Application of composite molecular sieve in hydrocarbon isomerization

doi:10.16085/j.issn.1000-6613.2021-1014

Abstract

Abstract:

In recent years, researchers have found that composite molecular sieves have many advantages, such as rich pore structure, good hydrothermal stability and adjustable surface properties, which show higher reactivity and better isomer selectivity than single molecular sieves in hydrocarbon isomerization. The microporous-microporous composite molecular sieves composed of MOR, Y, β, ZSM series molecular sieve, SAPO series molecular sieve and the microporous-mesoporous composite molecular sieves composed of microporous molecular sieve and MCM-41 or SBA-15 mesoporous molecular sieve were reviewed in this paper. The research and development directions of composite molecular sieves for hydroisomerization were prospected, and it is pointed out that the composite molecular sieves for real petroleum fractions isomerization still need more in-depth and systematic researches. Green and efficient synthesis of composite molecular sieves and their activity and selectivity improvement in hydroisomerization through structural design and acid regulation are the focus of future research.

Key words: isomerization, catalyst, hydrogenation, selectivity, composite molecular sieve

摘要：

近年来研究者发现复合分子筛具有孔结构丰富、水热稳定性良好、表面性质可调控等优点，在烃类异构化反应中表现出比单一分子筛更高的反应活性和更好的异构体选择性。本文综述了丝光沸石分子筛（MOR）、Y型分子筛、β分子筛、ZSM系列分子筛、SAPO系列分子筛等两两复合的微孔-微孔复合分子筛和微孔分子筛与MCM-41分子筛、SBA-15分子筛等介孔分子筛复合的微孔-介孔复合分子筛在烷烃异构化、烯烃异构化等反应中的应用研究进展，并对用于烃类异构化复合分子筛的研究与发展方向进行了展望，指出复合分子筛用于真实石油馏分的异构化研究仍需更深入、系统地展开；采用绿色高效的合成方法合成复合分子筛以及探究通过复合分子筛的结构设计和酸性调控，如何进一步提高复合分子筛在烃类异构化反应中的活性和选择性是未来研究的重点。

关键词: 异构化, 催化剂, 加氢, 选择性, 复合分子筛

CLC Number:

TQ519

CHEN Zhiping, WANG Miaomiao, WEI Xiaoyi, ZHOU Wenwu, YANG Zhiyuan, ZHOU Anning. Application of composite molecular sieve in hydrocarbon isomerization[J]. Chemical Industry and Engineering Progress, 2022, 41(5): 2404-2415.

陈治平, 王苗苗, 韦晓艺, 周文武, 杨志远, 周安宁. 复合分子筛在烃类异构化反应中的应用研究进展[J]. 化工进展, 2022, 41(5): 2404-2415.

Figures/Tables 1

References 55

1	LIU Y X, LIU W R, LYU Y C, et al. Intra-crystalline mesoporous SAPO-11 prepared by a grinding synthesis method as FCC promoters to increase iso-paraffin of gasoline[J]. Microporous and Mesoporous Materials, 2020, 305: 110320.
2	刘宇, 谭涓, 刘靖, 等. Pt/ZSM-35催化长链正构生物烷烃加氢裂化/异构化制航空煤油[J]. 化工进展, 2020, 39(12): 5086-5094.
	LIU Yu, TAN Juan, LIU Jing, et al. Production of bio-jet fuel by hydrocracking and hydroisomerization of long-chain normal bio-paraffins over Pt/ZSM-35 catalysts[J]. Chemical Industry and Engineering Progress, 2020, 39(12): 5086-5094.
3	陈治平, 徐建, 石冈, 等. 催化裂化汽油临氢异构化/芳构化改质过程的反应特性[J]. 化工学报, 2014, 65(7): 2751-2760.
	CHEN Zhiping, XU Jian, SHI Gang, et al. Hydroisomerization and aromatization hydro-upgrading behavior of fluid catalytic cracking gasoline[J]. CIESC Journal, 2014, 65(7): 2751-2760.
4	BIKMETOVA L I, SMOLIKOV M D, ZATOLOKINA E V, et al. Supported sulfated zirconia catalysts for isomerization of n-hexane[J]. Procedia Engineering, 2016, 152: 87-93.
5	ZHANG Z, CHENG J, ZHU Y X, et al. Jet fuel range hydrocarbons production through competitive pathways of hydrocracking and isomerization over HPW-Ni/MCM-41 catalyst[J]. Fuel, 2020, 269: 117465.
6	高善彬, 迟克彬, 杨晓东, 等. 正构烷烃在Pt/SAPO-11催化剂上加氢异构反应性能[J]. 化工学报, 2016, 67(12): 5024-5030.
	GAO Shanbin, CHI Kebin, YANG Xiaodong, et al. Performance of n-alkane isomerization over Pt/SAPO-11 catalyst[J]. CIESC Journal, 2016, 67(12): 5024-5030.
7	孟祥彬, 高善彬, 孙发民, 等. 石蜡基原料油加氢异构脱蜡制润滑油基础油催化剂的研制[J]. 石油炼制与化工, 2014, 45(11): 33-37.
	MENG Xiangbin, GAO Shanbin, SUN Famin, et al. Development of hydroisomerization catalyst for lube base oil production from paraffinic feedstocks[J]. Petroleum Processing and Petrochemicals, 2014, 45(11): 33-37.
8	徐会青, 刘全杰. FRIPP异构脱蜡催化剂研发及应用[J]. 当代化工, 2020, 49(9): 1997-2000.
	XU Huiqing, LIU Quanjie. FRIPP isodewaxing catalyst R & D and industrial applications[J]. Contemporary Chemical Industry, 2020, 49(9): 1997-2000.
9	谢彬, 王嘉祎, 刘坤红, 等. 润滑油加氢异构催化剂PHI-01的研发与应用[J]. 石油炼制与化工, 2021, 52(4): 15-20.
	XIE Bin, WANG Jiayi, LIU Kunhong, et al. Development and application of lubricating oil hydroisomerization catalyst PHI-01[J]. Petroleum Processing and Petrochemicals, 2021, 52(4): 15-20.
10	郑仁垟. 金属-分子筛双功能催化剂的结构设计及其烷烃异构研究进展[J]. 化工进展, 2021, 40(7): 3785-3790.
	ZHENG Renyang. Advances in structure design and alkane isomerization performance of metal-zeolite bifunctional catalyst[J]. Chemical Industry and Engineering Progress, 2021, 40(7): 3785-3790.
11	SAKTHIVEL A, SINGH A K. Role of meso/microporous molecular sieve composite materials on various catalytic transformations[M]//Sustainable Catalytic Processes. Amsterdam: Elsevier, 2015: 1-21.
12	杨旭, 段爱军, 赵震, 等. L/W复合分子筛的合成及在催化裂化汽油加氢改质催化剂中的应用[J]. 高等学校化学学报, 2015, 36(2): 336-343.
	YANG Xu, DUAN Aijun, ZHAO Zhen, et al. Synthesis of L/W composite zeolite and its application in FCC gasoline hydro-upgrading catalyst[J]. Chemical Journal of Chinese Universities, 2015, 36(2): 336-343.
13	WEITKAMP J. Isomerization of long-chain n-alkanes on a Pt/CaY zeolite catalyst[J]. Industrial & Engineering Chemistry Product Research and Development, 1982, 21(4): 550-558.
14	ALVAREZ F, RIBEIRO F R, PEROT G, et al. Hydroisomerization and hydrocracking of alkanes: 7. Influence of the balance between acid and hydrogenating functions on the transformation of n-decane on PtHY catalysts[J]. Journal of Catalysis, 1996, 162(2): 179-189.
15	ZHAO Q Q, QIN B, ZHENG J J, et al. Core-shell structured zeolite-zeolite composites comprising Y zeolite cores and nano-‍β zeolite shells: synthesis and application in hydrocracking of VGO oil[J]. Chemical Engineering Journal, 2014, 257: 262-272.
16	杜君, 王艳, 孟双明, 等. Y/Beta双微孔复合分子筛的合成、表征及其催化性能[J]. 石油学报(石油加工), 2010, 26(5): 773-778.
	DU Jun, WANG Yan, MENG Shuangming, et al. Synthesis, characterization and catalytic property of Y/beta micro-microporous composite molecular sieve[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2010, 26(5): 773-778.
17	金昌磊, 马波, 张喜文, 等. 不同分子筛载体制备的Pt催化剂对正辛烷加氢异构反应的催化性能[J]. 石油学报(石油加工), 2008, 24(5): 509-514.
	JIN Changlei, MA Bo, ZHANG Xiwen, et al. Catalytic performance of the catalysts supported on different zeolites in n-octane hydroisomerization[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2008, 24(5): 509-514.
18	秦波, 杜艳泽, 柳伟, 等. 一种Y/Silicalite-1复合分子筛及其制备方法: CN104556094B[P]. 2016-06-22.
	QIN Bo, DU Yanze, LIU Wei, et al. A Y/silicalite-1 composite molecular sieve and its preparation method: CN104556094B[P]. 2016-06-22.
19	张振莉, 周亚松, 李长喜, 等. HZSM-5/Hβ复合分子筛的正辛烷临氢异构化和芳构化性能[J]. 燃料化学学报, 2008, 36(2): 160-165.
	ZHANG Zhenli, ZHOU Yasong, LI Changxi, et al. Hydroisomerization and aromatization of n-octane over HZSM-5/Hβ composite zeolite[J]. Journal of Fuel Chemistry and Technology, 2008, 36(2): 160-165.
20	张健, 董宏光, 邹雄, 等. 用于正构烷烃异构化贵金属催化剂及其制备方法与应用: CN108993575A[P]. 2018-12-14.
	ZHANG Jian, DONG Hongguang, ZOU Xiong, et al. Preparation and application of noble metal catalysts for isomerization of n-alkanes: CN108993575A[P]. 2018-12-14.
21	朱数金, 刘粟侥, 张怀科, 等. 复合方式对SAPO-11/MOR复合分子筛催化剂临氢异构化性能的影响[J]. 石油学报(石油加工), 2015, 31(3): 670-677.
	ZHU Shujin, LIU Suyao, ZHANG Huaike, et al. Influence of composite methods on performance of SAPO-11/MOR composite zeolite catalyst in catalytic hydroisomerization of n-heptane[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2015, 31(3): 670-677.
22	SUN N, WANG H Y, MA Y X, et al. Synthesis of MOR/SAPO-11 composite molecular sieve via seed crystallization for n-alkane hydroisomerization[J]. China Petroleum Processing & Petrochemical Technology, 2019, 21(2): 58-66.
23	孙娜, 王海彦, 马宇翔, 等. 一种以预置MOR晶种制备SAPO-11/MOR复合分子筛的方法: CN106582805B[P]. 2019-09-27.
	SUN Na, WANG Haiyan, MA Yuxiang, et al. A method for preparing SAPO-11/MOR composite molecular sieve with preset MOR seed: CN106582805B[P]. 2019-09-27.
24	孙娜, 王海彦, 马宇翔, 等. MOR@SAPO-11复合分子筛的合成及Pt/MOR@SAPO-11催化剂的加氢异构化性能[J]. 石油学报(石油加工), 2019, 35(6): 1175-1182.
	SUN Na, WANG Haiyan, MA Yuxiang, et al. Synthesis of MOR@ SAPO-11 composite molecular sieve and the hydroisomerization evaluation of Pt/MOR@SAPO-11 catalyst[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2019, 35(6): 1175-1182.
25	林绍杰. 生物烷烃加氢制备液体燃料催化剂的研究[D]. 杭州: 浙江工业大学, 2015.
	LIN Shaojie. Research on the catalysts for preparation of liquid fuels through hydroisomerization and hydrocracking of bio-paraffin[D]. Hangzhou: Zhejiang University of Technology, 2015.
26	孙启文, 孙燕, 滕强. 一种适用于费托合成馏分油的异构降凝催化剂及其制备方法与应用: CN111068771A[P]. 2020-04-28.
	SUN Qiwen, SUN Yan, TENG Qiang. A preparation method and application of heterogeneous pour point depressant catalyst for Fischer-Tropsch synthesis distillate oil: CN111068771A[P]. 2020-04-28.
27	ZHU S J, LIU S Y, ZHANG H K, et al. Investigation of synthesis and hydroisomerization performance of SAPO-11/beta composite molecular sieve[J]. Chinese Journal of Catalysis, 2014, 35(10): 1676-1686.
28	董神功. ZSM-22复合分子筛催化剂的选择加氢裂化/异构化[D]. 大连: 大连理工大学, 2017.
	DONG Shengong. Selective hydrocracking and isomerization of n-alkanes over ZSM-22 composite catalyst[D]. Dalian: Dalian University of Technology, 2017.
29	徐霆, 杜立方, 岑诗雨, 等 . EU-1/ZSM-48 复合分子筛催化剂的制备方法: CN108745408A[P]. 2018-11-06.
	XU Ting, DU Lifang, CEN Shiyu, et al. Preparation method of EU- 1/ZSM-48 composite molecular sieve catalyst: CN108745408A[P]. 2018-11-06.
30	李德宝, 林明桂, 侯博, 等. 一种含有TON/MTT骨架拓扑结构的沸石分子筛及其制备方法: CN107416860A[P]. 2017-12-01.
	LI Debao, LIN Mingjia, HOU Bo, et al. Molecular sieve with TON/MTT skeleton topology its preparation method: CN107416860A[P]. 2017-12-01.
31	宋毅. 新型亚微米沸石催化剂的制备及催化性能评价[D]. 沈阳: 东北大学, 2014.
	SONG Yi. Preparation of new submicrometer-sized zeolite catalysts and evaluation of catalytic performance[D]. Shenyang: Northeastern University, 2014.
32	FAN Y, BAO X J, SHI G, et al. Olefin reduction of FCC gasoline via hydroisomerization aromatization over modified HMOR/HZSM-5/Hβ composite carriers[J]. Applied Catalysis A: General, 2004, 275(1/2): 61-71.
33	甄星. 复合分子筛催化剂的烷烃临氢异构化反应行为研究[D]. 西安: 西安石油大学, 2018.
	ZHEN Xing. Study on the behavior of alkanes hydroisomerization reaction on composite molecular sieve catalysts[D]. Xi’an: Xi’‍an Shiyou University, 2018.
34	TANG W W, ZHANG H, LU Y, et al. Two-step hydrothermal synthesis of β-MCM-41 composite molecular sieves as supports of bifunctional catalysts for hydroisomerization of n-heptane[J]. Journal of Porous Materials, 2016, 23(6): 1489-1493.
35	LIU P, YAO Y, WANG J. Using β-MCM41 composite molecular sieves as supports of bifunctional catalysts for the hydroisomerization of n-heptane[J]. Reaction Kinetics, Mechanisms and Catalysis, 2010, 101(2): 465-475.
36	GAO L, SHI Z Y, ETIM U J, et al. Beta-MCM-41 micro-mesoporous catalysts in the hydroisomerization of n-heptane: definition of an indexed isomerization factor as a performance descriptor[J]. Microporous and Mesoporous Materials, 2019, 277: 17-28.
37	张君涛, 宋菁, 甄星, 等. MCM-41/MOR复合分子筛的制备及其烷烃异构化性能研究[J]. 燃料化学学报, 2017, 45(6): 675-681.
	ZHANG Juntao, SONG Jing, ZHEN Xing, et al. Synthesis of MCM-41/MOR composite molecular sieves and its catalytic properties for isomerization of alkane[J]. Journal of Fuel Chemistry and Technology, 2017, 45(6): 675-681.
38	KONNOV S V, IVANOVA I I, PONOMAREVA O A, et al. Hydroisomerization of n-alkanes over Pt-modified micro/mesoporous materials obtained by mordenite recrystallization[J]. Microporous and Mesoporous Materials, 2012, 164: 222-231.
39	ZHANG Y D, LIU D, LOU B, et al. Hydroisomerization of n-decane over micro/mesoporous Pt-containing bifunctional catalysts: effects of the MCM-41 incorporation with Y zeolite[J]. Fuel, 2018, 226: 204-212.
40	ZHANG Y D, LIU D, MEN Z W, et al. Hydroisomerization of n-dodecane over bi-porous Pt-containing bifunctional catalysts: effects of alkene intermediates’ journey distances within the zeolite micropores[J]. Fuel, 2019, 236: 428-436.
41	刘学军, 王燕娣, 卢美贞, 等 . 一种MCM-41/SAPO-11 复合分子筛负载贵金属催化剂及其制备方法和应用: CN110292947A[P]. 2019-10-01.
	LIU Xuejun, WANG Yandi, LU Meizhen, et al. Preparation and application of a noble metal catalyst supported on MCM- 41/SAPO-11 composite molecular sieve: CN110292947A[P]. 2019-10-01.
42	ELANGOVAN S P, HARTMANN M. Evaluation of Pt/MCM-41//MgAPO-n composite catalysts for isomerization and hydrocracking of n-decane[J]. Journal of Catalysis, 2003, 217(2): 388-395.
43	AZOFRA A, PESQUERA C, GONZÁLEZ F, et al. Hydroisomerization of n-heptane on MCM-41/Al-PILC Pt-catalysts[J]. Studies in Surface Science and Catalysis, 2005, 158: 1445-1452.
44	GAO L, SHI Z Y, ETIM U J, et al. Superior catalytic performance of micro-mesoporous beta-SBA-15 composite with a high indexed isomerization factor in hydroisomerization of n-heptane[J]. Fuel, 2019, 252: 653-665.
45	FEDYNA M, ŚLIWA M, JAROSZEWSKA K, et al. Effect of zeolite amount on the properties of Pt/(AlSBA-15 + Beta zeolite) micro-mesoporous catalysts for the hydroisomerization of n-heptane[J]. Fuel, 2020, 280: 118607.
46	GAO L, ETIM U J, SHI Z Y, et al. Predicting catalytic performance of micro-mesoporous Pt/beta-KIT-6 catalyst in n-heptane hydroisomerization using indexed isomerization factor and experimental verification[J]. Industrial & Engineering Chemistry Research, 2019, 58(13): 5146-5157.
47	PARSAFARD N, PEYROVI M H, RASHIDZADEH M. n-Heptane isomerization on a new kind of micro/mesoporous catalyst: Pt supported on HZSM-5/HMS[J]. Microporous and Mesoporous Materials, 2014, 200: 190-198.
48	JI Dekun, LI Shuyuan, DING Fuchen, et al. Investigation of ZSM-5/MCM-41 composite molecular sieve for reducing olefin content of FCC gasoline[J]. China Petroleum Processing and Petrochemical Technology, 2009, 11(4): 10-17.
49	冀德坤, 李术元, 丁福臣, 等. MCM-22/MCM-41与ZSM-5/MCM-41复合分子筛汽油降烯烃性能的对比分析[J]. 中国石油大学学报(自然科学版), 2010, 34(3): 140-145.
	JI Dekun, LI Shuyuan, DING Fuchen, et al. Comparison and analysis on gasoline olefin reduction performance of MCM-22/MCM-41 and ZSM-5/MCM-41 composite molecular sieves[J]. Journal of China University of Petroleum (Edition of Natural Science), 2010, 34(3): 140-145.
50	冀德坤, 李术元, 丁福臣, 等. ZSM-5/MCM-41复合分子筛汽油降烯烃反应条件考察[J]. 石油炼制与化工, 2011, 42(1): 53-59.
	JI Dekun, LI Shuyuan, DING Fuchen, et al. An investigation in the reaction conditions of gasoline olefin reduction over ZSM-5/MCM-41 composite molecular sieve[J]. Petroleum Processing and Petrochemicals, 2011, 42(1): 53-59.
51	崔生航. 汽油馏分改质催化剂及其反应性能研究[D]. 西安: 西安石油大学, 2016.
	CUI Shenghang. Synthesis and reaction study of gasoline fraction hydro-upgrading catalyst[D]. Xi’an: Xi’an Shiyou University, 2016.
52	高道伟. 基于SBA-15新型催化剂的构筑及其催化性能研究[D]. 北京: 中国石油大学(北京), 2016.
	GAO Daowei. Fabrication and catalytic properties of novel catalysts originated from SBA-15[D]. Beijing: China University of Petroleum (Beijing), 2016.
53	LYU Y P, WANG X L, GAO D W, et al. Hierarchically porous ZSM-5/SBA-15 zeolite: tuning pore structure and acidity for enhanced hydro-upgrading of FCC gasoline[J]. Industrial & Engineering Chemistry Research, 2018, 57(42): 14031-14043.
54	LI T S, DUAN A J, ZHAO Z, et al. Synthesis of ordered hierarchically porous L-SBA-15 material and its hydro-upgrading performance for FCC gasoline[J]. Fuel, 2014, 117: 974-980.
55	杨冬花, 吕爱凝, 余建蓉, 等. 一种T-L复合分子筛及其制备方法: CN105435838B[P]. 2018-01-19.
	YANG Donghua, Aining LYU, YU Jianrong, et al. A T-L composite molecular sieve and its preparation method: CN105435838B[P]. 2018-01-19.

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