Preparation of Co-Bi-B ternary composite and its application in hydrolysis of NaBH4

doi:10.16085/j.issn.1000-6613.2021-0026

Abstract

Abstract:

A new type of Co-Bi-B ternary alloy catalyst was prepared by a liquid phase co-reduction method, which was then characterized by X-ray diffractometer (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), etc. The effects of doping molar ratio and temperature on the catalytic performance of hydrogen generation from the hydrolysis of sodium borohydride were systematically investigated. The experimental results showed that the ternary alloy catalyst obtained by doping Bi had a well-defined crystal structure and the doping of Bi reduced the particle size of the catalyst and alleviated the agglomeration. When the molar ratio of Bi∶Co was 1∶9 and the reduction temperature was 0℃, the as-prepared Co-Bi-B ternary catalysts exhibited the best catalytic performance, and the activation energy of the catalyst calculated by Arrhenius equation was 38.97kJ/mol.

Key words: cobalt-bismuth-boron (Co-Bi-B), composite, hydrogen production, catalyst, doping

摘要：

通过液相共还原法制备了一种新型Co-Bi-B三元复合催化剂材料，并采用X射线衍射仪（XRD）、扫描电子显微镜（SEM）、X射线光电子能谱分析（XPS）等表征手段对材料的结构、形貌和元素分布进行了分析。系统考察了Co-Bi-B不同掺杂摩尔比和不同温度对催化NaBH₄水解制氢速率的影响。结果表明：掺杂Bi得到的三元合金催化剂呈晶体结构，且能够显著减小催化剂的粒径、减轻团聚现象。当化学还原温度为0℃、掺杂摩尔比Bi∶Co=1∶9时，Co-Bi-B三元催化剂展示了最佳的催化性能，并通过阿伦尼乌斯（Arrhenius）方程计算得到该催化剂的活化能为38.97kJ/mol。

关键词: Co-Bi-B, 复合材料, 制氢, 催化剂, 掺杂

CLC Number:

O643.3

CHEN Luyao, DONG Yanmei, XIE Pinhong, LI Fang, LI Qiming. Preparation of Co-Bi-B ternary composite and its application in hydrolysis of NaBH₄[J]. Chemical Industry and Engineering Progress, 2021, 40(9): 4830-4836.

陈露瑶, 董艳梅, 解品红, 李芳, 李其明. Co-Bi-B三元复合材料的制备及其在NaBH₄水解制氢中的应用[J]. 化工进展, 2021, 40(9): 4830-4836.

Figures/Tables 11

References 26

1	MUIR S S, YAO X. Progress in sodium borohydride as a hydrogen storage material: development of hydrolysis catalysts and reaction systems[J]. International Journal of Hydrogen Energy, 2011, 36(10): 5983-5997.
2	陈思安, 彭恩高, 范晶. 固体储氢材料的研究进展[J]. 船电技术, 2019, 39(9): 31-35, 39.
	CHEN S A，PENG E G，FAN J. Research progress of solid-state hydrogen storage materials[J]. Marine Electric & Electronic Engineering, 2009, 39(9): 31-35, 39.
3	马通祥, 高雷章, 胡蒙均, 等. 固体储氢材料研究进展[J]. 功能材料, 2018, 49(4): 4001-4006.
	MA T X, GAO L Z, HU M J, et al. Research progress of solid hydrogen storage materials[J]. Journal of Functional Materials, 2018, 49(4): 4001-4006.
4	杨静怡.储氢材料的研究及其进展[J]. 现代化工, 2019, 39(10): 51-55.
	YANG J Y. Research and progress in hydrogen storage materials[J]. Modern Chemical Industry, 2019, 39(10): 51-55.
5	邵阳阳. 非晶态合金催化剂的制备及其催化硼氢化钠水解制氢性能的研究[D]. 扬州: 扬州大学, 2019.
	SHAO Y Y. Preparation of amorphous alloy catalyst and study on catalytic hydrolysis of sodium borohydride for hydrogen generation[D]. Yangzhou: Yangzhou University, 2019.
6	魏磊, 马麦霞, 付君宇, 等. Raney Ni催化碱性硼氢化钠溶液水解制氢[J]. 化工进展, 2017, 36(12): 4462-4467.
	WEI L, MA M X, FU J Y, et al. Hydrogen production from hydrolysis of alkaline sodium borohydride solution using Raney nickel catalyst[J]. Chemical Industry and Engineering Progress, 2017, 36(12): 4462-4467.
7	安鑫. 硼氢化钠催化水解性能的研究[D]. 西安: 长安大学, 2019.
	AN X. Study on catalytic hydrolysis of sodium borohydride[D]. Xi’an: Chang’an Univeristy, 2019.
8	AMENDOLA S C, SHARP-GOLDMAN S L, JANJUA M S, et al. An ultrasafe hydrogen generator: aqueous, alkaline borohydride solutions and Ru catalyst[J]. Journal of Power Sources, 2000, 85(2): 186-189.
9	EKINCI A, CENGIZ E, KUNCAN M, et al. Hydrolysis of sodium borohydride solutions both in the presence of Ni-B catalyst and in the case of microwave application[J]. International Journal of Hydrogen Energy, 2020, 45(60): 34749-34760.
10	FERNANDES R, PATEL N, MIOTELLO A. Efficient catalytic properties of Co-Ni-P-B catalyst powders for hydrogen generation by hydrolysis of alkaline solution of NaBH₄[J]. International Journal of Hydrogen Energy, 2009, 34(7): 2893-2900.
11	DONG H, YANG H X, AI X P, et al. Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst[J]. International Journal of Hydrogen Energy, 2003, 28(10): 1095-1100.
12	LIANG Z H, LI Q M, LI F, et al. Hydrogen generation from hydrolysis of NaBH₄ based on high stable NiB/NiFe₂O₄ catalyst[J]. International Journal of Hydrogen Energy, 2017, 42(7): 3971-3980.
13	何婷. 镁基复合储氢材料的制备及其吸放氢性能研究[D]. 杭州: 浙江大学, 2020.
	HE T. Study on synthesis and hydrogen on de/absorption properties of Mg-based hydrogen storage materials[D]. Hangzhou: Zhejiang University, 2020.
14	李其明, 李芳. CoB/TiO₂催化剂在硼氢化钠水解制氢中的应用[J]. 无机盐工业, 2013, 45(3): 55-57.
	LI Q M, LI F. Application of CoB/TiO₂ catalyst in hydrogen production from hydrolysis of NaBH₄[J]. Inorganic Chemicals Industry, 2013, 45(3): 55-57.
15	李晓静. 负载钌基催化剂的制备及其催化产氢的性能研究[D]. 南充: 西华师范大学, 2016.
	LI X J. Synthesis and catalytic property of Ru based catalysts for hydrogen evolution[D]. Nanchong: China West Normal University, 2016.
16	王丽娜. 负载型钴基催化剂的制备及其催化硼氢化钠水解制氢的性能[D]. 青岛: 青岛科技大学, 2016.
	WANG L N. Hydrogen generation from catalytic hydrolysis of sodium borohydride solution using supported cobalt-based alloy catalysts[D]. Qingdao: Qingdao University of Science & Technology, 2016.
17	马敬环, 苏彦铭, 刘莹. Co-Pr-B催化剂催化硼氢化钠水解制氢的性能[J]. 天津工业大学学报, 2020, 39(1): 31-36.
	MA J H, SU Y M, LIU Y. Performance of sodium borohydride hydrolysis to hydrogen by catalyst Co-Pr-B[J]. Journal of Tiangong University of Technology, 2020, 39(1): 31-36.
18	陈悦蓉, 靳惠明, 俞亮, 等. Cr掺杂的Co-B非晶态合金的制备及催化硼氢化钠水解制氢[J]. 无机盐工业, 2020, 52(2): 91-96.
	CHEN Y R, JIN H M, YU L, et al. Preparation of amorphous Co-Cr-B and catalytic sodium borohydride hydrolysis for hydrogen generation[J]. Inorganic Chemicals Industry, 2020, 52(2): 91-96.
19	WEI Y, WANG R, MENG L, et al. Hydrogen generation from alkaline NaBH₄ solution using a dandelion-like Co-Mo-B catalyst supported on carbon cloth[J]. International Journal of Hydrogen Energy, 2017, 42(15): 9945-9951.
20	SHEN X, DAI M, GAO M, et al. Solvent effects in the synthesis of CoB catalysts on hydrogen generation from hydrolysis of sodium borohydride[J]. Chinese Journal of Catalysis, 2013, 34(5): 979-985.
21	LI H, LIU J, QIAN J, et al. Preparation of Bi-doped TiO₂ nanoparticles and their visible light photocatalytic performance[J]. Chinese Journal of Catalysis, 2014, 35(9): 1578-1589.
22	MO M, ZHENG M, TANG J S, et al. Highly active Co-B, Co-Mo(W)-B amorphous nanotube catalysts for the selective hydrogenation of cinnamaldehyde[J]. Journal of Materials Science, 2014, 49(2): 877-885.
23	CHEN Y W, LEE D S. Hydrogenation of p-chloronitrobenzene on nanosized modified NiMoB catalysts[J]. Catalysis Surveys from Asia, 2012, 16(4): 198-209.
24	韩敏. 一步法制备硼氢化钠水解制氢Co-基催化剂的研究[D]. 青岛: 青岛科技大学, 2015.
	HAN M. Hydrogen generation from sodium borohydride solution with cobalt catalyst supported on corn stalk activated carbon prepared using a one-step approach[D]. Qingdao: Qingdao University of Science & Technology, 2015.
25	张月. 钴基复合催化剂的制备及其催化性能研究[D]. 青岛: 青岛科技大学, 2018.
	ZHANG Y. Preparation and catalytic performance of cobalt based composite catalyst[D]. Qingdao: Qingdao University of Science & Technology, 2018.
26	梁志花, 李其明, 李芳, 等. ZIF-7负载CoB催化剂的制备及其在制氢中的应用[J]. 应用化工, 2016, 45(10): 1832-1835, 1840.
	LIANG Z H, LI Q M, LI F, et al. The preparation of ZIF-7 supported CoB catalyst and its application in hydrogen genration[J]. Applied Chemical Industry, 2016, 45(10): 1832-1835, 1840.

元素	原子分数/%
B	45.47
Co	48.69
Bi	5.84

元素	原子分数/%
B	45.47
Co	48.69
Bi	5.84

[1]	ZHANG Mingyan, LIU Yan, ZHANG Xueting, LIU Yake, LI Congju, ZHANG Xiuling. Research progress of non-noble metal bifunctional catalysts in zinc-air batteries [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 276-286.
[2]	SHI Yongxing, LIN Gang, SUN Xiaohang, JIANG Weigeng, QIAO Dawei, YAN Binhang. Research progress on active sites in Cu-based catalysts for CO₂ hydrogenation to methanol [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 287-298.
[3]	XIE Luyao, CHEN Songzhe, WANG Laijun, ZHANG Ping. Platinum-based catalysts for SO₂ depolarized electrolysis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 299-309.
[4]	YANG Xiazhen, PENG Yifan, LIU Huazhang, HUO Chao. Regulation of active phase of fused iron catalyst and its catalytic performance of Fischer-Tropsch synthesis [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 310-318.
[5]	HU Xi, WANG Mingshan, LI Enzhi, HUANG Siming, CHEN Junchen, GUO Bingshu, YU Bo, MA Zhiyuan, LI Xing. Research progress on preparation and sodium storage properties of tungsten disulfide composites [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 344-355.
[6]	WANG Lele, YANG Wanrong, YAO Yan, LIU Tao, HE Chuan, LIU Xiao, SU Sheng, KONG Fanhai, ZHU Canghai, XIANG Jun. Influence of spent SCR catalyst blending on the characteristics and deNO _x performance for new SCR catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 489-497.
[7]	DENG Liping, SHI Haoyu, LIU Xiaolong, CHEN Yaoji, YAN Jingying. Non-noble metal modified vanadium titanium-based catalyst for NH₃-SCR denitrification simultaneous control VOCs [J]. Chemical Industry and Engineering Progress, 2023, 42(S1): 542-548.
[8]	CHENG Tao, CUI Ruili, SONG Junnan, ZHANG Tianqi, ZHANG Yunhe, LIANG Shijie, PU Shi. Analysis of impurity deposition and pressure drop increase mechanisms in residue hydrotreating unit [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4616-4627.
[9]	WANG Peng, SHI Huibing, ZHAO Deming, FENG Baolin, CHEN Qian, YANG Da. Recent advances on transition metal catalyzed carbonylation of chlorinated compounds [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4649-4666.
[10]	ZHANG Qi, ZHAO Hong, RONG Junfeng. Research progress of anti-toxicity electrocatalysts for oxygen reduction reaction in PEMFC [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4677-4691.
[11]	GE Quanqian, XU Mai, LIANG Xian, WANG Fengwu. Research progress on the application of MOFs in photoelectrocatalysis [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4692-4705.
[12]	WANG Weitao, BAO Tingyu, JIANG Xulu, HE Zhenhong, WANG Kuan, YANG Yang, LIU Zhaotie. Oxidation of benzene to phenol over aldehyde-ketone resin based metal-free catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4706-4715.
[13]	GE Yafen, SUN Yu, XIAO Peng, LIU Qi, LIU Bo, SUN Chengying, GONG Yanjun. Research progress of zeolite for VOCs removal [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4716-4730.
[14]	LIN Xiaopeng, XIAO Youhua, GUAN Yichen, LU Xiaodong, ZONG Wenjie, FU Shenyuan. Recent progress of flexible electrodes for ion polymer-metal composites (IPMC) [J]. Chemical Industry and Engineering Progress, 2023, 42(9): 4770-4782.
[15]	WU Haibo, WANG Xilun, FANG Yanxiong, JI Hongbing. Progress of the development and application of 3D printing catalyst [J]. Chemical Industry and Engineering Progress, 2023, 42(8): 3956-3964.

Preparation of Co-Bi-B ternary composite and its application in hydrolysis of NaBH₄

Co-Bi-B三元复合材料的制备及其在NaBH₄水解制氢中的应用

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 11

References 26

Related Articles 15

Recommended Articles 0

Metrics

Comments