Chemical Industry and Engineering Progress ›› 2022, Vol. 41 ›› Issue (9): 4653-4661.DOI: 10.16085/j.issn.1000-6613.2021-2432
• Chemical processes and equipment • Previous Articles Next Articles
LUO Zhenmin1,2,3(), LIU Lu1, SU Bin1, SONG Fangzhi1
Received:
2021-11-26
Revised:
2021-12-21
Online:
2022-09-27
Published:
2022-09-25
Contact:
LUO Zhenmin
通讯作者:
罗振敏
作者简介:
罗振敏(1976—),女,教授,博士生导师,研究方向为气体与粉尘爆炸防控。E-mail: zmluo@xust.edu.cn。
基金资助:
CLC Number:
LUO Zhenmin, LIU Lu, SU Bin, SONG Fangzhi. Effect of inert gas on ethylene explosion limit parameters and kinetic characteristics[J]. Chemical Industry and Engineering Progress, 2022, 41(9): 4653-4661.
罗振敏, 刘璐, 苏彬, 宋方智. 惰性气体影响乙烯爆炸极限参数及动力学特性[J]. 化工进展, 2022, 41(9): 4653-4661.
Add to citation manager EndNote|Ris|BibTeX
URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2021-2432
反应步 | 方程式 | 指前因子 |
---|---|---|
R25 | 1.25×107 | |
R38 | 2.65×1016 | |
R46 | 8.40×1013 | |
R112 | 3.60×106 | |
R119 | 3.78×1013 | |
R173 | 4.58×1016 | |
R285 | 6.70×106 | |
R294 | 3.03×1011 |
反应步 | 方程式 | 指前因子 |
---|---|---|
R25 | 1.25×107 | |
R38 | 2.65×1016 | |
R46 | 8.40×1013 | |
R112 | 3.60×106 | |
R119 | 3.78×1013 | |
R173 | 4.58×1016 | |
R285 | 6.70×106 | |
R294 | 3.03×1011 |
序号 | C2H4 | N2 | O2 | N2 | CO2 |
---|---|---|---|---|---|
工况1 | 4 | 76 | 20 | ||
工况2 | 4 | 52 | 14 | 30 | |
工况3 | 4 | 52 | 14 | 30 |
序号 | C2H4 | N2 | O2 | N2 | CO2 |
---|---|---|---|---|---|
工况1 | 4 | 76 | 20 | ||
工况2 | 4 | 52 | 14 | 30 | |
工况3 | 4 | 52 | 14 | 30 |
1 | 罗振敏, 解超, 王九柱, 等. N2和CO2对液化石油气(LPG)惰化抑爆效能对比分析[J]. 化工进展, 2019, 38(6): 2574-2580. |
LUO Zhenmin, XIE Chao, WANG Jiuzhu, et al. Comparative analysis of the inert effects of N2 and CO2 on LPG explosion[J]. Chemical Industry and Engineering Progress, 2019, 38(6): 2574-2580. | |
2 | 罗振敏, 杨勇, 程方明, 等. N2和CO2惰化丙烯爆炸极限参数实验研究[J]. 化工学报, 2020, 71(4): 1922-1928. |
LUO Zhenmin, YANG Yong, CHENG Fangming, et al. Experimental study on explosion limits parameters of propylene with dilution of nitrogen and carbon dioxide[J]. CIESC Journal, 2020, 71(4): 1922-1928. | |
3 | 周宁, 李海涛, 任常兴, 等. 氮气、二氧化碳对液化石油气的惰化抑爆研究[J]. 消防科学与技术, 2016, 35(6): 733-737. |
ZHOU Ning, LI Haitao, REN Changxing, et al. The liquefied petroleum gas inert gas explosion suppression about of nitrogen and carbon dioxide[J]. Fire Science and Technology, 2016, 35(6): 733-737. | |
4 | 周宁, 李海涛, 任常兴, 等. 多元混合气体爆炸特性及惰化防爆研究[J]. 安全与环境学报, 2018, 18(1): 165-171. |
ZHOU Ning, LI Haitao, REN Changxing, et al. On the bursting and explosion characteristic features and inert inhibition of the mixed gas[J]. Journal of Safety and Environment, 2018, 18(1): 165-171. | |
5 | 周宁, 王宇飞, 赵会军, 等. 惰化系统极限氧浓度变化规律及监测预警研究[J]. 中国安全科学学报, 2018, 28(1): 75-80. |
ZHOU Ning, WANG Yufei, ZHAO Huijun, et al. Study on change regulation of limit oxygen concentration and monitoring early warning system for inerting system[J]. China Safety Science Journal, 2018, 28(1): 75-80. | |
6 | TREVIÑO C, MÉNDEZ F. Reduced kinetic mechanism for methane ignition[J]. Symposium (International) on Combustion, 1992, 24(1): 121-127. |
7 | MEDVEDEV V G, TELEGIN V G, TELEGIN G G. Statistical analysis of kinetics of an adiabatic thermal explosion[J]. Combustion, Explosion, and Shock Waves, 2009, 45(3): 274-277. |
8 | NIE Baisheng, YANG Longlong, GE Boqing, et al. Chemical kinetic characteristics of methane/air mixture explosion and its affecting factors[J]. Journal of Loss Prevention in the Process Industries, 2017, 49:675-682. |
9 | 罗振敏, 张群, 王华, 等. 基于FLACS的受限空间瓦斯爆炸数值模拟[J]. 煤炭学报, 2013, 38(8): 1381-1387. |
LUO Zhenmin, ZHANG Qun, WANG Hua, et al. Numerical simulation of gas explosion in confined space with FLACS[J]. Journal of China Coal Society, 2013, 38(8): 1381-1387. | |
10 | 罗振敏, 邓军, 郭晓波. 基于Gaussian的瓦斯爆炸微观反应机理[J]. 辽宁工程技术大学学报(自然科学版), 2008, 27(3): 325-328. |
LUO Zhenmin, DENG Jun, GUO Xiaobo. Microcosmic mechanism of gas explosion based on Gaussian[J]. Journal of Liaoning Technical University (Natural Science), 2008, 27(3): 325-328. | |
11 | 梁运涛, 曾文. 定容燃烧弹中瓦斯爆炸的反应动力学模拟[J]. 燃烧科学与技术, 2010, 16(4): 375-381. |
LIANG Yuntao, ZENG Wen. Kinetic simulation of gas explosion in constant volume bomb[J]. Journal of Combustion Science and Technology, 2010, 16(4): 375-381. | |
12 | 梁运涛, 王连聪, 罗海珠, 等. 定容燃烧反应器中瓦斯爆炸反应动力学计算模型[J]. 煤炭学报, 2015, 40(8): 1853-1858. |
LIANG Yuntao, Wang Liancong, Luo Haizhu, et al. Computational model of reaction kinetic for gas explosion in constant volume combustion reactor[J]. Journal of China Coal Society, 2015, 40(8): 1853-1858. | |
13 | 贾宝山, 李艳红, 曾文, 等. 定容体系中氮气影响瓦斯爆炸反应的动力学模拟[J]. 过程工程学报, 2011, 11(5): 812-817. |
JIA Baoshan, LI Yanhong, ZENG Wen, et al. Kinetic simulation for the effect of N2 content on gas explosion in an constant volume system[J]. The Chinese Journal of Process Engineering, 2011, 11(5): 812-817. | |
14 | 贾宝山, 温海燕, 梁运涛, 等. 煤矿巷道内N2及CO2抑制瓦斯爆炸的机理特性[J]. 煤炭学报, 2013, 38(3): 361-366. |
JIA Baoshan, WEN Haiyan, Liang Yuntao, et al. Mechanism characteristics of CO2 and N2 inhibiting methane explosions in coal mine roadways[J]. Journal of China Coal Society, 2013, 38(3): 361-366. | |
15 | 贾宝山, 胡如霞, 李春苗, 等. 受限空间内C2H6对瓦斯爆炸的促进机理研究[J]. 中国安全生产科学技术, 2015, 11(10): 17-22. |
JIA Baoshan, HU Ruxia, LI Chunmiao, et al. Study on promoting mechanism of C2H6 on gas explosion in confined space[J]. Journal of Safety Science and Technology, 2015, 11(10): 17-22. | |
16 | 贾宝山, 李艳红, 曾文, 等. 受限空间瓦斯爆炸链式反应机理的敏感性分析[J]. 环境工程, 2011, 29(S1): 318-323. |
JIA Baoshan, LI Yanhong, ZENG Wen, et al. Sensitive analysis of chain reaction mechanism of gas explosion[J]. Environmental Engineering, 2011, 29(S1): 318-323. | |
17 | 贾宝山, 温海燕, 梁运涛, 等. 受限空间瓦斯爆炸与氢气促进机理研究[J]. 中国安全科学学报, 2012, 22(2): 81-87. |
JIA Baoshan, WEN Haiyan, LIANG Yuntao, et al. Study on the methane explosion in an enclosed space and hydrogen promoting mechanism[J]. China Safety Science Journal, 2012, 22(2): 81-87. | |
18 | 贾宝山, 王小云, 张师一, 等. 受限空间中CO与水蒸汽阻尼瓦斯爆炸的反应动力学模拟研究[J]. 火灾科学, 2013, 22(3): 131-139. |
JIA Baoshan, WANG Xiaoyun, ZHANG Shiyi, et al. Kinetic simulation of CO and water vapor damping the gas explosion in an enclosed space[J]. Fire Safety Science, 2013, 22(3): 131-139. | |
19 | 李孝斌, 李会荣, 何昆, 等. 甲烷爆炸感应期内CN/CH/CHO/CH2O/NCN特征光谱分析[J]. 煤炭学报, 2014, 39(10): 2042-2046. |
LI Xiaobin, LI Huirong, HE Kun, et al. Analysis of characteristic spectrum of CN/CH/CHO/CH2O/NCN in induction period of methane explosion[J]. Journal of China Coal Society, 2014, 39(10): 2042-2046. | |
20 | 杨春丽, 刘艳, 胡玢, 等. 氮气和水蒸气对瓦斯爆炸基元反应的影响及抑爆机理分析[J]. 高压物理学报, 2017, 31(3): 301-308. |
YANG Chunli, LIU Yan, HU Bin, et al. Effect of nitrogen and water vapor on methane-air mixture explosion elementary reaction and suppression mechanism[J]. Chinese Journal of High Pressure Physics, 2017, 31(3): 301-308. | |
21 | YU Xiaozhe, YAN Xingqing, JI Wentao, et al. Effect of super-ambient conditions on the upper explosion limit of ethane/oxygen and ethylene/oxygen mixtures[J]. Journal of Loss Prevention in the Process Industries, 2019, 59: 100-105. |
22 | 罗灿. 高温高压下乙烷、乙烯在纯氧中爆炸极限研究[D]. 大连: 大连理工大学, 2018. |
LUO Can. Research on the explosion limit of ethane-oxygen and ethylene-oxygen mixtures at elevated temperatures and pressures[D]. Dalian: Dalian University of Technology, 2018. | |
23 | 喻健良, 纪文涛, 孙会利, 等. 乙烯/聚乙烯两相体系爆炸特性[J]. 化工学报, 2017, 68(12): 4841-4847. |
YU Jianliang, JI Wentao, SUN Huili, et al. Explosibility of hybrid mixtures of ethylene and polyethylene dust[J]. CIESC Journal, 2017, 68(12): 4841-4847. | |
24 | 杨理, 饶国宁, 解立峰, 等. 扩散时间对乙烯-空气燃爆特性的影响[J]. 高压物理学报, 2015, 29(5): 369-376. |
YANG Li, RAO Guoning, XIE Lifeng, et al. Effect of diffusion time on deflagration and detonation parameters of ethene-air[J]. Chinese Journal of High Pressure Physics, 2015, 29(5): 369-376. | |
25 | 乐慧慧, 张浩, 朱中南, 等. 乙烯-氧-醋酸-氮气-二氧化碳系统爆炸极限的测定研究[J]. 化学反应工程与工艺, 1995, 11(1): 80-85. |
LE Huihui, ZHANG Hao, ZHU Zhongnan, et al. A study on the explosion limits for the system of ethylene-oxygen-acetic acid nitrogen-carbon dioxide[J].Chemical Reaction Engineering and Technology, 1995, 11(1): 80-85. | |
26 | HOLTAPPELS K, BRINKMANN C, DIETLEN S, et al. Measurement and prediction of the inert gas influence on explosion limits for ethylene/nitrogen/air and ethylene/carbon-dioxide/air mixtures at elevated pressures[J]. Chemical Engineering & Technology, 2001, 24(12): 1263-1267. |
27 | 张欣, 任常兴, 张琰, 等. 三种测试装置与判定标准对比研究可燃气体爆炸[J]. 消防科学与技术, 2018, 37(7): 863-866. |
ZHANG Xin, REN Changxing, ZHANG Yan, et al. Research on flammable gas by three test devices and three criterions[J]. Fire Science and Technology, 2018, 37(7): 863-866. | |
28 | LUTZ A E, KEE R J, MILLER J A. SENKIN: A Fortran program for predicting homogeneous gas phase chemical kinetics with sensitivity analysis[R]. Sandia National Laboratories Report, 1987. |
29 | RODAT S, ABANADES S, COULIÉ J, et al. Kinetic modelling of methane decomposition in a tubular solar reactor[J]. Chemical Engineering Journal, 2009, 146(1): 120-127. |
30 | CARRASCO N, ALCARAZ C, DUTUIT O, et al. Sensitivity of a Titan ionospheric model to the ion-molecule reaction parameters[J]. Planetary and Space Science, 2008, 56(12): 1644-1657. |
31 | RASMUSSEN C L, RASMUSSEN A E, GLARBORG P. Sensitizing effects of NO x on CH4 oxidation at high pressure[J]. Combustion and Flame, 2008, 154(3): 529-545. |
32 | GREGORY P, SMITH D G. Gri-Mech at 3.0[EB/OL]. , 2007. |
33 | 韩美. 新的爆炸危险度F值[J]. 低温与特气, 1995, 13(2): 57-60. |
HAN Mei. A new explosive hazard degree F [J]. Low Temperature and Specialty Gases, 1995, 13(2): 57-60. |
[1] | ZHAO Chen, MIAO Tianze, ZHANG Chaoyang, HONG Fangjun, WANG Dahai. Heat transfer characteristics of ethylene glycol aqueous solution in slit channel under negative pressure [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 148-157. |
[2] | YANG Hanyue, KONG Lingzhen, CHEN Jiaqing, SUN Huan, SONG Jiakai, WANG Sicheng, KONG Biao. Decarbonization performance of downflow tubular gas-liquid contactor of microbubble-type [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 197-204. |
[3] | ZHENG Qian, GUAN Xiushuai, JIN Shanbiao, ZHANG Changming, ZHANG Xiaochao. Photothermal catalysis synthesis of DMC from CO2 and methanol over Ce0.25Zr0.75O2 solid solution [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 319-327. |
[4] | GU Yongzheng, ZHANG Yongsheng. Dynamic behavior and kinetic model of Hg0 adsorption by HBr-modified fly ash [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 498-509. |
[5] | WANG Peng, ZHANG Yang, FAN Bingqiang, HE Dengbo, SHEN Changshuai, ZHANG Hedong, ZHENG Shili, ZOU Xing. Process and kinetics of hydrochloric acid leaching of high-carbon ferrochromium [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 510-517. |
[6] | SUN Yuyu, CAI Xinlei, TANG Jihai, HUANG Jingjing, HUANG Yiping, LIU Jie. Optimization and energy-saving of a reactive distillation process for the synthesis of methyl methacrylate [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 56-63. |
[7] | BAI Zhihua, ZHANG Jun. Oxidative removal of NO in DTPMPA/Fenton system [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4967-4973. |
[8] | LAI Shini, JIANG Lixia, LI Jun, HUANG Hongyu, KOBAYASHI Noriyuki. Research progress of ammonia blended fossil fuel [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4603-4615. |
[9] | ZHANG Zhichen, ZHU Yunfeng, CHENG Weishu, MA Shoutao, JIANG Jie, SUN Bing, ZHOU Zichen, XU Wei. Research advances on runaway decomposition of high pressure polyethylene: Reaction mechanism, initiation system and model [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 3979-3989. |
[10] | WANG Yaogang, HAN Zishan, GAO Jiachen, WANG Xinyu, LI Siqi, YANG Quanhong, WENG Zhe. Strategies for regulating product selectivity of copper-based catalysts in electrochemical CO2 reduction [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4043-4057. |
[11] | LIU Yi, FANG Qiang, ZHONG Dazhong, ZHAO Qiang, LI Jinping. Cu facets regulation of Ag/Cu coupled catalysts for electrocatalytic reduction of carbon dioxide [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4136-4142. |
[12] | GUO Jin, ZHANG Geng, CHEN Guohua, ZHU Ming, TAN Yue, LI Wei, XIA Li, HU Kun. Research progress on vehicle liquid hydrogen cylinder design [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4221-4229. |
[13] | HUANG Yufei, LI Ziyi, HUANG Yangqiang, JIN Bo, LUO Xiao, LIANG Zhiwu. Research progress on catalysts for photocatalytic CO2 and CH4 reforming [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4247-4263. |
[14] | LI Yanling, ZHUO Zhen, CHI Liang, CHEN Xi, SUN Tanglei, LIU Peng, LEI Tingzhou. Research progress on preparation and application of nitrogen-doped biochar [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3720-3735. |
[15] | LI Jia, FAN Xing, CHEN Li, LI Jian. Research progress of simultaneous removal of NO x and N2O from the tail gas of nitric acid production [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3770-3779. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||
京ICP备12046843号-2;京公网安备 11010102001994号 Copyright © Chemical Industry and Engineering Progress, All Rights Reserved. E-mail: hgjz@cip.com.cn Powered by Beijing Magtech Co. Ltd |