Preparation of three-dimensional MXene composite materials based on polyaniline modification and its capacitive performance

doi:10.16085/j.issn.1000-6613.2021-0842

Chemical Industry and Engineering Progress ›› 2021, Vol. 40 ›› Issue (11): 6211-6218.DOI: 10.16085/j.issn.1000-6613.2021-0842

• Materials science and technology • Previous Articles Next Articles

Preparation of three-dimensional MXene composite materials based on polyaniline modification and its capacitive performance

LI Rui¹^,²(), XIE Fangxia², ZHU Qiaoxia², CHEN Lu³, JIAN Xuan³()

^1.College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China
^2.College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, Shanxi, China
^3.College of Chemistry and Chemical Engineering, Yan'an University, Yan'an 716000, Shaanxi, China

Received:2021-04-21 Revised:2021-08-20 Online:2021-11-19 Published:2021-11-05
Contact: LI Rui,JIAN Xuan

基于聚苯胺改性构建三维MXene复合材料及其电容性能

李瑞¹^,²(), 谢芳霞², 朱巧霞², 陈露³, 简选³()

^1.太原理工大学环境科学与工程学院，山西太原 030024
^2.太原理工大学化学与化工学院，山西太原 030024
^3.延安大学化学与化工学院，陕西延安 716000

通讯作者: 李瑞,简选
作者简介:李瑞（1990—），男，博士，讲师，研究方向为水分解制氢。E-mail：lirui13233699182@163.com。
基金资助:
国家自然科学基金(22008167);陕西省教育厅科研项目(19JK0962);山西省自然科学基金(201901D211100);山西省高等学校科技创新项目(2019L0138)

Abstract

Abstract:

Three-dimensional MXene/polyaniline composite electrode materials were successfully synthesized through direct electrochemical method. Aniline monomer was induced and electrochemically polymerized by the surface functional groups of MXene nanosheets under external electric field. The surface, structure and composition of the composite electrode material were characterized by SEM, XRD, XPS, FTIR and Raman spectra. The capacitance properties of the composite electrode material were investigated in 1mol/L H₂SO₄. The results indicate that the MXene /PANI composite electrode exhibits excellent electron conduction ability and outstanding electrochemical performance due to the MXene doping. The gravimetric capacitance of the MXene/PANI composite electrodes can reach 417F/g at a scan rate of 10mV/s, and when the scan rate increases to 200mV/s, the electrode can still retain 52% of the original specific capacitance value, which is 31% higher than that of pure PANI electrode. In addition, the composite electrode also exhibits excellent cycling stability, and the capacitance retention can be maintained up to approximately 83.4% after 2000 cycles at a current density of 1.0A/g. This research work can provide design ideas for the construction of 3D MXene composites.

Key words: electrochemistry, composites, polymerization, MXene, polyaniline, capacitive performance

摘要：

通过直接电化学法，本文利用MXene表面官能团的诱导能力，在外加电场的作用下，将苯胺单体与MXene共同修饰在不锈钢电极表面，成功制得具有三维结构的MXene/聚苯胺复合电极材料。采用SEM、XRD、XPS、FTIR和Raman光谱对复合电极材料的表面形貌、物相结构和组成进行了表征，并在1mol/L H₂SO₄中详细研究了该电极材料的电容性能。结果表明，得益于MXene的掺杂，MXene/聚苯胺复合电极表现出较好的电子传导能力和优异的电容性能，在10mV/s的扫描速率下电容可达417F/g，当扫描速率增至200mV/s时，其电容保持率为52%，比纯PANI电极高31%。该复合电极材料具有良好的循环稳定性，在1.0A/g的电流密度下循环2000次后电容保持率可维持在83.4%。此项研究工作可为三维MXene复合材料的构建提供设计思路。

关键词: 电化学, 复合材料, 聚合, MXene, 聚苯胺, 电容性能

CLC Number:

O646

LI Rui, XIE Fangxia, ZHU Qiaoxia, CHEN Lu, JIAN Xuan. Preparation of three-dimensional MXene composite materials based on polyaniline modification and its capacitive performance[J]. Chemical Industry and Engineering Progress, 2021, 40(11): 6211-6218.

李瑞, 谢芳霞, 朱巧霞, 陈露, 简选. 基于聚苯胺改性构建三维MXene复合材料及其电容性能[J]. 化工进展, 2021, 40(11): 6211-6218.

Figures/Tables 7

References 26

1	MACKANIC D G, CHANG T H, HUANG Z J, et al. Stretchable electrochemical energy storage devices[J]. Chemical Society Reviews, 2020, 49(13): 4466-4495.
2	MA R, CHEN Z T, ZHAO D N, et al. Ti₃C₂T_x MXene for electrode materials of supercapacitors[J]. Journal of Materials Chemistry A, 2021, 9(19): 11501-11529.
3	DONG Y, ZHU J Y, LI Q Q, et al. Carbon materials for high mass-loading supercapacitors: filling the gap between new materials and practical applications[J]. Journal of Materials Chemistry A, 2020, 8(42): 21930-21946.
4	YANG G, ZHANG Y M, CAI Y, et al. Advances in nanomaterials for electrochromic devices[J]. Chemical Society Reviews, 2020, 49(23): 8687-8720.
5	ANDO Y, OKUBO M, YAMADA A, et al. Capacitive versus pseudocapacitive storage in MXene[J]. Advanced Functional Materials, 2020, 30(47): 2000820.
6	HU M M, ZHANG H, HU T, et al. Emerging 2D MXenes for supercapacitors: status, challenges and prospects[J]. Chemical Society Reviews, 2020, 49(18): 6666-6693.
7	AHMED A, HOSSAIN M M, ADAK B, et al. Recent advances in 2D MXene integrated smart-textile interfaces for multifunctional applications[J]. Chemistry of Materials, 2020, 32(24): 10296-10320.
8	SHIN H, EOM W, LEE K H, et al. Highly electroconductive and mechanically strong Ti₃C₂T_x MXene fibers using a deformable MXene gel[J]. ACS Nano, 2021, 15(2): 3320-3329.
9	ZHANG C F, PARK S N, SERAL‐ASCASO A, et al. High capacity silicon anodes enabled by MXene viscous aqueous ink[J]. Nature Communications, 2019, 10: 849.
10	XU S K, WEI G D, LI J Z, et al. Binder-free Ti₃C₂T_x MXene electrode film for supercapacitor produced by electrophoretic deposition method[J]. Chemical Engineering Journal, 2017, 317: 1026-1036.
11	GHIDIU M, LUKATSKAYA M R, ZHAO M Q, et al. Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance[J]. Nature, 2014, 516(7529): 78-81.
12	LING Z, REN C E, ZHAO M Q, et al. Flexible and conductive MXene films and nanocomposites with high capacitance[J]. PNAS, 2014, 111(47): 16676-16681.
13	LUKATSKAYA M R, MASHTALIR O, REN C E, et al. Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide[J]. Science, 2013, 341(6153): 1502-1505.
14	SYAMSAI R, KOLLU P, JEONG S K, et al. Synthesis and properties of 2D-titanium carbide MXene sheets towards electrochemical energy storage applications[J]. Ceramics International, 2017, 43(16): 13119-13126.
15	LI H, CHEN R, ALI M, et al. In situ grown MWCNTs/MXenes nanocomposites on carbon cloth for high-performance flexible supercapacitors[J]. Advanced Functional Materials, 2020, 30(47): 2002739.
16	XIA Y, MATHIS T S, ZHAO M Q, et al. Thickness-independent capacitance of vertically aligned liquid-crystalline MXenes[J]. Nature, 2018, 557(7705): 409-412.
17	VAHIDMOHAMMADI A, MONCADA J, CHEN H Z, et al. Thick and freestanding MXene/PANI pseudocapacitive electrodes with ultrahigh specific capacitance[J]. Journal of Materials Chemistry A, 2018, 6(44): 22123-22133.
18	MALESKI K, MOCHALIN V N, GOGOTSI Y. Dispersions of two-dimensional titanium carbide MXene in organic solvents[J]. Chemistry of Materials, 2017, 29(4): 1632-1640.
19	ALHABEB M, MALESKI K, ANASORI B, et al. Guidelines for synthesis and processing of two-dimensional titanium carbide (Ti₃C₂T_x MXene)[J]. Chemistry of Materials, 2017, 29(18): 7633-7644.
20	FENG X M, LI R M, MA Y W, et al. One-step electrochemical synthesis of graphene/polyaniline composite film and its applications[J]. Advanced Functional Materials, 2011, 21(15): 2989-2996.
21	SHIN J G, PARK C S, JUNG E Y, et al. Synthesis of a polyaniline nanoparticle using a solution plasma process with an Ar gas bubble channel[J]. Polymers, 2019, 11(1): 105.
22	QIAN A, HYEON S E, SEO J Y, et al. Capacitance changes associated with cation-transport in free-standing flexible Ti₃C₂T_x (T=O, F, OH) MXene film electrodes[J]. Electrochimica Acta, 2018, 266: 86-93.
23	XU H Z, ZHENG D H, LIU F Q, et al. Synthesis of an MXene/polyaniline composite with excellent electrochemical properties[J]. Journal of Materials Chemistry A, 2020, 8(12): 5853-5858.
24	HU M M, LI Z J, HU T, et al. High-capacitance mechanism for Ti₃C₂T_x MXene by in situ electrochemical Raman spectroscopy investigation[J]. ACS Nano, 2016, 10(12): 11344-11350.
25	WANG H B, ZHANG J F, WU Y P, et al. Surface modified MXene Ti₃C₂multilayers by aryl diazonium salts leading to large-scale delamination[J]. Applied Surface Science, 2016, 384: 287-293.
26	SARYCHEVA A, GOGOTSI Y. Raman spectroscopy analysis of the structure and surface chemistry of Ti₃C₂T_x MXene[J]. Chemistry of Materials, 2020, 32(8): 3480-3488.

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Preparation of three-dimensional MXene composite materials based on polyaniline modification and its capacitive performance

基于聚苯胺改性构建三维MXene复合材料及其电容性能

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