Progress in preparation and application of superhydrophobic materials based on polyvinyl chloride

doi:10.16085/j.issn.1000-6613.2021-1683

Abstract

Abstract:

Polyvinyl chloride (PVC) is one of the most widely used plastics in the world because of its excellent chemical and mechanical characteristics, the advantages of cheap accessible and widely used in medical equipment manufacturing, construction, food and electronic industries. PVC has a contact angle of 90° to water and is required to achieve superhydrophobic properties in applications such as biomedical and metal corrosion prevention. Therefore, the demand for PVC-based superhydrophobic materials has become increasingly urgent. In this paper, the classification, preparation methods and application fields of PVC-based superhydrophobic materials are reviewed. The different types, different preparation methods of hydrophobic performance of polyvinyl chloride based superhydrophobic material are compared. Finally, some problems of this field are summarized, mainly including that the preparation process is limited to laboratory operations, and the wear resistance, durability and mechanical strength of the materials need to be investigated, etc. The development direction of this field is pointed out: ①developing a simple, environmentally friendly, low-cost large-scale preparation processes; ②overcoming the weak points of poor thermal and light stability of PVC materials, carrying forward its advantages of good corrosion resistance and high mechanical strength, and further expanding the application range of PVC materials.

Key words: polyvinyl chloride, superhydrophobic, preparation, application, coating

摘要：

聚氯乙烯（PVC）是世界上应用最广泛的塑料之一，因其具有化学和机械特性优异、廉价易得等优点而广泛应用于医疗器械制造、建筑、食品和电子等行业。PVC对水的接触角为90°，而在生物医学和金属防腐蚀等领域的应用中，需要PVC达到超疏水性能。因此，PVC基超疏水材料的需求也变得愈加迫切。本文综述了聚氯乙烯基超疏水材料的分类、制备方法和应用领域，对比了不同种类、不同制备方法的聚氯乙烯基超疏水材料的疏水性能优劣，总结出目前该领域的一些问题，主要包括制备工艺仅限于实验室操作、材料的耐磨耐久性及机械强度有待考察等，并指出该领域的发展方向：①开发简单、环保、低成本的大规模制备工艺；②克服PVC材料热、光稳定性差的弱点，发扬其耐腐蚀性好、机械强度高的优点，进一步扩大材料的应用范围。

关键词: 聚氯乙烯, 超疏水, 制备, 应用, 涂层

CLC Number:

TQ317.9

ZHU Xuedan, YAO Yali, MA Lili, WANG Jiaxin, YANG Jie, PENG Lei, HE Jinmei, QU Mengnan. Progress in preparation and application of superhydrophobic materials based on polyvinyl chloride[J]. Chemical Industry and Engineering Progress, 2022, 41(7): 3676-3688.

朱雪丹, 姚亚丽, 马利利, 王嘉鑫, 杨杰, 彭磊, 何金梅, 屈孟男. 聚氯乙烯基超疏水材料的制备及应用研究进展[J]. 化工进展, 2022, 41(7): 3676-3688.

Figures/Tables 14

References 74

1	LAW K Y. Definitions for hydrophilicity, hydrophobicity, and superhydrophobicity: getting the basics right[J].The Journal of Physical Chemistry Letters, 2014, 5 (4): 686-688.
2	WENZEL R N. Resistance of solid surfaces to wetting by water[J]. Industrial & Engineering Chemistry, 2002, 28(8): 988-994.
3	CASSIE A B D, BAXTER S. Wettability of porous surfaces[J]. Transactions of the Faraday Society, 1944, 40: 546-551.
4	FENG X J, JIANG L. Design and creation of superwetting/antiwetting surfaces[J]. Advanced Materials, 2006, 18(23): 3063-3078.
5	NEINHUIS C, BARTHLOTT W. Characterization and distribution of water-repellent, self-cleaning plant surfaces[J]. Annals of Botany, 1997,79(6): 667-677.
6	BARTHLOTT W, NEINHUIS C. Purity of the sacred lotus, or escape from contamination in biological surfaces[J]. Planta, 1997, 202(1):1-8.
7	FENG L, LI S, LI Y, et al. Super-hydrophobic surfaces: from natural to artificial[J]. Advanced Materials, 2002, 14(24):1857-1860.
8	YU Y, ZHAO Z H, ZHENG Q S. Mechanical and superhydrophobic stabilities of two-scale surfacial structure of lotus leaves[J]. Langmuir, 2007, 23(15): 8212-8216.
9	LUO C, ZUO X, WANG L, et al. Flexible carbon nanotube-polymer composite films with high conductivity and superhydrophobicity made by solution process[J]. Nano Letters, 2008, 8(12):4454-4458.
10	HU Z H, SUN M, LYU M, et al. Deciphering buried air phases on natural and bioinspired superhydrophobic surfaces using synchrotron radiation-based X-ray phase-contrast imaging[J]. NPG Asia Materials, 2016, 8(9):e306.
11	MCKEEN L W. Handbook of polymer applications in medicine and medical devices: 3. Plastics used in medical devices[M]. Elsevier Inc. Chapters, 2013.
12	YUAN Z Q, CHEN H, ZHANG J D. Facile method to prepare lotus-leaf-like super-hydrophobic poly(vinyl chloride) film[J]. Applied Surface Science, 2008, 254(6):1593-1598.
13	CHEN H, YUAN Z Q, ZHANG J D, et al. Preparation, characterization and wettability of porous superhydrophobic poly(vinyl chloride) surface[J]. Journal of Porous Materials, 2009, 16(4): 447-451.
14	YANG N, LI J C, BAI N N, et al. One step phase separation process to fabricate superhydrophobic PVC films and its corrosion prevention for AZ91D magnesium alloy[J]. Materials Science and Engineering B, 2016, 209: 1-9.
15	KOPONEN H K, SAARIKOSKI I, KORHONEN T, et al. Modification of cycloolefin copolymer and poly(vinyl chloride)surfaces by superimposition of nano- and microstructures[J]. Applied Surface Science, 2007, 253(12):5208-5213.
16	GURAV A B, LATTHE S S, VHATKAR R S, et al. Superhydrophobic surface decorated with vertical ZnO nanorods modified by stearic acid[J]. Ceramics International, 2014, 40(5):7151-7160.
17	KOKARE A M, SUTAR R S, DESHMUKH S G, et al. ODS-modified TiO₂ nanoparticles for the preparation of self-cleaning superhydrophobic coating[J]. AIP Conference Proceedings, 2018, 1953(1): 100068.
18	LATTHE S S, NAKATA K, HÖFER R, et al. CHAPTER 5. Lotus effect-based superhydrophobic surfaces: candle soot as a promising class of nanoparticles for self-cleaning and oil-water separation applications[M]//Green Chemistry Series. Cambridge: Royal Society of Chemistry, 2019: 92-119.
19	SUTAR R S, KALEL P J, LATTHE S S, et al. Superhydrophobic PVC/SiO₂ coating for self-cleaning application[J]. Macromolecular Symposia, 2020, 393(1): 2000034.
20	YILGOR I, BILGIN S, ISIK M, et al. Facile preparation of superhydrophobic polymer surfaces[J]. Polymer, 2012, 53(6):1180-1188.
21	YOON H, KIM H, LATTHE S S, et al. A highly transparent self-cleaning superhydrophobic surface by organosilane-coated alumina particles deposited via electrospraying[J]. Journal of Materials Chemistry A, 2015, 3(21):11403-11410.
22	GUO Y G, WANG Q H. Facile approach in fabricating superhydrophobic coatings from silica-based nanocomposite[J]. Applied Surface Science, 2010, 257(1): 33-36.
23	PAWAR P G, XING R M, KAMBALE R C, et al. Polystyrene assisted superhydrophobic silica coatings with surface protection and self-cleaning approach[J]. Progress in Organic Coatings, 2017, 105:235-244.
24	ZHANG X, DING B, CHENG R, et al. Computational intelligence-assisted understanding of nature-inspired superhydrophobic behavior[J]. Advanced Science, 2018, 5(1): 1700520.
25	CHEN H Z, ZHANG X, ZHANG P Y, et al. Facile approach in fabricating superhydrophobic SiO₂/polymer nanocomposite coating[J]. Applied Surface Science, 2012, 261: 628-632.
26	LATTHE S S, SUTAR R S, KODAG V S, et al. Self-cleaning superhydrophobic coatings: potential industrial applications[J]. Progress in Organic Coatings, 2019, 128: 52-58.
27	QU M N, LIU S S, HE J M, et al. Fabrication of recyclable superhydrophobic materials with self-cleaning and mechanically durable properties on various substrates by quartz sand and polyvinylchloride[J]. RSC Advances, 2016, 6(82): 79238-79244.
28	QU M N, LIU S S, HE J M, et al. Fabrication of recyclable and durable superhydrophobic materials with wear/corrosion-resistance properties from kaolin and polyvinylchloride[J]. Applied Surface Science, 2017, 410: 299-307.
29	SEYFI J, PANAHI-SARMAD M, ORAEIGHODOUSI A, et al. Antibacterial superhydrophobic polyvinyl chloride surfaces via the improved phase separation process using silver phosphate nanoparticles[J]. Colloids and Surfaces B Biointerfaces, 2019, 183: 110438.
30	IRIBARREN A, RIVERO P, BERLANGA C, et al. Multifunctional protective PVC-ZnO nanocomposite coatings deposited on aluminum alloys by electrospinning[J]. Coatings, 2019, 9(4): 216.
31	RIVERO P J, IRIBARREN A, LARUMBE S, et al. A comparative study of multifunctional coatings based on electrospun fibers with incorporated ZnO nanoparticles[J]. Coatings, 2019, 9(6): 367.
32	MOLLA-ABBASI P. Effect of nano-size nodular structure induced by CNT-promoted phase separation on the fabrication of superhydrophobic polyvinyl chloride films[J]. Polymers for Advanced Technologies, 2021, 32(1):391-401.
33	RIOBOO R, DEMNATI I, ALI M A, et al. Superhydrophobicity of composite surfaces created from polymer blends[J]. Journal of Colloid and Interface Science, 2020, 560: 596-605.
34	张大帅.超疏水PVDF/PVC复合膜的制备及其在膜蒸馏海水淡化中的应用[D].海口：海南师范大学, 2020.
	ZHANG Dashuai. Preparation of superhydrophobic PVDF/PVC composite membrane and application in membrane distillation for desalination [D]. Haikou: Hainan Normal University, 2020.
35	ERBIL H Y, DEMIREL A L, AVCı Y, et al. Transformation of a simple plastic into a superhydrophobic surface[J]. Science, 2003, 299(5611): 1377-1380.
36	周存, 秦兆立, 王闻宇, 等. 动力/储能锂离子电池隔膜制备先进技术及研究进展[J].材料导报, 2018, 32(23): 4051-4060.
	ZHOU Cun, QIN Zhaoli, WANG Wenyu, et al. The state-of-the-art preparation technology of separator for power/energy storage lithium ion battery: a review[J]. Materials Review, 2018, 32(23): 4051-4060.
37	侯瑞, 李桂群, 张岩, 等.聚合物相分离技术在超疏水表面制备中的应用[J].化工进展, 2020, 39(2): 616-626.
	HOU Rui, LI Guiqun, ZHANG Yan, et al. Application of polymer phase separation technique in preparation of superhydrophobic surface[J]. Chemical Industry and Engineering Progress, 2020, 39(2): 616-626.
38	PATEL S U, CHASE G G. Separation of water droplets from water-in-diesel dispersion using superhydrophobic polypropylene fibrous membranes[J]. Separation and Purification Technology, 2014, 126: 62-68.
39	YUAN Z Q, CHEN H, TANG J X, et al. Facile method to fabricate stable superhydrophobic polystyrene surface by adding ethanol[J]. Surface and Coatings Technology, 2007, 201(16/17): 7138-7142.
40	KANG Y K, WANG J Y, YANG G B, et al. Preparation of porous super-hydrophobic and super-oleophilic polyvinyl chloride surface with corrosion resistance property[J]. Applied Surface Science, 2011, 258(3): 1008-1013.
41	MAGHSOUDI K, VAZIRINASAB E, MOMEN G, et al. Advances in the fabrication of superhydrophobic polymeric surfaces by polymer molding processes[J]. Industrial & Engineering Chemistry Research, 2020, 59(20): 9343-9363.
42	邓建辉, 杨晓青, 方称辉, 等. 静电纺丝/静电喷雾技术在电池领域的应用进展[J].化工进展，2021, 40(10)： 5600-5614.
	DENG Jianhui, YANG Xiaoqing, FANG Chenhui, et al. Application of electrospinning and electrospray technology in battery/cell field[J]. Chemical Industry and Engineering Progress, 2021, 40(10)： 5600-5614.
43	BAO Q L, ZHANG H, YANG J X, et al. Graphene-polymer nanofiber membrane for ultrafast photonics[J]. Advanced Functional Materials, 2010, 20(5): 782-791.
44	ZHAO R, LU X F, WANG C. Electrospinning based all-nano composite materials: recent achievements and perspectives[J]. Composites Communications, 2018, 10: 140-150.
45	RENEKER D H, YARIN A L, FONG H, et al. Bending instability of electrically charged liquid jets of polymer solutions in electrospinning[J]. Journal of Applied Physics, 2000, 87(9): 4531-4547.
46	SHIN Y M, HOHMAN M M, BRENNER M P, et al. Electrospinning: a whipping fluid jet generates submicron polymer fibers[J]. Applied Physics Letters, 2001, 78(8): 1149-1151.
47	LEE J K Y, CHEN N, PENG S J, et al. Polymer-based composites by electrospinning: preparation & functionalization with nanocarbons[J]. Progress in Polymer Science, 2018, 86: 40-84.
48	岳青, 王绍德, 徐飞, 等. 静电纺丝技术及其在各领域中的应用[J].材料导报, 2021, 35(S1): 594-599.
	YUE Qing, WANG Shaode, XU Fei, et al. Electrostatic spinning technology and its application in various fields[J]. Materials Reports, 2021, 35(S1): 594-599.
49	MA M, GUPTA M, LI Z, et al. Decorated electrospun fibers exhibiting superhydrophobicity[J]. Advanced Materials, 2007, 19(2): 255-259.
50	ACATAY K, SIMSEK E, OW-YANG C, et al. Tunable, superhydrophobically stable polymeric surfaces by electrospinning[J]. Angewandte Chemie International Edition, 2004, 43(39): 5210-5213.
51	PARK S H, LEE S M, LIM H S, et al. Robust superhydrophobic mats based on electrospun crystalline nanofibers combined with a silane precursor[J]. ACS Applied Materials & Interfaces, 2010, 2(3): 658-662.
52	RIVERO P, GARCIA J, QUINTANA I, et al. Design of nanostructured functional coatings by using wet-chemistry methods[J]. Coatings, 2018,8(2): 76.
53	ASMATULU R, CEYLAN M, NURAJE N. Study of superhydrophobic electrospun nanocomposite fibers for energy systems[J]. Langmuir, 2011, 27(2): 504-507.
54	LEE K H, KIM H Y, LA Y M, et al. Influence of a mixing solvent with tetrahydrofuran and N,N-dimethylformamide on electrospun poly(vinyl chloride) nonwoven mats[J]. Journal of Polymer Science B: Polymer Physics, 2002, 40(19): 2259-2268.
55	KIM D K, LEE S B, DOH K S. Surface properties of fluorosilicone copolymers and their surface modification effects on PVC film[J]. Journal of Colloid and Interface Science, 1998, 205(2): 417-422.
56	JIANG Z Q, WANG X Q, JIA H Y, et al. Superhydrophobic polytetrafluoroethylene/heat-shrinkable polyvinyl chloride composite film with super anti-icing property[J]. Polymers, 2019, 11(5): 805.
57	LI C Q, ZHU M Y, OU J F, et al. Dynamic corrosion behavior of superhydrophobic surfaces[J]. RSC Advances, 2018, 8(51): 29201-29209.
58	MOHAMED A M A, ABDULLAH A M, YOUNAN N A. Corrosion behavior of superhydrophobic surfaces: a review[J]. Arabian Journal of Chemistry, 2015, 8(6): 749-765.
59	JEEN ROBERT R B, HIKKU G S, JEYASUBRAMANIAN K, et al. ZnO nanoparticles impregnated polymer composite as superhydrophobic anti-corrosive coating for aluminium-6061 alloy[J]. Materials Research Express, 2019, 6(7): 75705.
60	GABRIEL M, STRAND D, VAHL C F. Cell adhesive and antifouling polyvinyl chloride surfaces via wet chemical modification[J]. Artificial Organs, 2012, 36(9): 839-844.
61	LAKSHMI S, JAYAKRISHNAN A. Migration resistant, blood-compatible plasticized polyvinyl chloride for medical and related applications[J]. Artificial Organs, 1998, 22(3): 222-229.
62	MILIANI K, MIGUERES B, VERJAT-TRANNOY D, et al. National point prevalence survey of healthcare-associated infections and antimicrobial use in French home care settings, May to June 2012[J]. Euro Surveillance, 2015, 20(27): 12-22.
63	NAEEMABADI N, SEYFI J, HEJAZI E, et al. Investigation on surface properties of superhydrophobic nanocomposites based on polyvinyl chloride and correlation with cell adhesion behavior[J]. Polymers for Advanced Technologies, 2019, 30(4): 1027-1035.
64	LOO C Y, YOUNG P M, LEE W H, et al. Superhydrophobic, nanotextured polyvinyl chloride films for delaying Pseudomonas aeruginosa attachment to intubation tubes and medical plastics[J]. Acta Biomaterialia, 2012, 8(5): 1881-1890.
65	HELLIO C, YEBRA D. Advances in marine antifouling coatings and technologies[M]. Oxford: Woodhead Publishing Series, Limited, 2009.
66	IYAPPARAJ P, REVATHI P, RAMASUBBURAYAN R, et al. Antifouling and toxic properties of the bioactive metabolites from the seagrasses Syringodium isoetifolium and Cymodocea serrulata [J]. Ecotoxicology and Environmental Safety, 2014, 103: 54-60.
67	GUDIPATI C S, FINLAY J A, CALLOW J A, et al. The antifouling and fouling-release perfomance of hyperbranched fluoropolymer (HBFP)-poly(ethylene glycol) (PEG) composite coatings evaluated by adsorption of biomacromolecules and the green fouling alga ulva[J]. Langmuir, 2005, 21(7): 3044-3053.
68	MARMUR A. Super-hydrophobicity fundamentals: implications to biofouling prevention[J]. Biofouling, 2006, 22(1/2): 107-115.
69	王强, 李昌诚, 闫雪峰等. 低表面能海洋防污涂层技术及其评价方法[J].材料导报, 2008, 22(10): 84-87, 94.
	WANG Qiang, LI Changcheng, YAN Xuefeng, et al. Marine antifouling coating technology with low surface energy and its evaluation methods[J]. Materials Review, 2008, 22(10): 84-87, 94.
70	BROWN R, RUSSELL S, MAY S, et al. Reproducible superhydrophobic PVC coatings; investigating the use of plasticizers for early stage biofouling control[J]. Advanced Engineering Materials, 2017, 19(7): 1700053.
71	WANG Y B, XU Y M, HUANG Q. Progress on ultrasonic guided waves de-icing techniques in improving aviation energy efficiency[J]. Renewable and Sustainable Energy Reviews, 2017, 79: 638-645.
72	ZUO Z P, LIAO R J, GUO C, et al. Fabrication and anti-icing property of coral-like superhydrophobic aluminum surface[J]. Applied Surface Science, 2015, 331: 132-139.
73	余春浩, 宫敬, 郝鹏飞, 等. 超疏水表面防结冰结霜性能的研究进展[J].材料导报, 2014, 28(13): 65-68.
	YU Chunhao, GONG Jing, HAO Pengfei, et al. Progress of anti-icing and anti-frosting properties of super hydrophobic surface[J]. Mterials Review, 2014, 28(13): 65-68.
74	LONG Y F, YIN X X, MU P, et al. Slippery liquid-infused porous surface (SLIPS) with superior liquid repellency, anti-corrosion, anti-icing and intensified durability for protecting substrates[J]. Chemical Engineering Journal, 2020, 401: 126137.

理论模型	二维模型	要点
Young方程		基于理想光滑平整固体表面，接触角取决于固体表面能
Wenzel模型		认为液体能完全进入固体表面的粗糙结构，粗糙度的增加有助于增加疏水固体表面的接触角
Cassie-Baxter方程		认为液体与粗糙结构之间会留存空气，使得液滴不会渗透进入表面粗糙结构中，提高固-气接触面积百分比可提高接触角
Cassie-Wenzel过渡态		Cassie和Wenzel两种状态可以共存也可以在一定情形发生转变，Cassie模式变为Wenzel模式时，表观接触角会降低

理论模型	二维模型	要点
Young方程		基于理想光滑平整固体表面，接触角取决于固体表面能
Wenzel模型		认为液体能完全进入固体表面的粗糙结构，粗糙度的增加有助于增加疏水固体表面的接触角
Cassie-Baxter方程		认为液体与粗糙结构之间会留存空气，使得液滴不会渗透进入表面粗糙结构中，提高固-气接触面积百分比可提高接触角
Cassie-Wenzel过渡态		Cassie和Wenzel两种状态可以共存也可以在一定情形发生转变，Cassie模式变为Wenzel模式时，表观接触角会降低

PVC膜类型	制备方法	共混聚合物/无机粒子	接触角	滑动角	应用领域	参考文献
单一PVC膜	NIPS（乙醇）	—	155°		金属防腐蚀	［14］
	NIPS（乙醇）	—	154°		耐酸碱腐蚀	［13］
	NIPS（乙酸）	—	150°±1.5°		耐酸碱腐蚀	［40］
	NIPS（甲醇、乙醇）	—	150°±3°		抗菌	［64］
	NIPS（乙醇）	—	154°		防生物污垢	［70］
	仿生模板法（荷叶）	—	157°±1.8°	3°±0.6°		［12］
含PVC的聚合物共混膜	NIPS（水）	PVDF	152°		自清洁	［34］
	溶剂压铸法	氟硅共聚物	117°			［55］
	表面沉积	PTFE	150°		除冰	［56］
PVC与无机粒子复合膜	NIPS（乙醇）	Ag₃PO₄	156°±1°	2°±1°	抗菌	［29］
	NIPS（乙醇）	碳纳米管	157°	<5°		［32］
	NIPS（乙醇）	疏水SiO₂（自购）	161°	<3°	抗菌	［63］
	仿生模板法（荷叶）	疏水SiO₂（HMDS）	162°	6°		［24］
	滴涂法	疏水SiO₂（HMDS）	168°		耐酸碱腐蚀	［22］
	喷涂法	疏水SiO₂（MTMS）	169°±2°	6°	自清洁、透明	［21］
	旋涂法	疏水SiO₂（TMCS）	162°		金属防腐蚀	［25］
	滴涂法	石英砂（DEDMS）	156°	6°	耐磨耐久	［27］
	滴涂法	高岭土（硬脂酸）	156°	<10°	耐磨耐腐蚀	［28］
	浸涂法	CS和ZnO	154°		金属防腐蚀	［59］
	静电纺丝	ZnO	146.39°		金属防腐蚀	［31］
	静电纺丝	TiO₂/石墨烯	168.3°/161°		光电极	［53］

PVC膜类型	制备方法	共混聚合物/无机粒子	接触角	滑动角	应用领域	参考文献
单一PVC膜	NIPS（乙醇）	—	155°		金属防腐蚀	［14］
	NIPS（乙醇）	—	154°		耐酸碱腐蚀	［13］
	NIPS（乙酸）	—	150°±1.5°		耐酸碱腐蚀	［40］
	NIPS（甲醇、乙醇）	—	150°±3°		抗菌	［64］
	NIPS（乙醇）	—	154°		防生物污垢	［70］
	仿生模板法（荷叶）	—	157°±1.8°	3°±0.6°		［12］
含PVC的聚合物共混膜	NIPS（水）	PVDF	152°		自清洁	［34］
	溶剂压铸法	氟硅共聚物	117°			［55］
	表面沉积	PTFE	150°		除冰	［56］
PVC与无机粒子复合膜	NIPS（乙醇）	Ag₃PO₄	156°±1°	2°±1°	抗菌	［29］
	NIPS（乙醇）	碳纳米管	157°	<5°		［32］
	NIPS（乙醇）	疏水SiO₂（自购）	161°	<3°	抗菌	［63］
	仿生模板法（荷叶）	疏水SiO₂（HMDS）	162°	6°		［24］
	滴涂法	疏水SiO₂（HMDS）	168°		耐酸碱腐蚀	［22］
	喷涂法	疏水SiO₂（MTMS）	169°±2°	6°	自清洁、透明	［21］
	旋涂法	疏水SiO₂（TMCS）	162°		金属防腐蚀	［25］
	滴涂法	石英砂（DEDMS）	156°	6°	耐磨耐久	［27］
	滴涂法	高岭土（硬脂酸）	156°	<10°	耐磨耐腐蚀	［28］
	浸涂法	CS和ZnO	154°		金属防腐蚀	［59］
	静电纺丝	ZnO	146.39°		金属防腐蚀	［31］
	静电纺丝	TiO₂/石墨烯	168.3°/161°		光电极	［53］

[1]	GAO Yanjing. Analysis of international research trend of single-atom catalysis technology [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4667-4676.
[2]	TAN Jihuai, YU Min, ZHANG Tongtong, HUANG Nengkun, WANG Ziwen, ZHU Xinbao. Manufacturing of tannin polypropoxy ether carboxylates as efficient and improved migration resistance plasticizers for PVC [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4847-4855.
[3]	SONG Weitao, SONG Huiping, FAN Zhenlian, FAN Biao, XUE Fangbin. Research progress of fly ash in anti-corrosion coatings [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4894-4904.
[4]	LI Zhiyuan, HUANG Yaji, ZHAO Jiaqi, YU Mengzhu, ZHU Zhicheng, CHENG Haoqiang, SHI Hao, WANG Sheng. Characterization of heavy metals during co-pyrolysis of sludge with PVC [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4947-4956.
[5]	MAO Shanjun, WANG Zhe, WANG Yong. Group recognition hydrogenation: From concept to application [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 3917-3922.
[6]	LI Runlei, WANG Ziyan, WANG Zhimiao, LI Fang, XUE Wei, ZHAO Xinqiang, WANG Yanji. Efficient catalytic performance of CuO-CeO₂/TiO₂ for CO oxidation at low-temperature [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4264-4274.
[7]	WANG Xin, WANG Bingbing, YANG Wei, XU Zhiming. Anti-scale and anti-corrosion properties of PDA/PTFE superhydrophobic coating on metal surface [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 4315-4321.
[8]	WU Haibo, WANG Xilun, FANG Yanxiong, JI Hongbing. Progress of the development and application of 3D printing catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 3956-3964.
[9]	CHU Tiantian, LIU Runzhu, DU Gaohua, MA Jiahao, ZHANG Xiao’a, WANG Chengzhong, ZHANG Junying. Preparation and chemical degradability of organoguanidine-catalyzed dehydrogenation type RTV silicone rubbers [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3664-3673.
[10]	YU Junnan, YU Jianfeng, CHENG Yang, QI Yibo, HUA Chunjian, JIANG Yi. Performance prediction of variable-width microfluidic concentration gradient chips by deep learning [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3383-3393.
[11]	SUN Xudong, ZHAO Yuying, LI Shirui, WANG Qi, LI Xiaojian, ZHANG Bo. Textual quantitative analysis on China’s local hydrogen energy development policies [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3478-3488.
[12]	CHEN Xiangli, LI Qianqian, ZHANG Tian, LI Biao, LI Kangkang. Research progress on self-healing oil/water separation membranes [J]. Chemical Industry and Engineering Progress, 2023, 42(7): 3600-3610.
[13]	LIU Zhanjian, FU Yuxin, REN Lina, ZHANG Xiguang, YUAN Zhongtao, YANG Nan, WANG Huaiyuan. New research progress of superhydrophobic coatings in the field of anti-corrosion and anti-scaling [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 2999-3011.
[14]	XU Guobin, LIU Honghao, LI Jie, GUO Jiaqi, WANG Qi. Preparation and properties of ZnO QDs water-based inkjet fluorescent ink [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 3114-3122.
[15]	YANG Jiatian, TANG Jinming, LIANG Zirong, LI Yinhong, HU Huayu, CHEN Yuan. Preparation and application of novel starch-based super absorbent polymer dust suppressant [J]. Chemical Industry and Engineering Progress, 2023, 42(6): 3187-3196.