, GENG Lei, DING Xunhao, et al. Experimental study of deicing asphalt mixture with anti-icing additives[J]. Construction and Building Materials, 2016, 127:653-662.
[25] 王春明,薛忠军,谢超,等. 三种融雪防冰材料路用性能评价分析[J]. 公路, 2016(9):267-272. WANG Chunming, XUE Zhongjun, XIE Chao, et al. Evaluation and analysis of asphalt mixture pavement performance with three antifreeze material[J]. Highway, 2016(9):267-272.
[26] 夏慧芸,李芳芳,宋莉芳,等. 自融雪材料制备及其融雪效果评价[J]. 公路, 2015(7):269-274. XIA Huiyun, LI Fangfang, SONG Lifang, et al. Preparation and performance evaluation of auto-snowmelt material[J]. Highway, 2015(7):269-274.
[27] BERNARD Baum, ROY White, LYNNE Thoma. Ice-pavement bond prevention:surface modifiction[R]. Washington D C:National Research Council, 1992.
[28] 张忠,刘红莹,李云霞,等. 盐化物融雪剂在高速公路建设中的应用研究[J]. 公路工程, 2012, 37(6):204-207. ZHANG Zhong, LIU Hongying, LI Yunxia, et al. Applied research of snow-melting agent of substance in expressway construction[J]. Highway Engineering, 2012, 37(6):204-207.
[29] XU Ouming,HAN Sen,ZHANG Caili,et al. Laboratory investigation of andesite and limestone asphalt mixtures containing sodium chloride-based anti-icing filler[J]. Construction and Building Materials, 2015, 98:671-677.
[30] 于洋. 缓释自融雪沥青混合料性能研究[D]. 大连:大连海事大学, 2015. YU Yang. Research on asphalt mixure with confrolled-release snowmelt salt[D]. Dalian:Dalian Maritime University, 2015.
[31] 何湘宁. 聚脂纤维对MFL融冰化雪沥青混合料的性能影响研究[J]. 公路工程, 2014, 39(4):282-285. HE Xiangning. Study on performance impact for polyester fibers into melting ice and snow MFL-asphalt mixture[J]. Highway Engineering, 2014, 39(4):282-285.
[32] 周健. 缓释型融冰雪沥青路面技术研究[D]. 南京:东南大学, 2013. ZHOU Jian. Research on the sustained-release snow melting technique of asphalt pavement[D]. Nanjing:Southeast University, 2013.
[33] 孙玉齐. 盐化物自融雪沥青路面性能研究[D]. 西安:长安大学, 2011. SUN Yuqi. Study on the performance of asphalt pavement with snow melt salt[D]. Xi'an:Chang'an University, 2011.
[34] 孙健,钱振东,罗桑. 融冰化雪型沥青混合料路用性能的试验评价[J]. 公路, 2013(12):204-207. SUN Jian, QIAN Zhendong, LUO Sang. Test and evaluation of road performance of ice-melting asphalt mixture[J]. Highway, 2013(12):204-207.
[35] 凡涛涛. 盐化物抗冰冻沥青混合料路用性能应用研究[D]. 杭州:浙江理工大学, 2015. FAN Taotao. Application study on the road performance of salt anti-freezing asphalt mixture[D]. Hangzhou:Zhejiang Sci-Tech University, 2015.
[36] 张丽娟. 盐化物融雪沥青混合料研究[D]. 西安:长安大学, 2010.ZHANG Lijuan. The study of salt antifreezing asphalt mixtures[D]. Xi'an:Chang'an University, 2010.
[37] 王锋, 韩森, 张洪伟, 等. 盐化物融冰雪沥青混合料的应用研究[J]. 公路, 2009(3):176-179. WANG Feng, HAN Sen, ZHANG Hongwei, et al. A study on application of salt antifreezing asphalt mixture[J]. Highway, 2009(3):176-179.
[38] 刘状壮,高杰,张正伟,等. 融雪抑冰沥青混合料路用性能及盐分溶析特性[J]. 公路, 2016(8):199-204. LIU Zhuangzhuang, GAO Jie, ZHANG Zhenwei, et al. Analysis of road performance and salt releasing characteristics of anti-freeze asphalt concrete[J]. Highway, 2016(8):199-204.
[39] 豆怀兵. 超薄罩面盐化物自融雪沥青混合料组成与性能研究[D]. 西安:长安大学, 2015. DOU Huaibing. Design and pavement performance of ultra-thin snow melt salt asphalt mixture pavement overlay[D]. Xi'an:Chang'an University, 2015.
[40] LIU Zhuangzhuang, XING Mingliang, CHEN Shuanfa, et al. Influence of the chloride-based anti-freeze filler on the properties of asphalt mixtures[J]. Construction and Building Materials, 2014, 51:133-140.
[41] LIU Zhuangzhuang, SHA Aimin, HE Rui, et al. Antifreeze asphalt mixtures design and antifreeze performances prediction based on the phase equilibrium of natural solution[J]. Cold Regions Science and Technology, 2016, 129:104-113.
[42] 张浩军,王修山,吴大志,等. 掺V-260主动抑冰沥青混合料路用性能试验研究[J]. 公路, 2015(8):26-29. ZHANG Haojun, WANG Xiushan, WU Dazhi, et al. Test and study of road performance of V-260 automatic anti-freezing asphalt mixture[J]. Highway, 2015(8):26-29.
[43] ZHENG Mulian, ZHOU Juanlan, WU Shujuan, et al. Evaluation of long-term performance of anti-icing asphalt pavement[J]. Construction and Building Materials, 2015, 84:277-283.
[44] 崔龙锡. 蓄盐类沥青混合料研究[D]. 重庆:重庆交通大学, 2010. CUI Longxi. The research on asphalt mixture include salt[D]. Chongqing:Chognqing Jiaotong University, 2010.
[45] STUART K D, MOGAWER W S. Laboratory evaluation of Verglimit and Plusride[J]. Public Roads, 1991, 55(3):79-86.
[46] JOHN Kiljan. Verglimit evaluation(Boulder)[R]. Colorado:Colorado Department of Highways, 1989.
[47] 王文峰,吴冬生,吴春颖,等. 缓释型抗冰冻SMA混合料的优化设计及路用性能研究[J]. 新型建筑材料, 2016(7):42-45. WANG Wenfeng, WU Dongsheng, WU Chunying, et al. Research on road performance and optimal design of sustained-release anti-freeze SMA[J]. New Building Materials, 2016(7):42-45.
[48] 彭磊. 自融雪沥青路面外加剂制备与运用研究[D]. 西安:长安大学, 2013. PENG Lei. Preparation and utilize of snowmelt admixture for asphalt pavement[D]. Xi'an:Chang'an University, 2013.
[49] 陈拴发,刘状壮,邢明亮,等. 融雪抑冰材料疏水性能影响因素研究[J]. 建筑材料学报, 2013, 16(6):1053-1057, 1071. CHEN Shuanfa, LIU Zhuangzhuang, XING Mingliang, et al. Research on the factors influence hydrophobic properties of anti-freezing material[J]. Journal of Building Materials, 2013, 16(6):1053-1057, 1071.
[50] LIU Zhuangzhuang, SHA Aimin, XING Mingliang, et al. Low temperature property and salt releasing characteristics of antifreeze asphalt concrete under static and dynamic conditions[J]. Cold Regions Science and Technology, 2015, 114:9-14.
[51] 吴淑娟. 盐化物沥青混合料融冰雪性能及适应性气候分区研究[D]. 西安:长安大学, 2012. WU Shujuan. The study of salt antifreezing asphalt mixture[D]. Xi'an:Chang'an University, 2012.
[52] 徐鸥明, 韩森. 盐分对储盐沥青混合料性能的影响[J]. 长安大学学报(自然科学版), 2015, 35(4):8-12. XU Ouming, HAN Sen. Effect of salt on the performance of salt storage asphalt mixture[J]. Journal of Chang'an University(Natural Science Edition) 2015, 35(4):8-12.
[53] 张丽娟,孙青松,韩森. 掺加盐化物融冰雪材料的沥青混合料路用性能研究[J]. 中外公路, 2011, 31(4):269-273. ZHANG Lijuan, SUN Qingsong, HAN Sen. Study on the pavement performance of asphalt mixture with salt antifreezing materials[J]. Journal of China & Foreign Highway, 2011, 31(4):269-273.
[54] 陈杰. 盐化物融雪沥青路面耐久性及其融雪持久性研究[D]. 西安:长安大学, 2013. CHEN Jie. Study on the durability and snowmelt perdurability of salt anti-freezing asphalt pavement[D]. Xi'an:Chang'an University, 2013.