Chemical Industry and Engineering Progress ›› 2019, Vol. 38 ›› Issue (08): 3881-3888.DOI: 10.16085/j.issn.1000-6613.2018-2086
• Resources and environmental engineering • Previous Articles Next Articles
Fan ZHANG(),Yufeng DUAN(),Shuai LIU,Jincheng LU,Shaojun REN,Hongqi WEI,Jun WANG
Received:
2018-10-22
Online:
2019-08-05
Published:
2019-08-05
Contact:
Yufeng DUAN
通讯作者:
段钰锋
作者简介:
张帆(1994—),男,硕士研究生,研究方向为大气污染物控制。E-mail:基金资助:
CLC Number:
Fan ZHANG,Yufeng DUAN,Shuai LIU,Jincheng LU,Shaojun REN,Hongqi WEI,Jun WANG. Mercury removal performance of bromine-modified coconut shell activated carbon in real flue gas[J]. Chemical Industry and Engineering Progress, 2019, 38(08): 3881-3888.
张帆,段钰锋,柳帅,卢锦程,任少君,韦红旗,王军. 溴元素改性椰壳活性炭对实际燃煤烟气的脱汞性能[J]. 化工进展, 2019, 38(08): 3881-3888.
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URL: https://hgjz.cip.com.cn/EN/10.16085/j.issn.1000-6613.2018-2086
序号 | 喷射量/kg·h-1 | 烟气温度/℃ | 停留时间/s | 氨氮比 | SO2/μL·L-1 | NO/μL·L-1 | O2体积分数/% |
---|---|---|---|---|---|---|---|
1 | 0.3 | 170 | 3 | 0.8 | 678 | 335 | 9 |
2 | 0.5 | 170 | 3 | 0.8 | 633 | 311 | 7.8 |
3 | 0.7 | 170 | 3 | 0.8 | 719 | 351 | 10.07 |
序号 | 喷射量/kg·h-1 | 烟气温度/℃ | 停留时间/s | 氨氮比 | SO2/μL·L-1 | NO/μL·L-1 | O2体积分数/% |
---|---|---|---|---|---|---|---|
1 | 0.3 | 170 | 3 | 0.8 | 678 | 335 | 9 |
2 | 0.5 | 170 | 3 | 0.8 | 633 | 311 | 7.8 |
3 | 0.7 | 170 | 3 | 0.8 | 719 | 351 | 10.07 |
样品 | BET比表面积/m2·g-1 | 微孔容积/cm3·g-1 | 总孔容积/cm3·g-1 | 微孔率/% | 平均孔径/nm |
---|---|---|---|---|---|
YAC | 761 | 0.30 | 0.39 | 75.2 | 2.07 |
YAC-Br | 769 | 0.31 | 0.40 | 76.1 | 2.09 |
样品 | BET比表面积/m2·g-1 | 微孔容积/cm3·g-1 | 总孔容积/cm3·g-1 | 微孔率/% | 平均孔径/nm |
---|---|---|---|---|---|
YAC | 761 | 0.30 | 0.39 | 75.2 | 2.07 |
YAC-Br | 769 | 0.31 | 0.40 | 76.1 | 2.09 |
样品 | C | O | Si | Na | Mg | Al | Cl | Br |
---|---|---|---|---|---|---|---|---|
YAC | 73.19 | 21.73 | 1.84 | 0.50 | 0.29 | 0.42 | 0.29 | — |
YAC-Br | 75.79 | 20.19 | 1.20 | 0.23 | 0.23 | 0.46 | 0.22 | 0.011 |
样品 | C | O | Si | Na | Mg | Al | Cl | Br |
---|---|---|---|---|---|---|---|---|
YAC | 73.19 | 21.73 | 1.84 | 0.50 | 0.29 | 0.42 | 0.29 | — |
YAC-Br | 75.79 | 20.19 | 1.20 | 0.23 | 0.23 | 0.46 | 0.22 | 0.011 |
工业分析/% | 元素分析/% | ||||||||
---|---|---|---|---|---|---|---|---|---|
Mar | Aar | Var | FCar | Car | Har | Oar | Nar | Sar | Clar |
4.27 | 25.73 | 27.75 | 42.83 | 56.03 | 3.63 | 8.06 | 0.83 | 1.45 | 0.05 |
工业分析/% | 元素分析/% | ||||||||
---|---|---|---|---|---|---|---|---|---|
Mar | Aar | Var | FCar | Car | Har | Oar | Nar | Sar | Clar |
4.27 | 25.73 | 27.75 | 42.83 | 56.03 | 3.63 | 8.06 | 0.83 | 1.45 | 0.05 |
取样点 | 汞形态 | YAC-Br-0.3 | YAC-Br-0.5 | YAC-Br-0.7 |
---|---|---|---|---|
输入汞 | 入炉煤/mg·h-1 | 3.557 | 2.538 | 3.066 |
ACI前 | 底渣汞/mg·h-1 | 0.005 | 0.006 | 0.003 |
气相元素汞/mg·h-1 | 0.529 | 0.297 | 0.332 | |
气相氧化汞/mg·h-1 | 1.030 | 0.996 | 1.501 | |
颗粒汞/mg·h-1 | 1.998 | 1.538 | 1.995 | |
平衡率/% | 100.141 | 111.781 | 124.951 | |
ACI后 | 底渣汞/mg·h-1 | 0.005 | 0.006 | 0.003 |
气相元素汞/mg·h-1 | 0.081 | 0.039 | 0.133 | |
气相氧化汞/mg·h-1 | 0.559 | 0.360 | 0.246 | |
颗粒汞/mg·h-1 | 2.916 | 2.852 | 2.974 | |
平衡率/% | 100.112 | 128.329 | 109.459 |
取样点 | 汞形态 | YAC-Br-0.3 | YAC-Br-0.5 | YAC-Br-0.7 |
---|---|---|---|---|
输入汞 | 入炉煤/mg·h-1 | 3.557 | 2.538 | 3.066 |
ACI前 | 底渣汞/mg·h-1 | 0.005 | 0.006 | 0.003 |
气相元素汞/mg·h-1 | 0.529 | 0.297 | 0.332 | |
气相氧化汞/mg·h-1 | 1.030 | 0.996 | 1.501 | |
颗粒汞/mg·h-1 | 1.998 | 1.538 | 1.995 | |
平衡率/% | 100.141 | 111.781 | 124.951 | |
ACI后 | 底渣汞/mg·h-1 | 0.005 | 0.006 | 0.003 |
气相元素汞/mg·h-1 | 0.081 | 0.039 | 0.133 | |
气相氧化汞/mg·h-1 | 0.559 | 0.360 | 0.246 | |
颗粒汞/mg·h-1 | 2.916 | 2.852 | 2.974 | |
平衡率/% | 100.112 | 128.329 | 109.459 |
吸附剂喷射量/kg·h-1 | ACI前/% | ACI后/% | 脱汞效率/% | ||||
---|---|---|---|---|---|---|---|
元素汞 | 二价汞 | 元素汞 | 二价汞 | 元素汞 | 二价汞 | 总效率 | |
0.3 | 14.85 | 28.92 | 2.28 | 15.7 | 84.65 | 45.71 | 58.92 |
0.5 | 10.47 | 35.1 | 1.2 | 11.5 | 88.54 | 67.24 | 72.13 |
0.7 | 8.67 | 39.18 | 3.97 | 7.33 | 54.21 | 81.29 | 76.38 |
吸附剂喷射量/kg·h-1 | ACI前/% | ACI后/% | 脱汞效率/% | ||||
---|---|---|---|---|---|---|---|
元素汞 | 二价汞 | 元素汞 | 二价汞 | 元素汞 | 二价汞 | 总效率 | |
0.3 | 14.85 | 28.92 | 2.28 | 15.7 | 84.65 | 45.71 | 58.92 |
0.5 | 10.47 | 35.1 | 1.2 | 11.5 | 88.54 | 67.24 | 72.13 |
0.7 | 8.67 | 39.18 | 3.97 | 7.33 | 54.21 | 81.29 | 76.38 |
吸附剂 | 脱汞率/% | 脱汞成本/CNY·g-1 |
---|---|---|
YAC-Br | 58.92~76.38 | 429.39~1076.02 |
美国商用活性炭 | 50~90 | 454~2481.22 |
吸附剂 | 脱汞率/% | 脱汞成本/CNY·g-1 |
---|---|---|
YAC-Br | 58.92~76.38 | 429.39~1076.02 |
美国商用活性炭 | 50~90 | 454~2481.22 |
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