MOFs-based materials for supercapacitor

doi:10.16085/j.issn.1000-6613.2016.09.026

Abstract

Abstract: Recently,more and more effort has been devoted to exploring metal-organic frameworks (MOFs)-based materials for electrochemical energy storage application because of their enormously high surface areas,tunable pore size and diverse structures. This article summarized recent research progress of pristine MOFs,MOFs-composites and MOF-derived materials made for supercapacitors. The general and feasible synthetic strategies for the design and fabrication of MOFs based supercapacitors,and their structural diversity and electrochemical properties with respect to capacitive performance were demonstrated. Finally,problems of MOF-based supercapacitors such as unstable structure, weak electronic conductivity and limited practical applications were highlighted.

Key words: metal-organic frameworks (MOFs), electrochemistry, supercapacitor, composites, derivative

摘要： 金属有机骨架材料（MOFs）多样的组成与结构、高的比表面积和丰富的孔结构等优势，使其逐渐成为高性能电化学储能与转换电极材料研究的热点之一。本文主要介绍了MOFs在超级电容器中的应用研究，阐述了MOFs自身及其复合材料和衍生物（多孔碳、金属硫化物及氧化物）在超级电容器材料应用领域的研究进展，讨论了MOFs基超级电容器的结构特征及其在电化学储能领域中展现出特殊的性质和新颖的功能，提出了MOFs构筑的超级电容器在新能源储存与转换领域发挥的重要作用，最后对MOFs基超级电容器自身结构稳定性差、导电率偏低及其实际应用受限进行了分析。

关键词: 金属有机骨架, 电化学, 超级电容器, 复合材料, 衍生物

CLC Number:

TQ152

ZHOU Jian, XIE Linhua, DOU Yibo, LI Jianrong. MOFs-based materials for supercapacitor[J]. Chemical Industry and Engineering Progree, 2016, 35(09): 2830-2838.

周健, 谢林华, 豆义波, 李建荣. MOFs基材料在超级电容器中的应用[J]. 化工进展, 2016, 35(09): 2830-2838.

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