Recent progress in research and application of DBBF additive in preparation and combustion process

doi:10.16085/j.issn.1000-6613.2017.04.013

Abstract

Abstract: The screening and application of densified biomass briquetting fuel(DBBF) additive is of great importance for the large-scale preparation and efficient combustion of DBBF. At present,the relevant literature reviews are more concentrated on the DBBF,its preparation,and combustion equipment. Based on emissions management and efficient combustion,DBBF modification,fuel additives preparation,and functional classification and mechanism,this paper summarized the research progress of DBBF additives for adhesives,anti-corrosion additives,and accelerant. DBBF binders have high selectivity and low price,but the mechanical strength of the fuel needs to be improved. DBBF additives for anti-corrosion and anti-settling are abundant,but their work efficiencies are low. There were few DBBF accelerants.Their combustion mechanism is not clear. And there is no unified standards for research and development. The accelerantadditive can effectively improve the combustion performance of DBBF. Finally,the principles of selecting DBBF common additives and the future research directions in the development of new DBBF additives are clearly presented.

Key words: bio fuel, additive, bond, corrosion, combustion

摘要： 生物质成型燃料（densified biomass briquetting fuel，DBBF）添加剂的筛选和应用对于DBBF的规模化制备和高效燃烧均具有重要意义。目前相关文献综述较多集中在DBBF和其制备、燃烧设备方面。本文基于尾气排放管理和高效燃烧，围绕DBBF的提质改性，针对其在制备和燃烧环节使用的添加剂，从功能分类和作用机理的角度出发，综述了黏结剂、防腐降沉添加剂、助燃剂三大类DBBF添加剂的研究进展。相比较，DBBF黏结剂种类可选择性高、廉价易得，但其对于燃料的机械强度的改善有待提高；DBBF防腐降沉添加剂来源广泛，但工作效率低，工业运用效果有待提升；DBBF助燃剂虽然种类较少、机理尚不明确、无统一的研究开发标准，但是助燃剂能够有效改善DBBF的燃烧性能，提高燃烧效率。最后，明确给出了常见DBBF添加剂的筛选原则，并展望了未来DBBF添加剂的研究方向，即在研究开发新型DBBF添加剂的同时，提升黏结剂和防腐降沉添加剂的工作效果，大力研发和完善DBBF助燃剂等具有复合功能效果的新型添加剂。

关键词: 生物燃料, 添加剂, 黏结, 腐蚀, 燃烧

CLC Number:

U473.5

CUI Xuyang, YANG Junhong, LEI Wanning, HUANG Tao, WANG Pufang, JIA Chen. Recent progress in research and application of DBBF additive in preparation and combustion process[J]. Chemical Industry and Engineering Progress, 2017, 36(04): 1247-1257.

崔旭阳, 杨俊红, 雷万宁, 黄涛, 王朴方, 贾晨. 生物质成型燃料制备及燃烧过程添加剂应用及研究进展[J]. 化工进展, 2017, 36(04): 1247-1257.

References

[1] 何玉凤,钱文珍,王建凤,等. 废弃生物质材料的高附加值再利用途径综述[J]. 农业工程学报,2016,32(15):1-8. HE Yufeng,QIAN Qian,WANG Jianfeng,et al. A review of the high added value of waste biomass materials[J]. Transactions of the Chinese Society of Agricultural,2016,32(15):1-8.
[2] 蔡政汉,林咏梅,陈翠霞,等. 椰壳碎炭制备高强度柱状颗粒活性炭试验[J]. 林业工程学报,2016,1(04):74-79. CAI Zhenghan,LIN Yongmei,CHEN Cuixia,et al. Preparation of high strength granular activated carbon from coconut shell activated carbon[J]. Journal of Forestry Engineering,2016,1(04):74-79.
[3] O'HAGAN C P,LEEN S B. A microstructural investigation into the accelerated corrosion of P91 steel during biomass co-firing[J]. Corrosion Science,2016,109(3):101-114.
[4] YUAN Hairong,PANG Yunzhi,WANG Kuisheng,et al. Ignition and emission characteristics of ignition-assisting agents for densified corn stover briquette fuel[J]. Chinese Journal of Chemical Engineering,2010,18(4):687-694.
[5] 黄艳,杜鹏东,张明远,等. 生物质颗粒燃料成型影响因素研究进展[J]. 生物质化学工程,2015,49(05):53-58. HUANG Yan,DU Pengdong,ZHANG Mingyuan,et al. Research progress on influence factors of biomass pellet fuel forming[J]. Biomass Chemical Engineering,2015,49(05):53-58.
[6] 陈彦宏,武佩,田雪艳,等. 生物质致密成型燃料制造技术研究现状[J]. 农机化研究,2010,32(01):206-211. CHEN Yanhong,WU Pei,TIAN Xueyan,et al. Research on manufacturing technology of biomass briquette fuel[J]. Journal of Agricultural Mechanization Research,2010,32(01):206-211.
[7] 庞利沙,田宜水,侯书林,等. 生物质颗粒成型设备发展现状与展望[J]. 农机化研究,2012,34(09):237-241. PANG he,TIAN Yishui,HOU Shulin,et al. Study on biomass and prospect of particle forming equipment[J]. Journal of Agricultural Mechanization Research,2012,34(09):237-241.
[8] 罗娟,侯书林,赵立欣,等. 生物质颗粒燃料燃烧设备的研究进展[J]. 可再生能源,2009,27(06):90-95. LUO Juan,HOU Shulin,ZHAO Lixin,et al. Research progress of pellet burning equipment[J]. Renewable Energy,2009,27(6):90-95.
[9] MILLER R B.Wood handbook-woodas an engineering material[M]. Madison:United States Department of Agriculture-Forest Service-Forest Products Laboratory,1999:25.
[10] 左鹏鹏,杨俊红,黄涛,等. 粒度和含水率对秸秆成型燃料生产能耗的影响[J]. 化工进展,2016,35(3):773-779. ZUO Pengpeng,YANG Junhong,HUANG Tao,et al. Energy consumption of straw briquette production of particle size and moisture content[J]. Chemical Industry and Engineering Progress,2016,35(3):773-779.
[11] OlSSON A M,SALMEN L.Viscoelasticity of insitu lignin as affected by structure-softwood vshardwood[M]//GlasserW,editor. Viscoelasticity of biomaterials. ACS symposium series 489.Washington:American Chemical Society,1992:133-143.
[12] STELTE W,HOHN J K.,SANADI A R.,et al. A study of bonding and failure mechanisms in fuel pellets from different biomassresources[J]. Biomass and Bioenergy,2011,32(2):910-918.
[13] STEVENS C A. Starch gelatinization and the influence of particle size,steam pressure and die speed onthe pelleting process[D]. Manhattan,KS:Kansas State University,1987.
[14] CAVALCANTI W B. The effect of ingredient composition on the physical quality of pelleted feeds:amixture experimental approach[D]. Manhattan,KS:Kansas State University,2004.
[15] THOMAS M,VAN VLIET T,VANDERPORL AFB. Physical quality of pelleted animal feed.3.contribution of feedstuff components[J]. Animal Feed Science and Technology,1998,70(01):59-78.
[16] 吴云玉,董玉平,吴云荣.生物质固化成型的微观机理[J]. 太阳能学报,2011,32(02):268-271. WU Yunyu,DONG Yuping,WU Yunrong. Micro mechanism of biomass solidification[J]. Acta Energiae Solaris Sinica,2011,32(02):268-271.
[17] CHUNG F H.Unified theory and guidelines on adhesion[J]. J. Appl. Polym. Sci.,1991,42(05):1319-1331.
[18] MARTINEZ A T. Molecular biology and structure-function oflignin-degrading heme peroxidases[J]. Enzyme and Microbial Technology,2002,30(4):425-444.
[19] 路瑶,魏贤勇,宗志敏,等. 木质素的结构研究与应用[J]. 化学进展,2013,25(05):838-858. LU Yao,WEI Xianyong,ZONG Zhimin,et al. Progress of lignin structure research and application of[J]. Progress in Chemistry,2013,25(05):838-858.
[20] 封百涛. 生物质液压成型机模具结构分析及优化[D]. 济南:山东大学,2012. FENG B T. Analysis and optimization of mold structure of biomass hydraulic forming machine[D]. Ji'nan:Shandong University,2012
[21] BACK E L.The bonding mechanism in hardboard manufacture[J]. Holzforschung,1987,41(4):247-258.
[22] 黎演明,黄志民,韦光贤,等. 一种生物质颗粒燃料黏结剂的制备方法及其应用:201510258246.3[P]. 2015-08-19. LI Yanming,HUANG Zhimin,WEI Guangxian,et al. A method for the preparation of biomass pellet fuel binder and its application:201510258246.3[P]. 2015-08-19.
[23] BULL H W,SWINEHART R W.Charcoal briquettes and method for their manufacture:US2822251[P]. 1958-04-04.
[24] 潘磊,王玉婷,王成双,等. 热固性环氧树脂改性沥青黏结剂的性能研究[J]. 热固性树脂,2011(4):33-37. PAN Lei,WANG Yuting,WANG Chengshuang,et al. Study on properties of thermosetting epoxy resin modified asphalt binder[J]. Thermosetting Resin,2011(4):33-37.
[25] 蒋健,李庆华,景阳,等. 固硫高强耐水型煤黏结剂:98100445.8[P]. 1998-07-22. JIANG Jian,LI Qinghua,JING Yang,et al. Sulfur high-strength waterproof briquette binder:98100445.8[P]. 1998-07-22.
[26] 龙波,张志敏,周向清,等. 一种基于生物质废料的酸性水体氟氯脱除剂及制备方法:201510605422.6[P]. 2015-11-25. LONG Bo,ZHANG Zhimin,ZHOU Xiangqing,et al. A method for the removal of fluoride from acid water bodies based on biomass waste:201510605422.6[P]. 2015-11-25.
[27] 沈美珍.一种复合型生物质型煤黏结剂及其制备方法:201510998135.6[P]. 2016-05-25. SHEN Meizhen. A composite bio briquette binder and its preparation method:201510998135. 6[P]. 2016-05-25.
[28] 王兢,刘凯,朱鹏飞. 生物质炭粉添加剂及其制备方法:201310004079.0[P]. 2014-07-09. WANG Jing,LIU Kai,ZHU Pengfei. The biomass carbon powder additive and preparation method thereof:201310004079.0[P]. 2014-07-09.
[29] M·梅多夫,H·梅多夫. 加工生物质:US105567743A[P]. 2016-05-11. MEDOFF M,MEDOFF H. Processing biomass:US105567743A[P]. 2016-05-11.
[30] 崔宁宁.利用造纸废液制作小麦秆成型燃料的试验研究[D]. 保定:华北电力大学(保定),2009. CUI Ningning. Experimental study on the formation of wheat straw based on the waste liquid of papermaking[D]. Baoding:North China Electric Power University (Baoding),2009
[31] 张俊. 黑荆树单宁-糠醇树脂的制备与应用性能研究[D]. 北京:北京林业大学,2016. ZHANG Jun. Black wattle tannin-furfuryl alcohol resin preparation and application properties of[D]. Beijing:Beijing Forestry University,2016
[32] FABORODE M O,CALLAGHAN JRO.Optimizing the compression/briquetting of fibrous agricultural materials[J]. Journal of Agricultural Engineering Research,1987,38(4):245-262.
[33] RUMPF H.The strength of granules and agglomeration[M]//Knepper W A,editor. Agglomeration. New York:JohnWiley,1962:379-418.
[34] BIKA D,TARDOS G I,PANMAI S,et al. Strength and morphology of solid bridges indry granules of pharmaceutical powders[J]. Powder Technology,2005,150(2):104-116.
[35] 肖雷. 基于褐煤的生物质型煤成型机理及其特性研究[D]. 北京:中国矿业大学,2011. XIAO Lei.Study on mechanism of biomass briquette forming of lignite and its characteristics[D]. Beijing:China University of Mining and Technology,2011.
[36] 闫新龙,刘欣梅,乔柯,等. 成型活性炭制备技术研究进展[J]. 化工进展,2008,27(12):1868-1872,1881. YAN Xin long,LIU Xinmei,QIAO Ke,et al. Progress of technology progress of chemical preparation of formed activated carbon[J]. Chemical Industry and Engineering Progress,2008,27(12):1868-1872,1881.
[37] 王越,白向飞.粉煤成型机理研究进展[J]. 洁净煤技术,2014,91(03):8-11. WANG Yue,BAI Xiang fei. The mechanism of fine coal forming progress of[J]. Clean Coal Technology,2014,91(03):8-11.
[38] 乔星星,张永发,王琪,等. 粉煤成型黏结力及其作用机理研究进展[J]. 煤炭技术,2015,261(09):295-297. QIAO Xingxing,ZHANG Yongfa,WANG Qi,et al. Research progress on bonding strength and mechanism of pulverized coal[J]. Coal Technology,2015,261(09):295-297.
[39] TAYLOR J W. Compaction and cementing of char particles with a tarderived binder[J]. Fuel,1988,67(11):1495-1502.
[40] 徐振刚,刘随芹.型煤技术[M]. 北京:煤炭工业出版社,2001:70-76. XU Zhengang,LIU Suiqin. coal technology[M].Beijing:Coal Industry Press,2001:70-76.
[41] 刘滋武,黄滔,巩馨骏,等. 生物质型煤发展综述[J]. 洁净煤技术,2014,20(03):98-102. LIU Ziwu,HUANG Tao,GONG Xinjun,et al. Review of the development of of biomass briquette[J]. Clean Coal Technology,2014,20(03):98-102.
[42] 杨凤玲,曹希,韩海忠,等. 高效复合型煤黏结剂性能及应用研究[J]. 洁净煤技术,2015,21(05):1-7. YANG Fengling,CAO Xi,HAN Haizhong,et al. Properties and application of high efficiency composite briquette binder[J]. Clean Coal Technology,2015,21(05):1-7.
[43] 刘佳. 生物质复合型煤黏结剂的制备与应用研究[D]. 兰州:兰州大学,2015. LIU Jia. Biomass briquette binder prepared and applied rearch[D]. Lanzhou:Lanzhou University,2015.
[44] SINGH J,KAURB L,MCCARTHYB OJ,Factors influencing the physico-chemical,morphological,thermal and rheological properties of some chemically modified starches for food applications:a review[J]. Food Hydrocolloids,2007,21(01):1-22.
[45] 刘雷.一种环保型高能复合生物质燃料及其制备方法:201510260642.X[P]. 2015-07-29. LIU Lei. A kind of environment friendly high energy compound biomass fuel and its preparation method:201510260642.X[P]. 2015-07-29.
[46] 文博,范高潮,孙长青,等. 成型参数对有黏结剂成型玉米秸秆燃料密度与强度的影响[J]. 沈阳农业大学学报,2012,43(01):114-116. WEN Bo,FAN Gaochao,SUN Changqing,et al. Effects of molding parameters on the density and strength of corn stalk with binder[J]. Journal of Shenyang Agricultural Uinversity,2012,43(01):114-116.
[47] 常厚春,马革,李祖芹,等. 生物质成型燃料:200910039713.8[P]. 2010-12-01. CHANG Houchun,Ma Ge,LI Zuqin,et al. Biomass fuel:200910039713.8[P]. 2010-12-01.
[48] PFOST H B. The effect of lignin binders,die thickness and temperature on the pelleting,process[J]. Feedstuffs,1964,36:54-69.
[49] SINGH A,SINGH Y. Briquetting of paddy straw[J]. Agricultural Mechanization in Asia,Africa and Latin America,1982,13:42-49.
[50] TABIL JR L G,SOKHANSANJ S,TYLER R T. Performance of different binders during alfalfa pelleting[J]. Canadian Agricultural Engineering,1997,39(01):17-23.
[51] RAZUAN R,CHEN Q,ZHANG X,et al. Pyrolysis and combustion of oil palm stone and palm kernel cake in fixed-bed reactors.[J]. Bioresource Technology,2010,101(12):4622-4629.
[52] 曾娘荣.一种助燃型生物质成型燃料的综合利用方法:201510473531.7[P]. 2015-11-04. CENG Niangrong. Comprehensive utilization method of biomass briquette combustion type:201510473531.7[P]. 2015-11-04.
[53] 颉二旺,张维.一种炭水浆燃料及其制备方法:201210204426.X[P]. 2012-10-24. Jie Erwang,ZHANG Wei. A carbon slurry fuel and its preparation method:201210204426.X[P]. 2012-10-24.
[54] 钱湘群,陈腾蛟,盛奎川,等. 玉米/木薯淀粉基竹炭成型燃料的品质特性[J]. 农业工程学报,2011,27(s1):157-161. QIAN Xiangqun,CHEN Tengjiao,SHENG Kuichuan,et al. The quality characteristics of maize/cassava starch based bamboo charcoal forming fuel[J]. Transactions of the Chinese Society of Agricultural,2011,27(s1):157-161.
[55] 张守玉,侯宝鑫,吴巧美,等. 生物质炭质成型燃料及其制备方法:201410499233.0[P]. 2015-03-11. ZHANG Shouyu,HOU Baoxin,WU Qiaomei,et al. Biomass carbon forming fuel and its preparation method:201410499233.0[P]. 2015-03-11.
[56] 相国松.秸秆生物蜂窝煤的生产方法及其专用设备:200710053916.3[P]. 2007-08-22. XIANG Guosong. Production method of stalk honeycomb briquet and its special equipment:200710053916.3[P]. 2007-08-22.
[57] 赵乐群,李玉琢,邰学林,等. 复合黏结剂及用于型煤生产工艺:94119416.7[P].1995-10-18. ZHAO Lequn,LI Yuzhuo,TAI Xuelin,et al. The composite binder and briquette for production process:94119416.7[P].1995-10-18.
[58] 兰进华. 一种生物质颗粒燃料的添加剂及其制备方法:201510635400. 4[P]. 2015-12-16. LAN Jinhua. An additive of biomass pellet fuel and its preparation method:201510635400.4[P]. 2015-12-16.
[59] 潘春跃,胡慧萍,黄可龙,等. 木炭粉成型用胶黏剂和成型工艺的研究[J]. 化学与黏合,2000(04):187-188. PAN Chunyue,HU Huiping,HUANG Kelong,et al. Study on adhesive and molding process of charcoal powder molding[J]. Chemistry and Bonding,2000(04):187-188.
[60] 崔锦棠. 一种烧烤用木炭的制作方法:199104366.9[P]. 2000-10-18. CUI Jintang. A method of making charcoal for barbecue:199104366.9[P]. 2000-10-18.
[61] 许绍良.一种生产高强度后成型生物质炭的生产方法:200610150049. 0[P].2008-04-30. XU Shaoliang. A method of producing biomass carbon after high strength:200610150049.0[P].2008-04-30.
[62] 卢辛成,蒋剑春,孟中磊,等. 生物质成型炭的制备及其性能研究[J]. 林产化学与工业,2013,33(2):81-84. LU Xincheng,JIANG Jianchun,MENG Zhonglei,et al.Study on the preparation and properties of biomass briquette[J]. Chemistry and Industry of Forest Products,2013,33(2):81-84.
[63] 张瑁,金就砺,李铮,等. 一种炭燃棒:01128124.3[P]. 2002-02-27. ZHANG Mao,LI Jiuin,LI Zheng,et al. A carbon fuel rod:01128124.3[P]. 2002-02-27.
[64] 刘兴洲,钱招瑞,徐世泊,等. 一种环保型固体燃料:200710120894.8[P]. 2008-06-8. LIU Xingzhou,QIAN Zhaorui,XU Shibo,et al. Zhaorui money,an environmentally friendly solid fuel:200710120894.8[P]. 2008-06-8.
[65] 耿玉国,李喜民. 一种木炭粉型材及制备方法:200410010341.3[P]. 2005-02-23. GENG Yuguo,LI Ximin. A kind of charcoal powder and its preparation method:200410010341.3[P]. 2005-02-23.
[66] UBAFO-PEREZ R,CARRASCO-MARIN F,FAIREN-JUNENEZ D,et al. Granular and monolithic activated carbons from KOH-activation of olive stones[J]. Microporous and Mesoporons Materials,2006,92(1-3):64-70.
[67] RODRIGUEZ-REINOSO F,MOLINA-SABIO M,GONZALEZ J C. Preparation ofactivated carbon-sepiolite pellets[J]. Carbon,2001,39(5):776-779.
[68] MOLINA-SABIO M,GONZALEZ J C,RODRIGUEZ-REINOSO F. Adsorption of NH₃and H₂S on activated carbon and activated carbon-sepiolite pellets[J]. Carbon,2004,42(2):448-450.
[69] 王丹. 生物质能源造型煤及生产工艺:200710056133.0[P]. 2008-04-09. WANG Dan. Biomass energy modeling coal and its production process:200710056133.0[P]. 2008-04-09.
[70] 祖元刚,杨磊,孙国勇,等. 一种固体生物燃料块的制备方法:200810209672. 8[P]. 2009-05-20. ZU Yuangang,YANG Lei,SUN Guoyong,et al. A method for the preparation of solid biofuel blocks:200810209672.8[P]. 2009-05-20.
[71] HÄKAN K,MARKUS B,MAGNUS B.Measures to reduce chlorine in deposits:application in a large-scale circulating fluidised bed boiler firing biomass[J]. Fuel,2011,90(04):1325-1334.
[72] NIELSEN H P,FRANDSEN F J,DAM-JOHANSEN K,et al.The implications of chlorine-associated corrosion on the operation of biomass-firing boilers[J]. Progress in Energy and Combustion Science,2000,26(3):283-298.
[73] HARDING N S,CONNOR D C.Ash deposition impacts in the power industry[J]. Fuel Processing Technology,2007,290(88):1082-1093.
[74] 左军,陈恩鉴.垃圾焚烧炉过热器高温腐蚀与防护的研究概况[J]. 锅炉技术,2002,33(3):26-32. ZUO Jun,CHEN Enjian. Study of boiler corrosion and protection technology of high temperature incineration furnace superheater[J]. Boiler Technology,2002,33(3),26-32.
[75] JENKINS B M,BAKKER R R,WEI J B. On the properties of washed straw[J]. Biomass and Bioenergy,1996,10(4):177-200.
[76] KASSMAN H,BÄFVER L,ÄMAND L E.The importance of SO₂ and SO₃ for sulphation of gaseous KCl——an experimental investigation in a biomass fired CFB boile[J]. Combustion and Flame,2010,157(09):1649-1657.
[77] AHO M,VAINIKKA P,TAIPALE R. Effective new chemicals to prevent corrosion due to chlorine in power plant superheaters[J]. Fuel,2008,87(06):647-654.
[78] 余滔. 添加剂对生物质燃烧灰沉积和腐蚀特性的影响规律研究[D]. 济南:山东大学,2013. YU Tao. Study on the influence of on characteristics of ash deposition and corrosion during biomass combustion[D]. Ji'nan:Shandong University,2013.
[79] THY P,ENKINS B M.High temperature melting behavior of urban wood fuel ash[J]. Energy & Fuels,2004,13(04):839-850.
[80] THOMASR M,LARRY J R,BAXTER L.Boiler deposits from firing Biomass fuels[J]. Biomass and Bioenergy,1996,10(02):125-138.
[81] 徐晓光. 生物质燃烧过程积灰形成机理的实验研究[D]. 北京:清华大学,2009. XU Xiaoguang. Experimental study on formation mechanism of ash accumulation in biomass combustion process[D]. Beijing:Tsinghua University,2009.
[82] 王瀚平. 复合生物质颗粒燃料灰特性及热特性研究[D]. 长春:吉林大学,2012. WANG Hanping. Study on the characteristics and thermal characteristics of compound biomass pellet fuel ash[D]. Changchun:Jilin University,2012.
[83] 谢泽琼. 生物质燃烧碱金属及氯排放特性研究[D]. 广州:华南理工大学,2013. XIE Zeqiong. Study on the characteristics of alkali metals and chlorine emission from biomass burning[D]. Guangzhou:South China University of Technology,2013.
[84] MISCHATHEIS,BENGT JOHANSKRIFVARS,MIK-KOHUPA.Fouling tendency of ash resulting from burning mixtures of biofuels.Part1:depositionrates[J]. Fuel,2006,85(07):1125-1130.
[85] 马孝琴,骆仲泱,方梦祥. 添加剂对秸秆燃烧过程中碱金属行为的影响[J]. 浙江大学学报,2006,40(4):599-604. MA Xiaoqin,LUO Zhongyang,FANG mengxiang. Effects of additives on straw burning behavior of alkali metals during[J]. Journal of Zhejiang University,2006,40(4):599-604.
[86] 袁海荣. 秸秆固化成型燃料助燃剂研制及燃烧特性试验与模拟研究[D]. 北京:北京化工大学,2010. YUAN Hairong. The straw briquette fuel combustion agent and combustion characteristics test and Simulation of[D]. Beijing:Beijing University of Chemical Technology,2010.
[87] 袁海荣,左晓宇,李秀金,等. 影响秸秆固化成型燃料点火过程的因素分析[J]. 农业工程学报,2009,25(6):224-228. YUAN Hairong,ZUO Xiaoyu,LI Xiujin,et al. Analysis of factors influencing the ignition process of straw curing[J]. Transactions of the Chinese Society of Agricultural,2009,25(6):224-228.
[88] 袁海荣,左晓宇,李秀金,等. 生物质成型燃料引火助燃剂的试验研究[J]. 可再生能源,2010,28(2):76-79,82. YUAN Hairong,ZUO Xiaoyu,LI Xiujin,et al. Biomass fuel ignition assisting agent test study of[J]. Renewable Energy,2010,28(2):76-79,82.
[89] 左晓宇,袁海荣,李秀金.秸秆固化成型燃料引火助燃剂研究[J]. 北京化工大学学报(自然科学版),2009,36(5):84-87. ZUO Xiaoyu,YUAN Hairong,LI Xiujin. The straw briquette fuel ignition combustion[J]. Journal of Beijing University of Chemical Technology(Natural Science Edition),2009,36(5):84-87.
[90] 黎诚.一种生物质成型燃料高效助燃物及生物质成型燃料输送机:201510383453.1[P].2015-10-07. LI Cheng. A high efficient combustion of biomass fuel and biomass fuel conveyor:201510383453.1[P].2015-10-07.
[91] 张守玉,侯宝鑫,吴巧美,等. 生物质炭质成型燃料及其制备方法:201410499233.0[P].2015-03-11. ZHANG Shouyu,HOU Baoxin,WU Qiaomei,et al. Biomass carbon forming fuel and its preparation method:201410499233.0[P].2015-03-11.
[92] 朱川,姜英,丁华.燃煤助燃剂催化助燃效果评价方法研究[J]. 煤炭科学技术,2014,42(11):111-115. ZHU Chuan,JIANG Ying,DING Hua. Coal combustion improver for catalytic combustion effect evaluation method of[J]. Coal Science and Technology,2014,42(11):111-115.
[93] 常厚春,马革,李祖芹.生物质成型燃料制备方法及系统:200910039714.2[P]. 2010-12-01. CHANG Houchun,MA,LI Zuqin. The biomass fuel preparation method and system:200910039714.2[P]. 2010-12-01.
[94] YANG Junhong,SHI Lei,LUO Mengyuan,et al. Enhanced lipid accumulation of Chlorella vulgaris through the culture strategy of cultivation with two-stage pH control method[C]//The 15th International Heat Transfer Conference,August 10-15,2014,Kyoto,Japan.
[95] 张芳,程丽华,徐新华,等. 能源微藻采收及油脂提取技术[J]. 化学进展,2012,24(10):2062-2072. ZHANG Fang,CHENG Lihua,XU Hua,et al. oil recovery and extraction of oil and fat[J]. Progress in Chemistry,2012,24(10):2062-2072.
[96] 蔡卓平,段舜山,朱红惠."污水-微藻-能源"串联技术新进展[J]. 生态环境学报,2012,21(7):1380-1386. CAI Zhuoping,DUAN Shunshan,ZHU Honghui. "Section by sewage-microalgae-energy" series of new advances in technology[J]. Ecology and Environmental Sciences,2012,21(7):1380-1386.
[97] 李道义,李树君,刘天舒,等. 微藻能源产业化关键技术的研究进展[J]. 农业机械学报,2010,41(s1):160-166. LI Daoyi,LI Shujun,LIU Tianshu,et al. Research progress on key technologies of microalgae energy industrialization[J]. Transactions of the Chinese Society for Agricultural Machinery,2010,41(s1):160-166.
[98] 李涛,李爱芬,桑敏,等. 富油能源微藻的筛选及产油性能评价[J]. 中国生物工程杂志,2011,31(4):98-105. LI Tao,LI Aifen,SANG Min,et al. Screening of microalgae and evaluation of oil production performance[J]. China Biotechnology,2011,31(4):98-105.
[99] 张海阳,匡亚莉,林喆.能源微藻采收技术研究进展[J]. 化工进展,2013,32(9):2092-2098. ZHANG Haiyang,KUANG Yali,LIN Zhe. Energy microalgae recovery technology research progress in[J]. Chemical Industry and Engineering Progress,2013,32(9):2092-2098.