Research advances of synthesis and applications of porous g-C3N4-based photocatalyst

doi:10.16085/j.issn.1000-6613.2021-0288

Abstract

Abstract:

The porous g-C₃N₄-based photocatalysts have broad application prospects due to their unique properties such as large specific surface area, abundant surface reaction active sites and short electron transfer pathway, which can well overcome the disadvantages as compared with the bulk g-C₃N₄ including low specific surface area, fast recombination possibility of photogenerated electron-hole pairs and low utilization of visible light. In the review, the general synthetic strategies applied to prepare porous g-C₃N₄-based photocatalyst, such as hard template method, soft template method, hydrothermal methods, thermal polymerization and supramolecular self-assembly, are briefly introduced. Besides, the potential applications of porous g-C₃N₄-based photocatalyst in photocatalytic water splitting, photocatalytic degradation of organic pollutants, photocatalytic CO₂ reduction and photocatalytic NO_x abatement are discussed in detail. Finally, several comments to the challenges and the development trends of porous g-C₃N₄-based photocatalyst are also prospected.

Key words: porous materials, graphite phases-C₃N₄(g-C₃N₄), synthesis methods, catalysis, hydrogen production, degradation of organic pollutants, CO₂ reduction

摘要：

多孔g-C₃N₄基光催化材料由于具有较高的比表面积、丰富的反应活性位点和较短的电子传递路径等特点，能较好地解决块体g-C₃N₄基材料存在的比表面积小、光生载流子复合快及可见光利用效率低等问题，因而具有广阔的发展前景和应用潜力。本文主要从以下方面进行综述：多孔g-C₃N₄基光催化材料常用的制备方法，包括硬模板法、软模板法、水热合成法、热聚合法、超分子自组装法；多孔g-C₃N₄基材料在光催化领域的应用，包括光解水制氢、光催化降解有机污染物、光催化去除氮氧化物和光催化还原CO₂等；最后指出了当前影响多孔g-C₃N₄基光催化材料发展的关键问题，并对其在光催化领域的应用前景进行了展望。

关键词: 多孔材料, 石墨相氮化碳, 合成, 催化, 制氢, 降解有机污染物, CO₂还原

CLC Number:

WANG Wenxia, LIU Xiaofeng, CHEN Xi, XU Yanhong, MENG Zhenbang, ZHENG Junxia, AN Taicheng. Research advances of synthesis and applications of porous g-C₃N₄-based photocatalyst[J]. Chemical Industry and Engineering Progress, 2022, 41(1): 300-309.

王文霞, 刘小丰, 陈浠, 许艳虹, 蒙振邦, 郑俊霞, 安太成. 多孔g-C₃N₄基光催化材料的制备及应用研究进展[J]. 化工进展, 2022, 41(1): 300-309.

Figures/Tables 8

References 60

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多孔催化剂	催化剂质量/mg	反应溶剂	光源（>420nm）	产氢速率/μmol?g^-1?h^-1	参考文献
P掺杂g-C₃N₄	50	TEOA（体积分数为10%）	300W 氙灯	2020	［20］
Ph-CN-MCA	20	TEOA/H₂PtCl₆?H₂O	300W 氙灯	4455	［24］
3D g-C₃N₄	50	H₂O	300W 氙灯	101.4	［27］
g-C₃N₄-MF_x	50	TEOA（体积分数为20%）	300W 氙灯	3612.6	［31］
O掺杂g-C₃N₄	50	TEOA/H₂PtCl₆?H₂O	300W 氙灯	396	［34］
g-C₃N₄/Ni₂P	50	TEOA	300W 氙灯	474.7	［35］

多孔催化剂	催化剂质量/mg	反应溶剂	光源（>420nm）	产氢速率/μmol?g^-1?h^-1	参考文献
P掺杂g-C₃N₄	50	TEOA（体积分数为10%）	300W 氙灯	2020	［20］
Ph-CN-MCA	20	TEOA/H₂PtCl₆?H₂O	300W 氙灯	4455	［24］
3D g-C₃N₄	50	H₂O	300W 氙灯	101.4	［27］
g-C₃N₄-MF_x	50	TEOA（体积分数为20%）	300W 氙灯	3612.6	［31］
O掺杂g-C₃N₄	50	TEOA/H₂PtCl₆?H₂O	300W 氙灯	396	［34］
g-C₃N₄/Ni₂P	50	TEOA	300W 氙灯	474.7	［35］

多孔催化剂	催化剂质量/mg	有机污染物	光源	降解率	参考文献
g-C₃N₄	40	RhB（5mg/L）	300W 卤钨灯	100%，60min	［36］
g-C₃N₄纳米片	10	MB（1.2×10^-5mol/L）	300W 氙灯	100%，300min	［37］
双氧掺杂g-C₃N₄	50	BA（20mg/L）	300W 氙灯	99%，50min	［40］
石墨烯-碳量子点/g-C₃N₄	30	MO（30mg/L）	300W 氙灯	91.1%，240min	［42］
g-C₃N₄/Ag₃PO₄	50	MB（10mg/L）	300W 氙灯	96%	［43］
Ag@AgCl/g?C₃N₄	25	RhB（10mg/L）	300W 氙灯	100%，30min	［44］
g-C₃N₄/AgBr/rGO	50	TC（20mg/L）	250W 氙灯	79.8%，90min	［45］
Cl掺杂g-C₃N₄	50	TC（20mg/L）	300W 氙灯	92%，120min	［46］
氮化硼量子点/g-C₃N₄	50	OTC-HCl（10mg/L）	300W 氙灯	82%，60min	［47］
g-C₃N₄/Ag₂CrO₄	10	RhB（10mg/L）	300W 氙灯	99.2%，90min	［48］

多孔催化剂	催化剂质量/mg	有机污染物	光源	降解率	参考文献
g-C₃N₄	40	RhB（5mg/L）	300W 卤钨灯	100%，60min	［36］
g-C₃N₄纳米片	10	MB（1.2×10^-5mol/L）	300W 氙灯	100%，300min	［37］
双氧掺杂g-C₃N₄	50	BA（20mg/L）	300W 氙灯	99%，50min	［40］
石墨烯-碳量子点/g-C₃N₄	30	MO（30mg/L）	300W 氙灯	91.1%，240min	［42］
g-C₃N₄/Ag₃PO₄	50	MB（10mg/L）	300W 氙灯	96%	［43］
Ag@AgCl/g?C₃N₄	25	RhB（10mg/L）	300W 氙灯	100%，30min	［44］
g-C₃N₄/AgBr/rGO	50	TC（20mg/L）	250W 氙灯	79.8%，90min	［45］
Cl掺杂g-C₃N₄	50	TC（20mg/L）	300W 氙灯	92%，120min	［46］
氮化硼量子点/g-C₃N₄	50	OTC-HCl（10mg/L）	300W 氙灯	82%，60min	［47］
g-C₃N₄/Ag₂CrO₄	10	RhB（10mg/L）	300W 氙灯	99.2%，90min	［48］

多孔催化剂	催化剂质量/mg	反应溶剂	光源（>420nm）	产物产生速率/μmol?g^-1?h^-1	参考文献
富氮g-C₃N₄	10	H₂O/TEOA/CoCl₂/MeCN	300W 氙灯	103.6	［19］
O掺杂g-C₃N₄	50	H₂O	350W 氙灯	0.88	［54］
3D g-C₃N₄/C	100	H₂O	500W 氙灯	112	［55］
Cu-NPs/g-C₃N₄	50	H₂O	300W 氙灯	10.25	［56］
CsPbBr₃ QDs/g-C₃N₄	8	乙腈/H₂O	300W 氙灯	148.9	［57］
g-C₃N₄/Sn₂S₃-DETA	100	H₂O	300W 氙灯	4.84	［58］
NH₂-UiO-66/g-C₃N₄	10	H₂O/TEOA	300W 氙灯	31.7	［59］

Research advances of synthesis and applications of porous g-C₃N₄-based photocatalyst

多孔g-C₃N₄基光催化材料的制备及应用研究进展

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