New progress in synthesis and application of functionalized polyolefin graft copolymers

doi:10.16085/j.issn.1000-6613.2015.06.031

Abstract

Abstract: The paper briefly describes the general significance of the synthesis of functional polyolefin graft copolymers. The recent progress in the design and the synthesis of functional polyolefin graft copolymers is reviewed. Three kinds of methods for the synthesis of functional polyolefin graft copolymers are introduced and compared with each other, i.e. I grafting onto, II grafting from:①living anionic polymerization, ②boron oxide mediated free radical polymerization, ③atom transfer radical polymerization(ATRP), ④nitrogen oxide mediated free radical polymerization(NMRP), ⑤reversible addition-fragmentation chain transfer polymerization, III grafting through. Then, the applications of polyolefin graft copolymers are briefly introduced. Finally, the prospect in functionalized polyolefin graft copolymers is foreseen, the research in new-pattern, high efficiency, practical methodologies and practical application are deemed to be the main research focuses of functional polyolefin graft copolymers.

Key words: functionalization, graft copolymers , synthesis , polymerization , ployolefin

摘要： 介绍了制备功能化聚烯烃接枝共聚物的意义及近年来功能化聚烯烃接枝共聚物的设计与合成中的应用研究新进展, 重点评述了制备功能化聚烯烃接枝共聚物时所采用的3种方法, I偶合接枝法;II引发接枝法:①阴离子聚合;②硼氧自由基存在下的控制自由基聚合;③原子转移自由基聚合(ATRP);④氮氧自由基存在下的控制自由基聚合(NMRP);⑤可逆加成-裂解链转移活性自由基聚合(RAFT);III直接接枝法, 并对上述方法进行了简单的优缺点对比。随后介绍了功能化聚烯烃接枝共聚物的应用。最后对功能化聚烯烃接枝共聚物的未来发展趋势进行了展望, 认为对新型、高效、实用的制备方法的探索以及实际应用将是功能化聚烯烃接枝共聚物领域的主要研究方向。

关键词: 功能化, 接枝共聚物, 合成, 聚合, 聚烯烃

CLC Number:

O632.1
TQ325

WU Haotian, L? Chi, JIANG Tao, CUI Kun, MA Zhi. New progress in synthesis and application of functionalized polyolefin graft copolymers[J]. Chemical Industry and Engineering Progree, 2015, 34(06): 1699-1707.

吴昊天, 吕弛, 姜涛, 崔崑, 马志. 功能化聚烯烃接枝共聚物的制备和应用研究新进展[J]. 化工进展, 2015, 34(06): 1699-1707.

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