Improvement on the photoelectrocatalytic performance of tungsten oxide（WO3） thin film and its application prospects

doi:10.16085/j.issn.1000-6613.2019-0785

Abstract

Abstract:

Semiconductor WO₃ possesses a small band gap, good stability, and strong absorption in visible light region. Thus, it exhibits a wide range of applications in photocatalysis and photoelectrocatalysis. However, there are still some problems for single WO₃ thin films, such as high photogenerated electron-hole recombination rate, low photoelectrocatalytic activity and low energy conversion efficiency. In this paper, recent research progress on the photoelectrocatalytic properties of WO₃ thin film is reviewed from two aspects of improvement methods and applications. Regarding the former, methods of construction of ordered nanostructures, ion doping and surface modification were summarized. At the same time, the applications of WO₃ thin films as photoelectrodes in water decomposition for hydrogen production, photoelectrocatalytic reduction of CO₂ and degradation of organic pollutants were concluded. The problems of WO₃ thin films in photoelectrocatalytic process were put forward. It is suggested that the construction of ordered nanoheterojunctions is an effective method to improve the photoelectrocatalytic activity of the WO₃ thin films. The large-scale preparation of WO₃ thin film photoelectrodes, the use of cheap cocatalysts, the stability and corrosion resistance of the photoelectrodes are the difficult problems to be solved in its practical applications.

Key words: tungsten trioxide, film, nanostructure, catalyst, photoelectrocatalysis

摘要：

半导体WO₃具有较小的禁带宽度和良好的稳定性，对可见光具有较强的吸收，在光催化和光电催化领域具有广泛的用途。然而，单一WO₃薄膜仍然存在着光生电子-空穴复合率高、光电催化活性与能量转换效率偏低等问题。本文从WO₃薄膜光电催化性能的改善及应用两个方面对近年来的研究进行了综述。在WO₃薄膜光电催化性能的改善方面，分别从有序纳米结构的构建、离子掺杂与表面修饰进行总结。同时，也归纳总结了WO₃薄膜作为光电极在分解水制氢、光电催化还原CO₂和降解有机污染物等方面的应用，并提出了WO₃薄膜在光电催化过程中存在的问题，指出WO₃有序纳米异质结的构建是提高WO₃薄膜光电催化活性的有效方法。WO₃薄膜光电极的规模制备、廉价助催化剂的使用、光电极的稳定性与耐蚀性是其实际应用过程中需要解决的问题。

关键词: 氧化钨, 膜, 纳米结构, 催化剂, 光电催化

CLC Number:

Q649

Wenhua ZHANG,Liwen DIAN,Haiyan CHEN,Wenhua YE,Xiaofeng HU,Huihu WANG,Ying CHANG,Xinguo MA,Shijie DONG. Improvement on the photoelectrocatalytic performance of tungsten oxide（WO₃） thin film and its application prospects[J]. Chemical Industry and Engineering Progress, 2020, 39(2): 521-532.

张文华,佃丽雯,陈海燕,叶文华,胡晓峰,王辉虎,常鹰,马新国,董仕节. 氧化钨（WO₃）薄膜光电催化性能的改善及应用[J]. 化工进展, 2020, 39(2): 521-532.

References 83

1	LEWIS N S. A prospective on energy and environmental science[J]. Energy & Environmental Science, 2019, 12(2): 343-362.
2	BYRANVAND M M, KIM T, SONG S, et al. P-type CuI islands on TiO₂ electron transport layer for a highly efficient planar perovskite solar cell with negligible hysteresis[J]. Advanced Energy Materials, 2018, 8(5): 1702235.
3	VAIANO V, MATARANGOLO M, MURCIA J J, et al. Enhanced photocatalytic removal of phenol from aqueous solutions using ZnO modified with Ag[J]. Applied Catalysis B: Environmental, 2018, 225: 197-206.
4	JIANG Z F, WAN W M, LI H M, et al. A hierarchical Z-scheme alpha-Fe₂O₃/g-C₃N₄ hybrid for enhanced photocatalytic CO₂ reduction[J]. Advanced Materials, 2018, 30(10): 1706108.
5	ZHOU Y G, ZHANG S, DING Y, et al. Efficient solar energy harvesting and storage through a robust photocatalyst driving reversible redox reactions[J]. Advanced Materials, 2018, 30(31): 1802294.
6	尹莉, 陈德良, 李涛, 等. 贵金属/WO₃复合纳米晶的气敏与光催化研究进展[J]. 化工进展, 2012, 31(1): 133-143.
	YIN L, CHEN D L, LI T, et al. Recent progress in noble metal/WO₃ composite nanostructures for gas-sensing and photocatalytic applications[J]. Chemical Industry and Engineering Progress, 2012, 31(1): 133-143.
7	KIM T H, HASANI A, LE Q V, et al. NO₂ sensing properties of porous Au-incorporated tungsten oxide thin films prepared by solution process[J]. Sensors and Actuators B: Chemical, 2019, 286: 512-520.
8	TSAI T H, LIN C T. Rapid preparation of WO₃ nanorods via microwave-assisted solvothermal synthesis[J]. Synthesis and Reactivity in Inorganic Metal, 2015, 45(11): 1655-1659.
9	SHI Y D, ZHANG Y, TANG K, et al. Designed growth of WO₃/PEDOT core/shell hybrid nanorod arrays with modulated electrochromic properties[J]. Chemical Engineering Journal, 2019, 355: 942-951.
10	YAMAZAKI S, SHIMIZU D, TANI S, et al. Effect of dispersants on photochromic behavior of tungsten oxide nanoparticles in methylcellulose[J]. ACS Applied Materials & Interfaces, 2018, 10(23): 19889-19896.
11	LIANG Y, YANG Y, ZOU C W, et al. 2D ultra-thin WO₃ nanosheets with dominant {002} crystal facets for high-performance xylene sensing and methyl orange photocatalytic degradation[J]. Journal of Alloys and Compounds, 2019, 783: 848-854.
12	HUANG Y, LI Y, ZHANG G Y, et al. Simple synthesis of 1D, 2D and 3D WO₃ nanostructures on stainless steel substrate for high-performance supercapacitors[J]. Journal of Alloys and Compounds, 2019, 778: 603-611.
13	GHESHIAGHI M G, SEIFZADEH D, SHOGHI P, et al. Electroless Ni-P/nano-WO₃ coating and its mechanical and corrosion protection properties[J]. Journal of Alloys and Compounds, 2018, 769: 149-160.
14	ZENG Q Y, GAO Y W, LAI L, et al. Highly improving photoelectrocatalytic efficiency and stability of WO₃ photoanodes by facile in situ growth of TiO₂ branch overlayers[J]. Nanoscale, 2018, 10(28): 13393-13401.
15	ROGER I, SHIPMAN M A, SYMES M D. Earth abundant catalysts for electrochemical and photoelectrochemical water splitting[J]. Nature Reviews Chemistry, 2017, 1: 1-13.
16	SOLTANI T, TAYYEBI A, LEE B K, Sonochemical driven ultrafast facile synthesis of WO₃ nanoplates with controllable morphology and oxygen vacancies for efficient photoelectrochemical water splitting[J]. Ultrasonics Sonochemistry,2019, 50: 230-238.
17	YANG Y H, XIE R R, LI H, et al. Photoelectrocatalytic reduction of CO₂ into formic acid using WO_3-_x/TiO₂ film as novel photoanode[J]. Transaction of Nonferrous Metals Society of China, 2016, 26(9): 2390-2396.
18	HUNGE Y M, YADAV A A, MAHADIK M A, et al. A highly efficient visible-light responsive sprayed WO₃/FTO photoanode for photoelectrocatalytic degradation of brilliant blue[J]. Journal of the Taiwan Institute of Chemical Engineers, 2018, 85: 273-281.
19	ZHAN F Q, XIE R R, LI W Z, et al. In situ synthesis of g-C₃N₄/WO₃ heterojunction plates array films with enhanced photoelectrochemical performance[J]. RSC Advances, 2015, 5(85): 69753-69760.
20	ZHENG F, GUO M, ZHANG M. Hydrothermal preparation and optical properties of orientation-controlled WO₃ nanorod arrays on ITO substrates[J]. Crystengcomm, 2013, 15(2): 277-284.
21	LU H, YAN Y, ZHANG M, et al. The effects of adjusting pulse anodization parameters on the surface morphology and properties of a WO₃ photoanode for photoelectrochemical water splitting[J]. Journal of Solid State Electrochemistry, 2018, 22(7): 2169-2181.
22	FERNANDEZ-DOMENE R M, SANCHEZ-TOVAR R, LUCAS-GRANADOS B, et al. Visible light photoelectrodegradation of diuron on WO₃ nanostructures[J]. Journal of Environmental Management, 2018, 226: 249-255.
23	DONG Z Z, CASSANDRA D E, KEA B H. Investigating oxidation growth routes in the flame synthesis of tungsten-oxide nanowires from tungsten substrates[J]. Combustion and Flame, 2018, 195: 311-321.
24	XU S, FU D G, SONG K, et al. One dimensional WO₃/BiVO₄ heterojunction photoanodes for efficient photoelectrochemical water splitting[J]. Chemical Engineering Journal, 2018, 349: 368-375.
25	MA Z M, HOU H L, SONG K, et al. Ternary WO₃/porous-BiVO₄/FeOOH hierarchical architectures: towards highly efficient photoelectrochemical performance[J]. Chemelectrochem, 2018, 5(23): 3660-3667.
26	GEORGIEVA J, SOTIROPOULOS S, VALOVA E, et al. Pt doped TiO₂/WO₃ bilayer catalysts on graphite substrates with enhanced photoelectrocatalytic activity for methanol oxidation under visible light[J]. Journal of Photochemistry and Photobiology A: Chemistry, 2017, 346: 70-76.
27	KONG Y, SUN H, FAN W, et al. Enhanced photoelectrochemical performance of tungsten oxide film by bifunctional Au nanoparticles[J]. RSC Advances, 2017, 7(25): 15201-15210.
28	LI D, TAKEUCHI R, CHANDRA D, et al. Prominent performance for visible-light-driven water oxidation on an in situ N₂-intercalated WO₃ nanorod photoanode synthesized by a dual functional structure directing agent[J]. Chemsuschem, 2018, 11(7): 1151-1156.
29	CORIDAN R H, SHANER M, WIGGENHORM C, et al. Electrical and photoelectrochemical properties of WO₃/Si tandem photoelectrodes[J]. Journal of Physical Chemistry C, 2013, 117(14): 6949-6957.
30	LI N X, TENG H C, ZHANG L, et al. Synthesis of Mo-doped WO₃ nanosheets with enhanced visible light-driven photocatalytic properties[J]. RSC Advances, 2015, 5(115)：95394-95400.
31	KALANUR S S, HWANG Y J, CHAE S Y, et al. Facile growth of aligned WO₃ nanorods on FTO substrate for enhanced photoanodic water oxidation activity[J]. Journal of Materials Chemistry A, 2013, 1(10): 3479-3488.
32	WANG P, YANG L, DAI B, et al. Nanoplate-like tungsten trioxide (hydrate) films prepared by crystal-seed-assisted hydrothermal reaction[J]. International Journal of Modern Physics B, 2017, 31: 1744072.
33	REYES-GIL K R, WIGGENHORN C, BRUNSCHWIG B S, et al. Comparison between the quantum yields of compact and porous WO₃ photoanodes[J]. Journal of Physical Chemistry C, 2013, 117(29): 14947-14957.
34	WANG F G, DI VALENTIN C, PACCHIONI G. Doping of WO₃ for photocatalytic water splitting: hints from density functional theory[J]. Journal of Physical Chemistry C, 2012, 116(16): 8901-8909.
35	LIU Y Y, LI Y, LI W Z, et al. Photoelectrochemical properties and photocatalytic activity of nitrogen-doped nanoporous WO₃ photoelectrodes under visible light[J]. Applied Surface Science, 2012, 258(12): 5038-5045.
36	COLE B, MARSEN B, MILLER E, et al. Evaluation of nitrogen doping of tungsten oxide for photoelectrochemical water splitting[J]. Journal of Physical Chemistry C, 2008, 112(13): 5213-5220.
37	LI D, CHANDRA D, TAKEUCHI R, et al. Dual-functional surfactant-templated strategy for synthesis of an in-situ N₂-intercalated mesoporous WO₃ photoanode for efficient visible light driven water oxidation[J]. Chemistry-A European Journal, 2017, 23(27): 6596-6604.
38	SHEIN I R, IVANOVSKII A L. Ab initio probing of the electronic band structure and Fermi surface of fluorine-doped WO₃, as a novel low-Tc. superconductor[J]. Jetp Letters, 2012, 95(2): 66-69.
39	YANG Y, JIN G, LI H. Photoelectrochemical properties and photocatalytic activity of fluorine-doped plate-like WO₃ from hydrothermal radio-frequency (RF) sputtered tungsten thin films[J]. Nano, 2017, 12(4): 1750041.
40	LI D, HUANG W Q, XIE Z, et al. Mechanism of enhanced photocatalytic activities on tungsten trioxide doped with sulfur: dopant-type effects[J]. Modern Physics Letters B, 2016, 30(27): 1650340.
41	ALEXANDER J E, KLAVETTER K C, LIN J F, et al. Improved visible light harvesting of WO₃ by incorporation of sulfur or iodine: a tale of two Impurities[J]. Chemistry of Materials, 2014, 26(4): 1670-1677.
42	BARCZUK P J, KROLIKOWSKA A, LEWERA A, et al. Structural and photoelectrochemical investigation of boron-modified nanostructured tungsten trioxide films[J]. Electrochimica Acta, 2013, 104(8): 282-288.
43	ZHANG T, ZHU Z, CHEN H, et al. Iron-doping-enhanced photoelectrochemical water splitting performance of nanostructured WO₃: a combined experimental and theoretical study[J]. Nanoscale, 2015, 7(7): 2933-2940.
44	SONG K, MA Z, YANG W, et al. Electrospinning WO₃ nanofibers with tunable Fe-doping levels towards efficient photoelectrochemical water splitting[J]. Journal of Materials Science: Materials in Electronics, 2018, 29(10): 8338-8346.
45	XIAO Y H, XU C Q, ZHANG W D. Facile synthesis of Ni-doped WO₃ nanoplate arrays for effective photoelectrochemical water splitting[J]. Journal of Solid State Electrochemistry, 2017, 21(11): 3355-3364.
46	KALANUR S S, SEO H. Influence of molybdenum doping on the structural, optical and electronic properties of WO₃ for improved solar water splitting[J]. Journal of Colloid and Interface Science, 2018, 509: 440-447.
47	KALANUR S S, SEO H. Aligned nanotriangles of tantalum doped tungsten oxide for improved photoelectrochemical water splitting[J]. Journal of Alloys and Compounds, 2019, 785: 1097-1105.
48	LIU Y, LI J, LI W, et al. Enhancement of the photoelectrochemical performance of WO₃ vertical arrays film for solar water splitting by gadolinium doping[J]. Journal of Physical Chemistry C, 2015, 119(27): 14834-14842.
49	姜子龙. Co-Pi/WO₃纳米片光电极的制备及其光电协同降解苯酚[J]. 化工技术与开发, 2017, 46(5): 43-46.
	JIANG Z L. Synthesis of Co-Pi/WO₃ nanosheet photoanode and its photoelectrocatalytic degradation of phenol[J]. Technology Development of Chemical Industry, 2017, 46(5): 43-46.
50	ZHANG H W, WANG Y Y, ZHU X G, et al. Bilayer Au nanoparticle-decorated WO₃ porous thin films: on-chip fabrication and enhanced NO₂ gas sensing performances with high selectivity[J]. Sensors and Actuators B: Chemical, 2019, 280: 192-200.
51	MIU D, BIRJEGA R, VIESPE C. Surface acousticwave hydrogen sensors based on nanostructured Pd/WO₃ bilayers[J]. Sensors, 2018, 18(11): 3636.
52	BOSE R J, IllYASUKUTTY N, TAN K S, et al. Preparation and characterization of Pt loaded WO₃ films suitable for gas sensing applications[J]. Applied Surface Science, 2018, 440: 320-330.
53	COSTA M J S, COSTA G S, LIMA A E B, et al. Investigation of charge recombination lifetime in γ-WO₃ films modified with Ag⁰and Pt⁰ nanoparticles and its influence on photocurrent density[J]. Ionics, 2018, 24: 3291-3297.
54	RAMKUMAR S, RAJARAJAN G. Enhanced visible light photocatalytic activity of pristine and silver (Ag) doped WO₃ nanostructured thin films[J]. Journal of Materials Science: Materials in Electronics, 2016, 27(11): 12185-12192.
55	LEE W J, SHINDE P S, GO G H, et al. Ag grid induced photocurrent enhancement in WO₃ photoanodes and their scale-up performance toward photoelectrochemical H₂ generation[J]. International Journal of Hydrogen Energy, 2011, 36(9): 5262-5270.
56	YAO M N, JIA X, LIU Y, et al. Surface plasmon resonance enhanced polymer solar cells by thermally evaporating Au into buffer layer[J]. ACS Applied Materials & Interfaces, 2015, 7(33): 18866-18871.
57	KIM H N, MINGGU L J, JAAFAR N A, et al. Enhanced plasmonic photoelectrochemical response of Au sandwiched WO₃ photoanodes[J]. Solar Energy Materials and Solar Cells, 2017, 172: 361-367.
58	LEE B R, LEE M G, PARK H, et al. All-solution-processed WO₃/BiVO₄ core-shell nanorod arrays for highly stable photoanodes[J]. ACS Applied Materials & Interfaces, 2019, 11(22): 20004-20012.
59	ZHAO W F, WANG X W, MA L Z, et al. WO₃/p-type-GR layered materials for promoted photocatalytic antibiotic degradation and device for mechanism insight[J]. Nanoscale Research Letters, 2019, 14: 146.
60	MA Z Z, SONG K, WANG L, et al. WO₃/BiVO₄ type-II heterojunction arrays decorated with oxygen-deficient ZnO passivation layer: a highly efficient and stable photoanode[J]. ACS Applied Materials & Interfaces, 2019, 11(1): 889-897.
61	HUANG W C, WANG J X, BIAN L, et al. Oxygen vacancy induces self-doping effect and metalloid LSPR in non-stoichiometric tungsten suboxide synergistically contributing to the enhanced photoelectrocatalytic performance of WO_3-_x/TiO_2-_x heterojunction[J]. Physical Chemistry Chemical Physics, 2018, 20(25): 17268-17278.
62	XIE T, ZHENG T, WANG R L, et al. A promising CuO_x/WO₃p-n heterojunction thin-film photocathode fabricated by magnetron reactive sputtering[J]. International Journal of Hydrogen Energy, 2019, 44(8): 4062-4071.
63	HU Z F, XU M K, SHEN Z R, et al. A nanostructured chromium (Ⅲ) oxide/tungsten (Ⅵ) oxide p-n junction photoanode toward enhanced efficiency for water oxidation[J]. Journal of Materials Chemistry A, 2015, 3(26): 14046-14053.
64	RONG F, WANG Q Y, LU Q F, et al. Rational fabrication of hierarchical Z-scheme WO₃/Bi₂WO₆ nanotubes for superior photoelectrocatalytic reaction[J]. Chemistryselect, 2019, 4(9): 2676-2684.
65	WANG C H, QIN D D, SHAN D L, et al. Assembly of g-C₃N₄-based type Ⅱ and Z-scheme heterojunction anodes with improved charge separation for photoelerojuncion water oxidation[J]. Physical Chemistry Chemical Physics, 2017, 19(6): 4507-4515.
66	KEVIN S. Metal oxide photoelectrodes for solar fuel production, surface traps, and catalysis[J]. Journal of Physical Chemistry Letters, 2013, 4(10): 1624-1633.
67	HISATOMI T, KUBOTA J, DOMEN K. Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting[J]. Chemical Society Reviews, 2014, 43(22): 7520-7535.
68	CHEN X P, ZHANG Z X, CHI L N, et al. Recent advances in visible-light-driven photoelectrochemical water splitting: catalyst nanostructures and reaction systems[J]. Nano-Micro Letters, 2016, 8(1): 1-12.
69	苏进展, 李明涛, 郭烈锦. 超声喷雾热分解WO₃薄膜的光电化学制氢研究[J]. 西安交通大学学报, 2008, 42(5): 617-621.
	SU J Z, LI M T, GUO L J. Characterization of ultrasonic spray pyrolysis deposited WO₃ thin film for Photoelectrochemical splitting of water[J]. Journal of Xi'an Jiaotong University, 2008, 42(5): 617-621.
70	SU J Z, GUO L J, BAO N Z, et al. Nanostructured WO₃/BiVO₄ heterojunction films for efficient photoelectrochemical water splitting[J]. Nano Letters, 2011, 11(5): 1928-1933.
71	TAYYEBEH S, AHMAD T, HYEONSEON H, et al. A novel growth control of nanoplates WO₃ photoanodes with dual oxygen and tungsten vacancies for efficient photoelectrochemical water splitting performance[J]. Solar Energy Materials and Solar Cells, 2019, 191: 39-49.
72	FAN X L, WANG T, XUE H R, et al. Synthesis of tungsten trioxide/hematite core-shell nanoarrays for efficient photoelectrochemical water splitting[J]. Chemelectrochem, 2019, 6(2): 543-551.
73	SHAO M F, NING F Y, WEI M, et al. Hierarchical nanowire arrays based on ZnO core-layered double hydroxide shell for largely enhanced photoelectrochemical water splitting[J]. Advanced Functional Materials, 2014, 24(5): 580-586.
74	CHEMELEWSKI W D, LEE H C, LIN J F, et al. Amorphous FeOOH oxygen evolution reaction catalyst for photoelectrochemical water splitting[J]. Journal of the American Chemical Society, 2014, 136(7): 2843-2850.
75	王冰, 赵美明, 周勇, 等. 光催化还原二氧化碳制备太阳燃料研究进展及挑战[J]. 中国科学: 技术科学, 2017(3): 70-80.
	WANG B, ZHAO M M, ZHOU Y, et al. Recent progress and challenges in research of photocatalytic reduction of CO₂ to solar fuels[J]. Scientia Sinica: Techologica, 2017(3): 70-80.
76	CHANG X X, WANG T G, GONG J L. CO₂ photo-reduction: insights into CO₂activation and reaction on surfaces of photocatalysts[J]. Energy & Environmental Science, 2016, 9(7): 2177-2196.
77	ZHANG N, LONG R, GAO C, et al. Recent progress on advanced design for photoelectrochemical reduction of CO₂ to fuels[J]. Science China Materials, 2018, 61(6): 771-805.
78	LIU W H, YANG Y H, ZHAN F Q, et al. Ultrafast fabrication of nanostructure WO₃ photoanodes by hybrid microwave annealing with enhanced photoelectrochemical and photoelectrocatalytic activities[J]. International Journal of Hydrogen Energy, 2018, 43(18): 8770-8778.
79	ZHAN F Q, LIU W H, LI W Z, et al. Boric acid assisted synthesis of WO₃ nanostructures with highly reactive (002) facet and enhanced photoelectrocatalytic activity[J]. Journal of Materials Science-Materials in Electronics, 2017, 28(18): 13836-13845.
80	YANG Y H, ZHAN F Q, LI H, et al. In situ Sn-doped WO₃ films with enhanced photoelectrochemical performance for reducing CO₂ into formic acid[J]. Journal of Solid State Electrochemistry, 2017, 21(8): 2231-2240.
81	MOHITE S V, GANBAVLE V V, RAJPURE K Y. Solar photoelectrocatalytic activities of rhodamine-B using sprayed WO₃ photoelectrode[J]. Journal of Alloys and Compounds, 2016, 655: 106-113.
82	HUNGE Y M, YADAV A A, MAHADIK M A, et al. A highly efficient visible-light responsive sprayed WO₃/FTO photoanode for photoelectrocatalytic degradation of brilliant blue[J]. Journal of the Taiwan Institute of Chemical Engineers, 2018, 85: 273-281.
83	WEN J, LIU C J, DU Y, et al. Enhanced photocatalytic degradation of methyl orange by CdS quantum dots sensitized platelike WO₃ photoelectrodes[J]. Journal of Central South University, 2015, 22(12): 4551-4559.

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Improvement on the photoelectrocatalytic performance of tungsten oxide（WO₃） thin film and its application prospects

氧化钨（WO₃）薄膜光电催化性能的改善及应用

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