Chemical Industry and Engineering Progress ›› 2022, Vol. 41 ›› Issue (4): 1825-1833.DOI: 10.16085/j.issn.1000-6613.2021-0845

• Energy processes and technology • Previous Articles     Next Articles

Research progress in CO2 mineral sequestration technology

HE Minyu1(), LIU Weizao1(), LIU Qingcai1, QIN Zhifeng2   

  1. 1.College of Materials Science and Engineering, Chongqing University, Chongqing 400044, Sichuan, China
    2.School of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China
  • Received:2021-04-21 Revised:2021-06-09 Online:2022-04-25 Published:2022-04-23
  • Contact: LIU Weizao

CO2矿物封存技术研究进展

何民宇1(), 刘维燥1(), 刘清才1, 秦治峰2   

  1. 1.重庆大学材料科学与工程学院,四川 重庆 400044
    2.四川大学化学工程学院,四川 成都 610065
  • 通讯作者: 刘维燥
  • 作者简介:何民宇(1998—),男,硕士研究生,研究方向为工业固废综合利用。E-mail: 1074687858@qq.com
  • 基金资助:
    国家重点研发计划(2016YFB0600904);中国博士后科学基金(2020TQ0392)

Abstract:

At present, CO2 capture and storage technology is the most effective way to achieve CO2 emission reduction. Wherein, CO2 mineral sequestration mainly utilizes the reactions of carbon dioxide with calcium and magnesium silicate minerals to form stable carbonates, and thus can permanently store CO2. The principles and pathways for CO2 mineral carbonation are briefly introduced in this paper. Indirect carbonation receives more attentions due to the moderate reaction condition, higher mineralization efficiency and possibility for recovering valuable byproducts. This paper reviews and compares the carbonation process by using natural minerals and industrial solid wastes as feedstock. It is found that the latter is more conducive to the CO2 mineralization process. This process realizes the disposal of industrial solid wastes while storing CO2, realizing the treatment of waste with waste, which had certain advantages in economy. Based on above, this paper takes blast furnace slag as representative and summarized its research progress in CO2 mineral carbonation. It is pointed out that using recyclable reagents and recovering valuable elements from blast furnace slag can improve the economy of CO2 mineralization. To realize the industrial application of the CO2 mineralization technology, the scale-up experiments, life cycle assessment and developments of new approaches with low energy consumption should be paid more attentions to.

Key words: CO2 mineralization, industrial solid wastes, carbonation, ammonium sulfate, blast furnace slag

摘要:

CO2捕集与封存技术是目前实现碳减排最有效的方法。其中,CO2矿物封存(又称CO2矿化)是利用CO2与含钙镁硅酸盐矿物进行反应使CO2以稳定的碳酸盐形式永久储存起来。本文首先介绍了CO2矿化的基本原理和技术路线,其中间接矿化反应条件较温和、矿化效率更高、得到的产物也更纯,因此对于CO2间接矿化的研究也更广泛。本文综述并对比了天然矿物及工业固废矿化CO2的研究进展,指出工业固废更有利于CO2矿化过程。工业固废矿化CO2过程矿化CO2的同时处理了工业固废,实现以废治废,因此它在经济上也是具有一定优势。在此基础上,本文以高炉渣为代表,介绍了其矿化CO2的详细研究进展,指出采用可循环的助剂、回收高炉渣中有价元素可提升矿化过程经济性。对于CO2矿化过程的放大试验、生命周期的评估及低能耗的新工艺开发将是CO2矿物封存实现工业化的关键。

关键词: CO2矿物封存, 工业固废, 碳酸化, 硫酸铵, 高炉渣

CLC Number: 

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